Ruthenium electrical resistivity

Fig. 9.5. The electrical resistance R(T) for some typical thermometers. A-B denotes Allen-Bradley carbon resistor. Speer is a carbon resistor. CG is carbon-in-glass. CX 1050 is a Cernox and RX 202A is a ruthenium oxide from LakeShore. Ge 100 and Ge 1000 are Cryocal germanium thermometers [45]. 

Figure 4-5 The composition dependence of the electrical resistance of ruthenium oxide/glass resistors.

From the macro point of view, it is possible to control electrical resistance by changing the volume ratio of the ruthenium oxide and glass, as shown in Figure 4-5 [9]. Various models have been suggested for the... 

Ruthenium see also Elements electrical resistivity, 12-39 to 40 electron configuration, 1-18 to 19 heat capacity, 4-135 history, occurrence, uses, 4-1 to 42 ionization energy, 10-203 to 205 isotopes and their properties, 11-56 to 253 magnetic susceptibility, 4-142 to 147 molten, density, 4-139 to 141 physical properties, 4-133 to 134 thermal properties, 12-201 to 202 vapor pressure, 6-61 to 90 vapor pressure, high temperature, 4-136 to 137... 

Ruthenium silicides are of interest for manufacturing high-density integrated circuit devices since they have a very good lattice match with silicon and relatively low electrical resistance. Other potential applications are in light emitting diodes and thermoelectrical devices. 

Ruthenium is a hard, white metal and has four crystal modifications. It does not tarnish at room temperatures, but oxidizes explosively. It is attacked by halogens, hydroxides, etc. Ruthenium can be plated by electrodeposition or by thermal decomposition methods. The metal is one of the most effective hardeners for platinum and palladium, and is alloyed with these metals to make electrical contacts for severe wear resistance. A ruthenium-molybdenum alloy is said to be... 

Ruthenium alloyed to platinum, palladium, titanium and molybdenum have many apphcations. It is an effective hardening element for platinum and palladium. Such alloys have high resistance to corrosion and oxidation and are used to make electrical contacts for resistance to severe wear. Ruthenium-palladium alloys are used in jewelry, decorations, and dental work. Addition of 0.1% ruthenium markedly improves corrosion resistance of titanium. Ruthenium alloys make tips for fountain pen nibs, instrument pivots, and electrical goods. Ruthenium catalysts are used in selective hydrogenation of carbonyl groups to convert aldehydes and ketones to alcohols. 

The functional phase in thick-film resistors is a mixture of electrically conducting (or semiconducting) ceramic powders such as ruthenium dioxide (RUO2), bismuth ruthenate (Bi2Ru207), lead ruthenate (Pb2Ru206), and Ag-Pd-PdO mixtures for use in air-fired pastes and tantalum nitride (TaN) for nitrogen-fired pastes. The resistance of thick-film resistors is specified in terms of sheet resistance, which has units of ohms/square (Q/D). 

Rhodium alloys find most of their applications in electrical contacts for radio frequency circuits, precision potentiometers, and spark plug electrodes. The trend is toward lower usage in electronics, mainly because of price. Osmium has minor uses in electrical equipment, mainly in contacts. Ruthenium is used in electrical contacts and high-voltage relays up to 500°C because even RuO c is conductive. A ruthenate thick-film paste is used for printed circuit resistance elements. The ruthenate is converted to RuOa, which has very low resistance drift, 0.10%. 

Ruthenium is used as an alloy component since it increases the hardness of platinum or palladium without lowering the corrosion resistance [4,5]. The alloy containing 30-70% ruthenium is used as an electric contact, the penpoint of a... 

Ruthenium is mainly used as the wear-resistant of platinum and palladimn in jewel, electrical connector alloy, hydrogenation catalyst, medicine apparatus, anticorrosion alloy, electroplating films, nitrogen fixed reagent and solar cell. Ruthenium oxide is used as coating on the titanium anode plate in the production of nitrogen using electrolysis. 

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