Sodium aluminum chlorid

Chloroform Aluminum, magnesium, potassium, sodium, aluminum chloride, ethylene, powerful oxidants... [Pg.1207]

The second electrolyte, the melt of sodium aluminum chloride, provides another advantage for the ZEBRA system. This second electrolyte makes the system tolerant to overcharge and overdischarge. In the overcharge reaction NaAlCl4 reacts with nickel to form sodium, nickel chloride, and... [Pg.567]

When all the nickel chloride has been discharged, the remaining sodium will react with sodium aluminum chloride to form sodium chloride and aluminum ... [Pg.567]

The molten salt, sodium aluminum chloride, fulfills two other tasks in the cell system. The ceramic electrolyte "-alumina is sensitive to high-current spots. The inner surface of the ceramic electrolyte tube is completely covered with molten salt, leading to uniform current distribution over the ceramic surface. This uniform current flow is one reason for the excellent cycle life of ZEBRA batteries. [Pg.568]

The properties of the molten electrolyte sodium aluminum chloride influence the performance and the behavior of the ZEBRA cell. [Pg.582]

Solubility of Nickel Chloride in Sodium Aluminum Chloride... [Pg.585]

Deville (1) The first commercial process for making aluminum metal. Molten sodium aluminum chloride was reduced by heating with metallic sodium. Invented by H. E. St-Claire Deville and operated around 1854 to 1890. Superseded by the Hall-Heroult process. See also Cowles. [Pg.85]

Gay Lussac and Thenard in 1809 obtained very impure amorphous silicon by passing silicon tetrafluoride over heated potassium. Berzelius in 1823 prepared elemental silicon in high purity by the same method. He also obtained silicon by heating potassium fluosilicate with potassium metal. Deville produced crystalline silicon in 1854 by electrolysis of a molten mixture of impure sodium aluminum chloride containing 10% silicon and a small quantity of aluminum. [Pg.818]

The first crystalline silicon was prepared by Henri Sainte-Claire Deville in 1854 ( 9,31). In the course of his researches on aluminum, he decomposed an impure sodium aluminum chloride with the voltaic pile, and obtained a gray, brittle, granular melt containing 10.3 per cent of silicon. When he dissolved away the aluminum, some shining platelets remained. [Pg.587]

In 1854 R. W. Bunsen in Heidelberg and H. Sainte-Claire Deville in Paris, working independently of each other, obtained metallic aluminum by electrolysis of fused sodium aluminum chloride (54, 80, 81). [Pg.605]

COLORANTS FORFOOD,DRUGS, COSMETICS AND MEDICALDEVICES] (Vol 6) Sodium aluminum chloride [7784-16-9]... [Pg.899]

Sodium aluminum chloride, 435 Sodium amalgam, 310, 416-417 Sodium amide-Sodium r-butoxide, 417-418 Sodium azide-Triphenylphosphine, 418 Sodium bis(2-methoxyethoxy)aluminum hydride, 166,418-420 Sodium borohydiidc, 323,420-421 Sodium borohydride-Alumina, 421 Sodium borohydride-Bis(2,4-pentane-dionato)copper(ll), 421 Sodium borohydride-Cerium(Ill) chloride,... [Pg.301]

Henri Saint-Claire Deville, of France, and R. Bunsen, of Germany, independently accomplish the electrolysis of aluminum from sodium aluminum chloride. [Pg.47]

Silver trifluoroacetate, 327, 328 Silyl ethers, 477-478 Simmons-Smith reagent, 436-437 (3-Sinensal, 283 Sirenin, 424 Sodium, 246, 268, 437 Sodium acetate, 578 Sodium aluminum chloride, 438 Sodium aluminum diethyl dihydride, 438 Sodium aluminum hydride, 316 Sodium amalgam, 41,438-439 Sodium amide, 231, 305,403,439 Sodium amide-Sodium f-butoxide, 439-440 Sodium-Ammonia, 26, 32,134, 260,438 Sodium azide, 9, 77, 210, 323, 440-441 Sodium benzoxide, 111 Sodium bis-(2-methoxyethoxy)aluminum hydride, 164, 293, 360,441-442 Sodium bistrimethylsilylamide, 442-443,... [Pg.331]

Aluminum chloride, AICI3. Mol. wt. 133.35. See also Sodium aluminum chloride. Some procedures of the not-too-distant past specified that commercial material be freshly sublimed or finely ground, or that an excess be taken to allow for the presence of inert material. Finely divided material of high purity is now available in small lots (B, E, F, Mallinckrodt, MCB). [Pg.15]

Friedel-Craets reaction Aluminum chloride. Benzenesulfonic anhydride. Boron trifluoride. 7-Butyrolactone. Catechol dichloromethylene ether. Chloroform (solvent). Chloromethyl methyl ether. 1,1-Didilorodimethyl ether. 2,4-Dinitrobenzenesulfenyl chloride. Hydrogen fluoride. Iodine. Folyphosphoric add. Sodium aluminum chloride. Stannic chloride. Sulfur. Sulfur monochloride. Titanium tetrachloride. Trichloramine. Zirconium tetrachloride. Friedel-Craets type reactions Dimethylacetamide. lodosobenzene. [Pg.658]

Sodium acetate, 433,1024-1627,1132 Sodium acetylide, 573, 1627 Sodium aluminum chloride, 709,1627-1629 Sodium aluminum hydride, 1036 Sodium amalgam, 1630-1633 40% Sodium amalgam (liquid), 1633-1634 Sodium amide, 185,250,357,392,698,1634-1041, 1217... [Pg.726]

Partridge el effected cyclodehydrogenation of the triazabenzanthracene (1) to tricycloquinazoline (2) with sodium aluminum chloride in much higher yield... [Pg.1248]

Cyclization Aluminum chloride. Phosphoric-Formic acid. Polyphosphoric acid. Sodium aluminum chloride. Sodium bistrimethylsilylamide. Stannic chloride. [Pg.1387]

Cyclodehydration Aluminum chloride see also Methyl fluorene-9-carboxylate). Dowtherm. Fluorosulfonic acid. Hydrogen fluoride. Perchloric add. Phosphorus pentoxide. Phosphoryl chloride. Polyphosphate ester. Polyphosphoric add. Potassium bisulfate. Sodium aluminum chloride. Sulfur trioxide-Dimelhylformamide. />-Toluenesulfonic acid. Trifluoroacetic acid. Trifluoroacetic anhydride. [Pg.1387]

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