Solid state supramolecular

Toward the Construction of Functional Solid-State Supramolecular Metal Complexes Containing Copper(I) and Silver(I)... 

Solid-State Supramolecular Chemistry Crystal Engineering , Comprehensive Supramolecular Chemistry, Vol. 6 (Eds. J. L. Atwood, J. E. D. Davies, D. D. MacNicol, F. Vogtle, K. S. Suslick), Pergamon, Oxford, 1996. 

MacNicol DD, Toda F,Bishop R (eds) (1996) Comprehensive supramolecular chemistry, vol 6. Solid-state supramolecular chemistry crystal engineering. Pergamon, Oxford... 

Solid-state supramolecular complexes, see Su-pramolecular copper(l)/silver(I) complexes Solubility products, 17 215 Soluble methane monooxygenase protein system, 42 263-286 hydroxylation... 

A dione 74 also undergoes ODPM rearrangement under direct irradiation to give compound 75 in 94% yield (Scheme 4.30) [44]. The product 75 was crystallized from ethyl acetate/hexane at room temperature to lead to two polymorphs. Polymorphism is recognized as being a vital branch of solid-state supramolecular chemistry. 

H. Kessler, in Comprehensive Supramolecular Chemistry, Vol. 7, Solid-State Supramolecular Chemistry Two- and Three-Dimensional Inorganic Networks, J.L. Atwood, J.E. Davis, D.D. MacNicol, and F. Vogtle, (editors), Pergamon, London, 1996, p. 425. 

Alberti G, Bein T, eds. Solid-state Supramolecular Chemistry Two- and Three-dimensional Inorganic Networks. Vol. 7. New York Pergamon, 1996. 

Zacharias, D. E. and Desiraju, G. R. (1993). Solid-state supramolecular assembly via C—H O hydrogen bonds - crystal structures of the complexes... 

A relatively new field called supramolecular chemistry has been developed over the last three decades. Supramolecular assemblies and supramolecular polymers differ from macromolecules, where the monomeric units are covalently linked. In a supramolecular polymer, the monomeric units self-assemble via reversible, highly directional, noncova-lent interactions. These types of bonding forces are sometimes called secondary interactions. Hydrogen bonding is the secondary force most utilized in supramolecular chemistry, but metal coordination and aromatic tt-tt electronic interactions have also been used. From a materials standpoint, supramolecular assemblies are promising because of the reversibility stemming from the secondary interactions. The goal is to build materials whose architectural and dynamical properties can respond reversibly to external stimuli. Solid phases are prepared by self-assembly from solution. In the solid-state, supramolecular polymers can be either crystalline or amorphous. 

Desiraju, G.R. Crystal engineering solid state supramolecular synthesis. Curr. Opin. Solid State Mater. Sci. 1997, 2 (4), 451 54. 

Fig. 15 The solid-state supramolecular wheel-and-axle compound involving 4-(triphenyl-methyl)benzoic acid. Included 4-chlorobenzene is shown between the dimers.

The first crystal structure to be described is that of 2,3-bis(trimethylsilyl)-l-stanna-2,3-dicarba-closo-heptaborane(4) (1), isolated as a benzene hemisolvate. The immediate coordination geometry about the tin atom is defined by three boron and two carbon atoms, all of which lie on one side of the tin atom, leaving a large gap in the environment of the tin atom. In the solid-state supramolecular structure, two tin atoms associate with a solvent benzene molecule that is disposed about a crystallographic center of... 

Das, A.K., Banerjee, A., Drew, M.G.B., Haidar, D., Banerjee, A. Stepwise self-assembly of a tripeptide from molecular dimers to supramolecular /3-sheets in crystals and amyloid-Uke fibrils in the solid state, Supramolecular Chemistry. 16(5) (2004) 331-335. 

TOWARD THE CONSTRUCTION OF FUNCTIONAL SOLID-STATE SUPRAMOLECULAR METAL COMPLEXES CONTAINING COPPER(I)... 

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