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SCD sulfur chemiluminescence

Figure 14.2 Schematic diagram of the cliromatographic system used for the analysis of low concenti ations of sulfur compounds in ethene and propene VI, injection valve V2, column switcliing valve SL, sample loop R, restriction to replace the column SCD, sulfur chemiluminescence detector. Figure 14.2 Schematic diagram of the cliromatographic system used for the analysis of low concenti ations of sulfur compounds in ethene and propene VI, injection valve V2, column switcliing valve SL, sample loop R, restriction to replace the column SCD, sulfur chemiluminescence detector.
SCD Sulfur chemiluminescence detector (flame and flameless) Ozone-induced CL... [Pg.177]

SCD, sulfur chemiluminescence detector PFPD, pulsed flame photometric detector FPD, flame photometric detector. [Pg.551]

Many sophisticated analytical techniques have been used to deal with these complex mixtures.5,45,46 A detailed description is not possible here, but it can be noted that GLC, often coupled with mass spectrometry (MS), is a major workhorse. Several other GLC detectors are available for use with sulfur compounds including flame photometer detector (FPD), sulfur chemiluminescence detector (SCD), and atomic emission detector (AED).47 Multidimensional GLC (MDGC) with SCD detection has been used48 as has HPLC.49 In some cases, sniffer ports are provided for the human nose on GLC equipment. [Pg.683]

The chemiluminescent reaction of SO with ozone is the basis of the sulfur chemiluminescence detector (SCD) [23] discussed later in this chapter,... [Pg.355]

The system described in the previous section has been extended with a sulfur chemiluminescence detector (SCD) for the detection of sulfur compounds (32). The separated fractions were thiols + sulfides + thiophenes (as one group), benzothio-phenes, dibenzothiophenes and benzonaphtho-thiophenes. These four groups have been subsequently injected on-line into and separated by the GC unit. Again, no overlap between these groups has been detected, as can be seen from Figure 14.20, in which the total sulfur compounds are shown and from Figure 14.21 in which the separated dibenzothiophenes fraction is presented. The lower limit of detection of this method proved to be 1 ppm (mg kg-1) sulfur per compound. [Pg.397]

An alternative to FPD in the sulfur mode is the sulfur chemiluminescence detector (SCD) (48). This detector works by forming sulfur monoxide in a reducing flame. Sulfur monoxide is detected by its chemiluminescent reaction with ozone. The SCD is at least one order of magnitude more sensitive than most FPDs. It provides a linear response with high selectivity and does not suffer considerably from quenching. [Pg.189]

Detectors commonly used in GC and specified in the USPP include FID, alkali FID (NPD, TD), BCD, and TCD. A description of these detectors, including their operational principles and relative performance, was presented in a previous volume of this encyclopedia. Various other useful detectors for GC include photoionization (PID), flame photometric (FPD), electrolytic conductivity (BLCD), redox (RCD) and sulfur chemiluminescence (SCD), and helium ionization (HID).[4 1 Table 1 summarizes some of the features of detectors used in GC. [Pg.469]

An attractive alternative for selective detection is sulfur chemiluminescence (SCD). In 1989 Benner and Stedman described a new ozone-based SCD. Owing to its high sensitivity, the great advantage of linear response vs. concentration of sulfur species, its wide linear dynamic range, high... [Pg.359]

ABSTRACT A novel measurement technique has been developed for the rapid determination of low levels of sulfur in hydrocarbon matrices. The technique employs low thermal mass gas chromatography (LTMGC) and a dual plasma sulfur chemiluminescence detector (DP-SCD). Highly sensitive total volatile sulfur measurement can be made in less than 30 s with detection limits in the 20-30 parts per billion range. Response is linear over at least three orders of magnitude sulfur with excellent repeatability. [Pg.164]

KEYWORDS sulfur, elemental, sulfur chemiluminescence detection (SCD), low thermal mass gas chromatography (LTMGC), dual plasma SCD... [Pg.164]

Other even more sjjccific detectors can also be coupled to GCxGC. Atomic emission detectors (AEDs), and more element-selective detectors, such as sulfur compound detectors (sulfur chemiluminescence detector, or SCD), have been reported in the oil characterization area [84,85]. In these detectors, the combustion of sulfur compounds by an energetic induced plasma produces sulfur oxides that further react to and produce light at a specific wavelength that... [Pg.36]


See other pages where SCD sulfur chemiluminescence is mentioned: [Pg.76]    [Pg.598]    [Pg.598]    [Pg.194]    [Pg.999]    [Pg.135]    [Pg.416]    [Pg.138]    [Pg.76]    [Pg.598]    [Pg.598]    [Pg.194]    [Pg.999]    [Pg.135]    [Pg.416]    [Pg.138]    [Pg.381]    [Pg.151]    [Pg.379]    [Pg.474]    [Pg.458]    [Pg.379]    [Pg.381]    [Pg.311]    [Pg.101]    [Pg.224]    [Pg.165]    [Pg.177]    [Pg.777]    [Pg.1059]    [Pg.80]    [Pg.354]    [Pg.683]    [Pg.550]   


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The Sulfur Chemiluminescence Detector (SCD)

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