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Ruthenium, tris -, dichloride

Tris(2,2 -bipyridine)ruthenium(II) dichloride (6H2O) [50525-27-4] M 748.6. Recrystd from water then from MeOH [Ikezawa et al. JAm Chem Soc 108 1589 1986]. [Pg.494]

Tokel NE, Bard AJ (1972) Electrogenerated chemiluminescence. IX. Electrochemistry and emission from systems containing tris(2,2 -bipyridine)ruthenium(II) dichloride. J Am Chem Soc 94 2862-2863... [Pg.103]

A comparison has been made of the structural parameters and hydrogen bonding in [Ru"Cl2L(HL)r and [Ru Cl2L(HL)] where HL = (226), and the crystal structure of tris (dimethylglyoxime)ruthenium(II) dichloride has been determined. ... [Pg.627]

Metal-catalyzed isomerization of unsymmetrical diallyl ethers is a unique route to synthesize allyl vinyl ethers for the Claisen rearrangement. In 1977, Reuter and Salomon reported that heating the diallyl ether 23 in the presence of a catalytic amount of tris(triphenylphosphine)ruthenium(II) dichloride resulted in the... [Pg.15]

Figure 14. Sonoelectrochemiluminescence of tris-bipyridine ruthenium (II) dichloride ((Ru(bpy)3]Cl2) at platinum in aqueous oxalate solution. Potentiostatic control +1.2 V (SCE). (a) Background zero line, (b) Sonoluminescence from 40-kHz probe, no applied potential, (c) Electrochemiluminescence at +1.2 V (SCE), silent, (d) Sonoelec-trochemiluminescence at 1.2 V (SCE) and ultrasound (40-kHz probe). (Taken from reference 209). Figure 14. Sonoelectrochemiluminescence of tris-bipyridine ruthenium (II) dichloride ((Ru(bpy)3]Cl2) at platinum in aqueous oxalate solution. Potentiostatic control +1.2 V (SCE). (a) Background zero line, (b) Sonoluminescence from 40-kHz probe, no applied potential, (c) Electrochemiluminescence at +1.2 V (SCE), silent, (d) Sonoelec-trochemiluminescence at 1.2 V (SCE) and ultrasound (40-kHz probe). (Taken from reference 209).
HYDROGENATION, TRANSFER Hexafluoroantimonic acid. Palladium black. Tris-(aquo)hexa-M-acetate-M3 -oxotriruthenium(IlI,IlI,Ill) acetate. Tris(triphenylphos-phine)chlororhodium. Tris(triphenylphosphine)ruthenium(Il) dichloride. HYDROLYSIS, ESTERS Quinoline-Acetic acid. [Pg.781]

Fig. 13.2 Structure of an optode for the detection of molecular oxygen and carbon dioxide. Fluorophore I (O2) tris(2,2 -bipyridyl)ruthenium(ll) dichloride fluorophore II (CO2) l-hydroxypyrene-3,6,8-trisulfonate. Adapted from Baldini et al. [4] with permission from Springer. Fig. 13.2 Structure of an optode for the detection of molecular oxygen and carbon dioxide. Fluorophore I (O2) tris(2,2 -bipyridyl)ruthenium(ll) dichloride fluorophore II (CO2) l-hydroxypyrene-3,6,8-trisulfonate. Adapted from Baldini et al. [4] with permission from Springer.
Ruthenlum(II)-tri (triphenylphosphine) dlchloride [tris(triphenylpho phine)ruthenium(II) dichloride)... [Pg.707]

A related iridium complex has been used for the decarbo)grlative radical allylation of aminoacids and phenylacetic acids that occurs smoothly at room temperature in the presence of Pd(PPh3)4, irradiating by white LEDs. The proposed scheme (Scheme 6) is based on dual catalysis. Ruthenium tris(phenanthroline) dichloride has been used for visible light catalysis of the mild amidation of ketoacids by ort/zo-substituted anilines using ozygen as terminal oxidant (Scheme 7) ... [Pg.8]

The efficiencies of these systems are, however, not high, mainly because of the small quantum yield for charge injection. High efficiency was reported in the sensitization of n-TiOj using surface-adsorbed tris(2,2 -bipyridyl-4,4 -dicarboxylate)ruthenium(II)-dichloride as a sensitizer The photocurrent of 36 pA cm" was obtained by monochromatic light flux of 0.22 mW cm at 460 nm, corresponding to a conversion efficiency of 44 %. [Pg.210]

Production of Hj Nd by the photodecomposition of water solves the problem of conversion and. storage of. solar energy. The tris(bipyri-dine)ruthenium(II) dichloride complex Ru(bPy),]Cb can theoretically pho-... [Pg.56]

See other pages where Ruthenium, tris -, dichloride is mentioned: [Pg.973]    [Pg.247]    [Pg.293]    [Pg.99]    [Pg.115]    [Pg.977]    [Pg.978]    [Pg.463]    [Pg.127]    [Pg.209]    [Pg.59]    [Pg.235]    [Pg.115]    [Pg.338]    [Pg.339]    [Pg.197]    [Pg.289]    [Pg.338]    [Pg.181]    [Pg.127]    [Pg.175]    [Pg.211]    [Pg.298]   
See also in sourсe #XX -- [ Pg.115 ]

See also in sourсe #XX -- [ Pg.115 ]



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Ruthenium dichloride

Ruthenium tris

Ruthenium tris -, dichloride, hexahydrate

Tris dichloride

Tris(2,2,-bipyridine)ruthenium(II) dichloride Hexahydrate

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