Satellite spectra

It is possible that the complexes benzene- -HX can be described in a similar way, but in the absence of any observed non-rigid-rotor behaviour or a vibrational satellite spectrum, it is not possible to distinguish between a strictly C6v equilibrium geometry and one of the type observed for benzene- ClF. In either case, the vibrational wavefunctions will have C6v symmetry, however. 

Fig. 8. Collision-induced satellite spectrum of Naj around X = 5290 A, due to fluorescence originating from rotational levels populated by collision from the V = 6, / = 43 level in the state, which was excited by the X = 4880 A argon laser line. (From ref.

Fig. 3. Long range and one-bond carbon-13 satellite spectrum of a 5% w/w solution of ethanediol in D2O at 94°C. 16 transients were measured on a Varian Associates Unity 500 spectrometer using the sequence of fig. 1, with 2.5 s presaturation, a t value of 100 ms, spin lock pulses of 450 ps, no homospoil pulse, and no homodecoupling during acquisition.

The integrated intensity of the satellite spectrum is very close to that of the trapped electron spectrum. The former spectrum decays concomitantly with the latter either with photo-bleaching with the infrared... 

The existence of satellite lines has already been mentioned several times, for example, in the explanation of the photoelectron spectra of rare gases (see Fig. 2.4), and in the discussion of 2p photoionization in magnesium. In this section the satellite spectrum related to outer-shell photoionization in argon will be treated... 

The FISCI method will be considered in more detail for the 2Se manifold of 3s photoionization in argon, even though finer details of the satellite spectrum can be understood only if further electron correlations and spin-orbit effects are included (see below). In the FISCI approach, uncorrelated functions < >[ with single-particle orbitals provide the starting point. They are abbreviated to their characteristic electron orbital, i.e.,... 

Of course, the dominance of FISCI in the argon satellite spectrum at intermediate and high photon energies only provides a rough orientation. In general, electron... 

The experimental 5s XPS spectrum in Xe7,8 (Fig. 32a) looks quite similar to the 4p spectrum in Ba, suggesting that the 5 s level lies just below the 5 1 level structure, forming a well-defined 5 s1/2 quasi-particle excitation and giving considerable strength to a prominent satellite spectrum, mainly 5 p25 d94, 95. The basic process is again giant Coster-Kronig fluctuation of the core hole... 

The recent experimental core level spectrum by Cavell and Allison129 in Fig. 50 is very similar to that of N2 (Fig. 45), with a weak Is 3(1 jAr) satellite with 2% relative intensity at 7.2 eV above the main line, a strong 1 s 3(1 n 2 ri) satellite with 10% relative intensity at 12.2 eV, followed by a prominent discrete and continuous satellite spectrum at higher energies. The total relaxation shift is 16 eV, the MO HF ljs level lies well above the low-lying nn satellites and the limited range of the shake-up and shake-off spectrum shown in Fig. 50 only accounts for about one third of the relaxation shift (through Eq. (22)). 

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