Sodium rhodate

C37H24ClNa60i9P2RhS6, Rhodate(6-), trans-carbonylchlorobis(tris(3-sulfonatophenyl)-phosphine)-, sodium, 34 124... 

ClNa60i9P2RhS6C37H24, Rhodate(6-), trans-carbonylchlorobis(tris(3-sulfonatophenyl)-phosphine)-, sodium, 34 124 CI2B2N2C4H12, Diborane(4), 1,2-dichloro-1,2-bis(dimethylamino)-, 34 3 CI2CUN4O9C18H20, Copper(II), aquatris(2-pyri-dylmethyl)amine-, perchlorate, 34 135 Cl2Fe7N24Oi2Ci32Hi50 6H2O, Iron(II), hexa-kis cyanobis(3-salicylidenoaminopropyl)-methylamineiron(lll) -, chloride, hexahy-drate, 34 143... 

Tris(ethylenediamine)rhodium(III) chloride, first reported by Werner,1 was prepared by the reaction of sodium hexachloro-rhodate(III) dodecahydrate with ethylenediamine monohydrate. The reaction product, however, contained sodium chloride, which could not be removed by recrystallization,1 probably because of the formation of a double salt. J Jaeger2,8 prepared the compound from rhodium (III) chloride trihydrate and 50 % aqueous ethylenediamine. Gillard, Osborn, and Wilkinson4 carried out the reaction of rhodium(III) chloride... 

Sodium Rhodate, Na2Rh04.—If the gases evolved by the action of hydrochloric acid upon potassium chlorate are passed into a solution of a rhodium salt rendered alkaline with sodium hydroxide, the liquid assumes a yellowish red, then a red colour, and finally a slight green precipitate forms. The latter dissolves, yielding a solution of blue colour known as Claus s Blue, and containing sodium rhodate. 

Arylation reactions of aromatic ketimines were developed, and in many cases the products of the reaction were isolated after subsequent hydrolysis. Therefore, these arylations constitute an indirect method for the preparation of arylated aromatic ketones, the direct functionalizations of which are often more difficult. Thus, direct arylation of imine 42 with sodium tetraphenylborate catalyzed by [RhCl(cod)]2 afforded a mixture of mono- and diarylated benzophenone imines (44 and 45) (Scheme 9.16) [53]. The formation of the corresponding amine 46 clearly indicated that 42 also acted as a hydride acceptor in this transformation. Most likely, the reaction occurs via initial coordination by the benzophenone imine to a phenylrho-dium intermediate followed by orfho-rhodation to afford the five-membered rhoda-cyde intermediate 47 (Scheme 9.16). Subsequent reductive elimination generates the monophenylated product 44 and a rhodium hydride, which then reduces imine 42 in the presence of ammonium chloride as proton donor to regenerate the catalytically active speties. 

DCSA Persoft SK Plurafac LF 711 Plurafac LF 1300 Plurafac RA-20 Plurafac RA-30 Plurafac RA-40 Propetal 140 Rhodamox LO Rhodapex CO-433 Rhodapex CO-436 Rhodapex EST-30 Rhodasurf BC-630 Rhodat-erge BCC Sodium cocoamphoacetate Sodium nonoxynol-4 sulfate Sodium trideceth sulfate STEOL 4N STEOL CA-460 Teric G12A4 Teric LA4 Ufasan 35 Ufasan 65 Unitol ID 30 Zusolat 1005/85... 

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