Session II High-temperature electrolysis

Status of the INL high-temperature electrolysis research programme - experimental and modelling 

Two thermal boundary condition limits were considered for the electrolyser isothermal and adiabatic. Actual electrolyser operation will generally lie between these limits. For the isothermal cases, heat from the reactor was directly supplied to the electrolyser to maintain isothermal conditions for operation below the thermal neutral voltage. Heat rejection from the electrolyser is required to maintain isothermal operation at operating voltages above thermal neutral. For the adiabatic cases, the direct electrolyser heater was not used. 

To allow for performance comparisons between HTE and alternate hydrogen production techniques, we have adopted a general overall efficiency definition that can be applied to any thermal 

The denominator in this efficiency definition quantifies all of the net thermal energy that is consumed in the process, either directly or indirectly. For a thermochemical process, the majority of the high-temperature heat from the reactor is supplied directly to the process as heat. For HTE, the majority of the high-temperature heat is supplied directly to the power cycle and indirectly to the HTE process as electrical work. Therefore, the summation in the denominator of Eq. (1) includes the direct nuclear process heat as well as the thermal equivalent of any electrically driven components such as pumps, compressors, HTE units, etc. The thermal equivalent of any electrical power consumed in the process is the power divided by the thermal efficiency of the power cycle. For an electrolysis process, the summation in the denominator of Eq. (1) includes the thermal equivalent of the primary electrical energy input to the electrolyser and the secondary contributions from smaller components such as pumps and compressors. In additional, any direct thermal inputs are also included. Direct thermal inputs include any net (not recuperated) heat required to heat the process streams up to the electrolyser operating temperature and any direct heating of the electrolyser itself required for isothermal operation. 

The stack electrolytes are scandia-stabilised zirconia, about 140 (im thick. The air-side electrodes (anode in the electrolysis mode) are a strontium-doped manganite. The electrodes are graded, with an inner layer of manganite/zirconia ( 13 pm) immediately adjacent to the electrolyte, a middle layer of pure manganite ( 18 pm), and an outer bond layer of cobaltite. The steam/hydrogen electrodes (cathode in the electrolysis mode) are also graded, with a nickel-zirconia cermet layer ( 13 pm) immediately adjacent to the electrolyte and a pure nickel outer layer ( 10 pm). 

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