Silanes vinylation

Styrene monomer was also copolymerized with a series of functional monomers by using a single-step dispersion copolymerization procedure carried out in ethanol as the dispersion medium by using azobisizobu-tyronitrile and polyvinylpyrollidone as the initiator and the stabilizer, respectively [84]. The comonomers were methyl methacrylate, hydroxyethyl acrylate, metha-crylic acid, acrylamide, allyltrietoxyl silane, vinyl poly-dimethylsiloxane, vinylsilacrown, and dimethylamino-... [Pg.216]

SYNS SILANE, VINYL TRICHLORO 1-150 TRICHLORO(VINYL)SILANE TRICHLOROVINYL SILICANE UNION CARBIDE A-150 VINYLSILICON TRICHLORIDE VINYL TRICHLOROSILANE pOT) VINYL TRICHLOROSILANE, INHIBITED pOT)... [Pg.1368]

However, at much higher temperatures, Tris reacts very cleanly with acetylene to give an excellent yield of vinyltris(dimethylamino)silane (vinyl-Tris) ... [Pg.610]

Silanes used for treatment dimethyldiethoxy silane, 3-(methacryloxy) propyltrimethoxy silane, vinyl triethoxy silane, amino silane. Silane coating was estimated to be 0.2 wt%. Treatment with epoxy silane has been used followed by PS-maleic anhydride grafting through amine spacer. [Pg.87]

One of the reactions which occurs on the surface of filler particles is that involving silanes. Vinyl silanes and mercapto silanes being typical examples. Kaolin modified with an isocyanate can react with polyols. Magnetic resonance spectroscopy was used to identify various crosslinks involving the filler and this shows that crosslinked rubber chains were attached to the surface of the carbon black. [Pg.339]

We have seen that vinyl silanes can be prepared by hydrosilylation of alkynes by three different mechanisms giving good control over geometry of these inevitably terminal vinyl silanes. Vinyl silanes are stable compounds and can be isolated, unlike most of the vinyl metals we have seen so far, and other ways of making vinyl silanes allow the more-or-less controlled synthesis of mono-or trisubstituted compounds with reasonable control over selectivity. These include the Peterson reaction with two SiMe3 groups on the same carbon atom 183 and, more relevant to this chapter, reactions of vinyl lithiums with silyl chlorides.44... [Pg.271]

Beilstein Handbook Reference) AI3-51468 BRN 1767229 CCRIS 2645 CV-4910 EINECS 201-081-7 KBE 1003 NV1107 Polyscience VTES Silane A151 Silane, ethenyltriethoxy-Silane, Iriethoxy-vinyl- Silane, vinyl triethoxy 1-151 Triethoxy(vinyl)sil-ane Triethoxyvinyl silane Triethoxyvinylsilicane Union Carbide A-151 Vinyltriethoxysilane VTES VTS-E Intermediate, especially when acidic by-products are undesirable filler, bp = 160-161 , bp20 = 62 d = 0.901 soluble in CHCI3 Degussa-Huls Corp. PCR Union Carbide Carp. [Pg.667]

CAS 78-08-0 EINECS/ELINCS 201-081-7 Synonyms Ethenyltriethyloxysilane Silane, ethenyltriethoxy- Silane, triethoxyvinyl- Silane, vinyl triethoxy (Triethoxysilyl) ethylene Triethoxyvinylsilane Triethoxyvinylsilicane VTES... [Pg.1416]

Silane, vinyl trichloro-. See Vinyltrichlorosilane Silane, vinyl triethoxy. See Vinyltriethoxysilane Silanol-terminated dimethicone Silanol-terminated polydimethylsiloxane. See Dimethicone, silanol-terminated Silanol-terminated... [Pg.3909]

Synonyms Silane, trichlorovinyl- Silane, vinyl trichloro- Trichloroethenylsilane (Trichlorosilyl) ethylene Trichlorovinylsilane Trichlorovinyl silicane Vinyl silicon trichloride Vinyl trichlorosilane, inhibited VTC Empirical C2H3CI Si Formula H2C=CHSiCl3... [Pg.4691]

Silane, vinyl triethoxy (Triethoxysilyl) ethylene Triethoxyvinylsilane Triethoxyvinylsilicane VTES... [Pg.4692]

EPR, EPDM Vinyl, sulfur, mercapto, thiocyanato Vinyltriethoxysilane, vinyltrimethoxysilane, vinyltris(2-methoxyethoxy)silane, vinyl/alkyl-functional siloxane oligomer... [Pg.78]

Trichloroethylene Tris(trimethylsiloxy)vinyl silane Vinyl acetate Vinylcaprolactam Vinylcarbazole Vinyl laurate... [Pg.266]

In addition to the numerous examples of the McMurry couplings described above, the following examples illustrate the power of the transformation in the synthesis of a broad range of natural products and non-natural molecules. Of particular note in the following examples is the impressive functional group tolerance of the McMurry conditions. In general, alcohols, tosyl alcohols, alkyl ethers, silyl ethers, alkyl silanes, vinyl silanes, amines, sulfides, and alkenes are inert to McMurry conditions. Acteals, halides, alkynes, nitriles, and carboxylic acids are semi-compatible. [Pg.278]

There are many versions of clays (hydrated aluminum silicate) available including soft clay, hard clay, air floated, water washed, calcined, and surface-treated versions. Surface treatments include stearates, mercapto-silane, vinyl silane, and amino silane. Select the silane treatment that is compatible with the cure system to be used. Clay may be used in large quantities, is inexpensive, easy to incorporate, calender or extrude and provides some reinforcement to NBR compounds. [Pg.65]

Glass Beads Z6032 Silane (Vinyl benzylamine functional silane)... [Pg.463]

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