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Singlet oxygen from hydrogen peroxide

The thermal generation of singlet oxygen from hydrogen peroxide and hypochlorite presumably involves the chloroperoxy anion other synthetically useful examples involve decomposition of phosphite ozonides or endoperox-ides, as indicated in Scheme 67 (cf. Murray, 1979). [Pg.480]

I. Formation of singlet oxygen from hydrogen peroxide with two-electron oxidants. [Pg.287]

Figure 2.51 Methods for the generation of singlet molecular oxygen from hydrogen peroxide. Figure 2.51 Methods for the generation of singlet molecular oxygen from hydrogen peroxide.
Inoue S, Kawanishi S (1989) ESR evidence for superoxide, hydroxyl radicals and singlet oxygen produced from hydrogen peroxide and nickel(II) complex of glycylglycyl-L-histidine. Biochem Biophys Res Commum 159 445-451 Inoue S, Yamamoto K, Kawanishi S (1990) DNA damage induced by metabolites of o-phenylphenol in the presence of copper(II) ion. Chem Res Toxicol 3 144-149... [Pg.367]

Classical chemiluminescence from lucigenin (20) is obtained from its reaction with hydrogen peroxide in water at a pH of about 10 Qc is reported to be about 0.5% based on lucigenin, but 1.6% based on the product A/-methylacridone which is formed in low yield (46). Lucigenin dioxetane (17) has been prepared by singlet oxygen addition to an electron-rich olefin (16) at low temperature (47). Thermal decomposition of (17) gives of 1.6% (47). [Pg.265]

Most likely singlet oxygen is also responsible for the red chemiluminescence observed in the reaction of pyrogaHol with formaldehyde and hydrogen peroxide in aqueous alkaU (152). It is also involved in chemiluminescence from the decomposition of secondary dialkyl peroxides and hydroperoxides (153), although triplet carbonyl products appear to be the emitting species (132). [Pg.270]

Strong evidence in favor of mechanism B was obtained when it was discovered that singlet oxygen produced chemically by the reaction of hydrogen peroxide and sodium hydrochlorite or from gaseous oxygen excited by an electrodeless discharge yields the same products as the direct photolysis/85-8 ... [Pg.342]

Emission from dimols of singlet oxygen may be detected by photomultipliers used for measurement of chemiluminescence from hydrocarbon polymers with a maximum spectral sensitivity at 460 nm. The above scheme, however, requires the presence of at least one molecule of hydrogen peroxide in close vicinity to the two recombining peroxyl radicals and assumes a large heterogeneity of the oxidation process. [Pg.465]

The photosensitized results are from I.B.C. Matheson and J. Lee 118h It is seen that the quantum yields in photosensitized oxidation depend on the concentrations of luminol and base, and on temperature. At higher temperature (50°) and low luminol concentrations, the quantum yields reached those of hemin-catalyzed hydrogen peroxide oxidation of luminol in aqueous-alkaline solution. Primary products of the photosensitized oxidation are singlet oxygen (1Ag02) or a photoperoxide derived from methylene blue, but neither of these is directly responsible for the luminol chemiluminescence. [Pg.104]

HTAC cationic micelles also markedly enhance the CL intensity of fluorescein (FL) in the oxidation of hydrogen peroxide catalyzed by horseradish peroxidase (HRP) [39], However, no CL enhancement was observed when anionic micelles of sodium dodecyl sulphate (SDS) or nonionic micelles of polyoxyethylene (23) dodecanol (Brij-35) were used (Fig. 9). CL enhancement is attributed to the electrostatic interaction of the anionic fluorescein with the HTAC micelles. The local concentration of fluorescein on the surface of the micelle increases the efficiency of the energy transferred from the singlet oxygen (which is produced in the peroxidation catalyzed by the HRP) to fluorescein. This chemiluminescent enhancement was applied to the determination of traces of hydrogen peroxide. The detection limit was three times smaller than that obtained in aqueous solution. [Pg.298]


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From oxygenates

From peroxides

OXYGEN hydrogen

Oxygen hydrogen peroxide

Oxygen peroxides

Oxygenation singlet oxygen

Singlet oxygen

Singlet oxygenation

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