Sodium phenylphenolate

For sapstain treatment (protection of freshly cut and sawn timber against staining fungi and superficial moulds) borax is used in mixture with other fungicides, in particular with sodium pentachlorophenate (Section 5.6.3), but with sodium phenylphenolate (Section 5.4.1) or with quaternary ammonium compounds (Section 16.1) too. 

Ortho- and/ i ra-phenylphenols are commercially significant biphenyl derivatives that do not involve biphenyl as a starting material. Both are produced as by-products from the hydrolysis of chlorobenzene [108-90-7] with aqueous sodium hydroxide (68). o-Phenylphenol, ie, l,l-biphenyl-2-ol [90-43-7], particularly as its sodium salt, is widely used as a germicide or fungicide. Pi ra-phenylphenol [92-69-3] with formaldehyde forms a resin used in surface coatings. 

Phenylphenol was one of the earliest carrier-active compounds used industrially. Originally it was used as its water-soluble sodium salt (4). By lowering the pH of the dyebath, the free phenol was precipitated in fine form and made available to the fiber. However, proprietary Hquid preparations containing the free phenol are available that afford a greater ease of handling. 

Sodium o-phenylphenolate (4H2O) [132-27-4] M 264.3. Crystd from acetone and dried under vacuum at room temperature. 

The mesogenic units with methylenic spacers were prepared by reacting the sodium salt of either 4-methoxy-4 -hydroxybiphenyl or 4-phenylphenol with a bromoester in DMF at 82° C for at least 4 hours in the presence of tetrabutylammonium hydrogen sulfate (TBAH) as phase transfer catalyst. In this way, ethyl 4-(4-oxybi-phenyl)butyrate, ethyl 4-(4-methoxy-4 -oxybiphenyl)butyrate, ethyl 4-(4-oxybiphenyl)valerate, ethyl 4-(4-methoxy-4 -oxybiphenyl)-valerate, n-propyl 4-(4-oxybiphenyl)undecanoate and n-propyl 4-(4-methoxy-4 -oxybiphenyl)undecanoate were obtained. These esters were hydrolyzed with base and acidified to obtain the carboxylic acids. The corresponding potassium carboxylates were obtained by reaction with approximately stoichiometric amounts of potassium hydroxide. Experimental details of these syntheses were described elsewhere (27). 

Sodium ortZ/o-phenylphenate see also ortho-Phenylphenol)... 

Weigh out 0.15 gof 3-phenylphenol into a 100-ml volumetric flask, dissolve in <100 ml of 0.5% (w/v) sodium hydroxide (see recipe) then adjust the final volume to 100 ml with 0.5% sodium hydroxide. Store in a dark bottle (or wrap the bottle in aluminum foil) at 4°C. The solution is stable for 1 month. 

DOWIZID A 2-HYDROXYBIPHENYL SODIUM SALT 2-HYDROXYDIPHENYL SODIUM 2-HYDROXYDIPHENYL, SODIUM SALT MIDDU-RID MYSTOX WFA NATRIPHENE OPP-Na OPP-SODIUM ORPHENOL PHENOL, o-PHENYL-, SODIUM deriv. o-PHENYLPHENOL, SODIUM SALT 2-PHENYL-PHENOL SODIUM SALT PREVENTOL-ON PREVENTOL ON ON EXTRA SODIUM 2-BIPHENYLOLATE SODIUM (l,l -BIPHENYL)-2-OLATE... 

SODIUM, (2-BIPHENYLYLOXY)- SODIUM 2-HYDROXYDIPHENYL SODIUM ORTHO PHENYLPHENATE SODIUM o-PHENYLPHENATE SODIUM 2-PHENYLPHENATE SODIUM o-PHENYLPHENOL SODIUM o-PHENYLPHENOLATE... 

The hydrogen atom of the aquo group of (XII) is acidic the complex reacts with sodium hydroxide to yield an ill-characterized salt (10), and will condense with other acidic hydroxyl groups. Thus Owen and Kenney (268) have synthesized a series of aryloxy aluminum derivatives by the condensation of (XII) with various phenols. The complexes formed with phenol, p-phenylphenol, and p-methoxyphenol—(XIV), (XV), and (XVI)... 

Sample preparation 50 mL Urine + 7 mL concentrated HCl, heat at 90° for 1 h, add 10 pL 1 mg/mL 4-phenylphenol in MeOH, extract 3 times with 10 mL diethyl ether, combine organic phases, wash twice with 20 mL portions of pH 10.5 NaHCOs/NaOH buffer, wash with 20 mL water, dry over 5 g anhydrous sodium sulfate. Filter, evaporate under reduced pressure almost to dryness, ttike up residue in 1 mL mobile phase, inject 20 pL aliquot. 

Biphenyl)-2-ol 2-Biphenylol o-Biphenylol. Seeo-Phenylphenol (1,1 -Biphenyl)-2-ol, sodium salt 2-Biphenylol, sodium salt. 5 Sodium... 

Thiodielhylene bis (3,5-di-t-butyl-4-hydroxy) hydrocinnamate m-Hydroxy-N,N-dimethyl aniline. See Dimethylaminomethyl phenol Hydroxydimethylbenzene. SeeXylenol 2-Hydroxydiphenyl o-Hydroxydiphenyl. Seeo-Phenylphenol 2-Hydroxydiphenyl sodium salL See Sodium o-phenylphenate... 

Phenylphenol sodium salt o-Phenylphenol sodium salt. See Sodium... 

Synonyms (1,1 -Biphenyl)-2-ol, sodium salt 2-Biphenylol, sodium salt 2-Hydro) iphenyl sodium salt 2-Hydroxydiphenyl sodium salt 2-Phenylphenol sodium salt o-Phenylphenol sodium salt Sodium 2-biphenylolate Sodium biphenyl-2-yl oxide Sodium 2-hydro) iphenyl Sodium o-phenylphenol Sodium 2-phenylphenolate Sodium 0-phenylphenolate Sodium o-phenylphenoxide SOPP Deiirndon Sodium salt of o-phenylphenol avail, commercially as the tetrahydrate En xrical C,2H,0 Na... 

Sodium o-phenylphenol Sodium 2-phenylphenolate Sodium o-phenylphenolate Sodium o-phenylphenoxide. See Sodium o-phenylphenate... 

Alcohof, p-Chloro-m-cresof, Chbroxylenot, Cresyllc add, p-DIchlorobenzene DIdecyIdImonlum chloride 2-Ethylhexanol, Formaldehyde Formk add, Glutaral, Glyoxal, Isobuyric add, o-Phenylphenol, Proplonaldehyde, Sodium fluoride Sodium o-phenylphenate Xylenol... 

Sodium pyrithbne preservative, wax dispersions DImethybl urea-, Protectol DMU preservative, wax emulsions o-Phenylphenol Troysan 186-11 ... 

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