Electrodes ring-disk

Electrochemiluminescence quantum yields of 8—10% from 9,10-diphenylanthracene and 14—20% from the 9,10-diphenylanthracene anion—thianthrene cation combination have been reported using the rotating ring disk electrode technique (157,173). 

FIGURE 4-9 (a) Rotating disk and (b) ring-disk electrodes. 

W.J Albery and M. Hitchman, Ring-Disk Electrodes, Clarendon Press, Oxford, 1971. 

How can you use the rotating ring disk electrode for detecting short-lived intermediate species ... 

Rigid film approximation, 53 Rotating disk electrode, 111 Rotating ring disk electrode, 113 Ruthenium dioxide, 121... 

Data on the electrochemistry of the telluride ion in alkaline media are relatively limited. Mishra et al. [53] studied the oxidation of Te to Te° at solid electrodes, focusing on the intermediate step(s) of this process, and in particular, the possibility of detecting ditelluride Te via rotating ring disk electrode (RRDE) methodology. Oxidation beyond the elemental state to TeO and TeO was also studied using cyclic and hydrodynamic voltammetry. 

A rotating ring-disk electrode study. J Electrochem Soc 137 3438-3441... 

MiUer B, Menezes S, Heller A (1978) Anodic formation of semiconductive sulfide films at cadmium and bismuth Rotating ring-disk electrode studies. 1 Electroanal Chem 94 85-97... 

FIGURE 4.7 Rotating ring-disk electrode (1) disk electrode (current/p) (2) ring electrode (current 7j ). 

Both cell designs permit positioning of the second electrode downstream of the first working electrode (Fig. 11), which is known as the series configuration. This electrochemical transducer is used in the same manner as the classic ring-disk electrode. Products generated at the upstream electrode are detected (or collected) at the downstream electrode Selectivity is enhanced when the products of the upstream... 

Schmidt TJ, Grgur BN, Behm RJ, Markovic NM, Ross PN. 2000b. Bi adsorption on Pt(l 11) in perchloric acid solution A rotating ring-disk electrode and XPS smdy. Phys Chem Chem Phys 2 4379-4386. 

Johnson DC, Napp DT, Bruckenstein S. 1970. A ring-disk electrode study of the current/poten-tial behaviour of platinum in 1.0 M sulphuric and 0.1 M perchloric acids. Electrochim Acta 15 1493-1509. 

The ORR has been studied with a rotating ring-disk electrode (RRDE), which can provide theand the H2O2 yield P(H202) at around room temperamre. However, for improving the ORR activity, PEFCs should be operated at high temperature (> 80 °C). In this section, we demonstrate the temperature dependencies of ORR activity and P(H202) at pure Pt (both bulk and supported catalyst) and bulk Pt alloys (Pt-Ni, Pt-Co, and Pt-Fe). 

Paulus UA, Schmidt TJ, Gasteiger HA, Behm RJ. 2001. Oxygen reduction on a high-surface area Pt/Vulcan carbon catalyst A thin-film rotating ring-disk electrode study. J Electroanal Chem 495 134-145. 

Thin catalyst layers on a GC rotating disk electrode (RDE) or a rotating ring-disk electrode (RRDE) serve for studies of ORR kinetics. In order to separate the kinetic current from the measured current j, Schmidt and co-workers [Schmidt et al., 1998b] corrected the latter for the influence of oxygen diffusion in the aqueous electrolyte and in the polymer film using the foUowing equation ... 

Hsueh KL, Gonzalez ER, Srinivasan S. 1983. Electrolyte effects on oxygen reduction kinetics at platinum—A rotating-ring disk electrode analysis. Electrochim Acta 28 691-697. 

In the most common approach, a water-insoluble metaUoporphyrin is deposited on the surface of a rotating disk electrode (RDE) or on the disk of a rotating ring-disk electrode (RRDE Fig. 18.7a) as a film of poorly defined morphology, either by spontaneous adsorption from a solution of the catalyst in an organic solvent or by evaporation of an aliquot of such a solution onto the electrode. It is impossible to know the... 

Figure 18.7 (a) Rotating ring-disk electrode (RRDE left) and schematics of chemical... 

Rotating (ring-)disk electrode, 256, 260, 265, 318-320, 521, 648 Ruthenium electrocatalyst, 465-498... 

The rotating ring disk electrode can be used to study the products of the electrode reaction (Fig. 5.20). The products of the electrode reaction at the disk are carried by convective diffusion to the ring where they undergo a... 

Of considerable interest is the use of small isolated electrodes, in the form of strips or disks embedded in the wall, to measure local mass-transfer rates or rate fluctuations. Mass-transfer to spot electrodes on a rotating disk is represented by Eqs. (lOg-i) of Table VII. Analytical solutions in this case have to take account of curved streamlines. Despic et al. (Dlld) have proposed twin spot electrodes as a tool for kinetic studies, similar to the ring-disk electrode applications of disk and ring-disk electrodes for kinetic studies are discussed in several monographs (A3b, P4b). In fully developed channel or pipe flow, mass transfer to such electrodes is given by the following equation based on the Leveque model ... 

The iron complex (23) adsorbed on graphite electrode surfaces is an active catalyst for the electroreduction of both nitrite and nitric oxide to yield NH2OH and NH3, as demonstrated by rotating ring-disk electrode voltammetry experiments.341... 

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