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Semifluorinated polymers

Granville AM, Boyes SG, Akgun B, EosterMD, Brittain WJ. Synthesis and characterization of stimuli-responsive semifluorinated polymer brushes prepared by atom transfer radical polymerization. Macromolecules 2004 37 2790-2796. [Pg.59]

One of the approaches to make organo-soluble polymer is the preparation of semifluorinated polymers. Over the past 30years or more there has been spectacular growth in research in the field of fluorinated polymers [7-9]. It has been observed that incorporation of fluorine in the form of trifluoromethyl (-CF3) or... [Pg.2]

The need to develop superior polymeric materials with an excellent combination of chemical, physical, and mechanical properties with ease of processability has triggered research on semifluorinated polymers. Incorporation of fluorine in polymers imparts many interesting properties. Ruorine and perfluoro-alkyl groups in polymers enhance processability and increase thermal stability, reduce water absorption and dielectric constant, and enhance gas permeability. All of these superior properties of perfluorinated polymers result from many unique properties of fluorine. The highest electronegativity of fluorine and the high bond strength and low polarizability of C-F bonds cause many of these properties. [Pg.9]

Surface orientation and grafting density of semifluorinated polymers (35-39)... [Pg.9336]

With an effort to determine the condition in which semifluorinated polymer surfaces become responsive, we have probed several families of semifluorinated polymers both experimentally [26-29] and computationally [30-32]. Our studies have... [Pg.44]

FIGURE 11.7 Polymer-analogous reactions to create semifluorinated polymers (a) hydrosi-lylation of polyhydrosiloxanes (b) conversion of hydroborated poly(styrene-Z -isoprene) block copolymers with 5/carboxylic acid chlorides. [Pg.243]

SELF-ORGANIZATION BEHAVIOR OF SEMIFLUORINATED POLYMERS IN BULK AND IN THIN FILMS... [Pg.252]

SEMIFLUORINATED POLYMERS FROM TRIFLUOROVINYL AROMATIC ETHER MONOMERS... [Pg.343]

Hirao, A., Sugiyama, K., and Yokoyama, H. (2007) Precise synthesis and surface structures of architectural per- and semifluorinated polymers with well-defined structures. Progress in Polymer Science, 32,1393-1438. [Pg.226]

GaUi, G., MartineUi, E., Chiellini, E. et al. (2005) Low surface energy characteristics of mesophase-forming ABC and ACB triblock copolymers with fluorinated B. blocks. Molecular Crystals arul Liquid Crystals, 441,211-226. Genzer, J., Sivaniah, E., Kramer, E.J. et al. (2000a) Temperature dependence of molecular orientation on the surfaces of semifluorinated polymer thin films. Langmuir, 16,1993-1997. [Pg.734]

Krupers, M.J. andMoUer, M. (1997a) Synthesis and characterization of semifluorinated polymers via group transfer polymerization J. Journal of Fluorine Chemistry, 82,119-124. [Pg.736]

Schadt K, Kerscher B, Thomann R, Miilhaupt R (2013) Structured semifluorinated polymer ionic liquids for metal nanoparticle preparation and dispersion in iluorous compartments. Macromolecules 46 4799-4804... [Pg.444]

See other pages where Semifluorinated polymers is mentioned: [Pg.117]    [Pg.8]    [Pg.14]    [Pg.27]    [Pg.9344]    [Pg.44]    [Pg.45]    [Pg.45]    [Pg.50]    [Pg.54]    [Pg.236]    [Pg.237]    [Pg.257]    [Pg.259]    [Pg.261]    [Pg.263]    [Pg.265]    [Pg.267]    [Pg.281]    [Pg.512]   
See also in sourсe #XX -- [ Pg.7 ]

See also in sourсe #XX -- [ Pg.44 , Pg.45 , Pg.46 , Pg.47 , Pg.48 , Pg.49 , Pg.50 , Pg.51 , Pg.52 , Pg.53 ]



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