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Resins perfluorinated

Chemical Properties. A combination of excellent chemical and mechanical properties at elevated temperatures result in high performance service in the chemical processing industry. Teflon PEA resins have been exposed to a variety of organic and inorganic compounds commonly encountered in chemical service (26). They are not attacked by inorganic acids, bases, halogens, metal salt solutions, organic acids, and anhydrides. Aromatic and ahphatic hydrocarbons, alcohols, aldehydes, ketones, ethers, amines, esters, chlorinated compounds, and other polymer solvents have Httle effect. However, like other perfluorinated polymers,they react with alkah metals and elemental fluorine. [Pg.375]

Another type of soHd supetacid is based on perfluorinated resin sulfonic acid such as the acid form of Du Font s Nafion resin, a copolymer of a perfluorinated epoxide and vinylsulfonic acid or soHd, high molecular weight petfluotoalkanesulfonic acids such as petfluotodecanesulfonic acid, CF2(CF2)qS02H. Such sohd catalysts have been found efficient in many alkylations of aromatic hydrocarbons (225) and other Friedel-Crafts reactions (226). [Pg.565]

Nafion-H (144), a perfluorinated resin-sulfonic acid, is an efficient Bronsted-acid catalyst which has two advantages it requires only catalytic amounts since it forms reversible complexes, and it avoids the destruction and separation of the catalyst upon completion of the reaction [94], Thus in the presence of Nafion-H, 1,4-benzoquinone and isoprene give the Diels-Alder adduct in 80% yield at 25 °C, and 1,3-cyclohexadiene reacts with acrolein at 25 °C affording 88 % of cycloadduct after 40 h, while the uncatalyzed reactions give very low yields after boiling for 1 h or at 100 °C for 3.5 h respectively [95], Other examples are given in Table 4.24. In the acid-catalyzed reactions that use highly reactive dienes such as isoprene and 2,3-dimethylbutadiene, polymerization of alkenes usually occurs with Nafion-H, no polymerization was observed. [Pg.189]

Furthermore, the same sol-gel matrices have been used in a system where acid and base catalysis occur in the same pot without quenching either catalyst [29]. In this case, the acids were either entrapped Nafion (perfluorinated resin sulfonic super acid, a3) or entrapped molybdic acid (M03-Si02, a2), while the bases were two ORMOSILs (organically modified silica sol-gel materials), one with H2N (CH2)2NH(CH2)3 groups (bi) and the other guanidine base residues (b2) (Scheme 5.12). [Pg.144]

Nafion, a perfluorinated sulfonated polymer, is a typical example of an ion-exchangeable resin with high promise as a catalyst support. Its properties are significantly different from those of common polymers (stability towards strong bases, and strong oxidizing and reducing acids and thermal stability up to at least 120 °C if the counter ion is a proton, and up to 200-235 °C if it is a... [Pg.450]

Nafion-H, a perfluorinated sulfonic acid resin, is another strongly acidic solid that has been explored as alkylation catalyst. Rprvik et al. (204) examined unsupported Nafion-H with a nominal surface area of 0.2 m2/g (surface area of a swellable polymer is difficult to define) in isobutane/2-butene alkylation at 353 K and compared it with a CeY zeolite. The zeolite gave a better alkylate and higher conversion than Nafion-H, which produced significant amounts of octenes and heavy-end products. The low surface area of the resin and questions about the accessibility of the sulfonic acid groups probably make the comparison inadequate. [Pg.291]

Proceeding on the same line, Hagerdal et al. reported that perfluorinated resin supported sulfonic sites (NATION 501) can hydrolyze disaccharides [25]. In particular, these authors studied the effect of the addition of sodium chloride in the hydrolysis of cellobiose, a subunit of cellulose much more resistant to hydrolysis than sucrose. They observed that the presence of sodium chloride in water dramatically increased the conversion of cellobiose. Indeed, in the presence of 10 wt% of sodium chloride, 80% of cellobiose was converted at 95°C after 6 h. For comparison, when 1% of sodium chloride was added, only 50% of cellobiose was hydrolyzed. It should be noted that without addition of sodium chloride only 15% conversion was achieved, thus pushing forward the key role of sodium chloride on the reaction rate. Effect of salt on the reaction rate was attributed to a change of the pH caused by the release of proton in the reaction medium (due to an exchange of the supported proton by sodium). [Pg.66]

Substantial progress has been made to carry out alkylation in the gas phase over solid superacid catalysts. Nafion-H, a perfluorinated resin-sulfonic acid, for example, catalyzes the methylation of benzene and methylbenzenes with methyl alcohol under relatively mild conditions. The reaction shows low substrate selectivity.203... [Pg.246]

Chromium(III) and cerium(IV) impregnated Nafion K (a perfluorinated sulfonic acid resin) were used as catalysts f°r the themoselective oxidation of a variety of alcohols using TBHP or NaBr03 as tlie oxy9en donor A e.g. [Pg.46]

Liquid acids such as HC1 or H2SO4 have been found to be efficient catalysts. However, the catalysts produce intermediate compounds having methylene-amino bonds, such as N-benzyl compound, C6H5N(COOCH3)(CH2C6H5NHCOOCH3) [1], These intermediates do not produce isocyanates and have a harmful influence on the next thermal decomposition step. Since these compounds must be catalytically transformed to desired MDU, the condensation reaction has to be carried out in two steps to use the best characteristics of each catalyst. Solid acid catalysts such as a perfluorinated ion-exchange resin (Nafion) have received limited attention as catalysts for the condensation reaction [2]. [Pg.495]

Polymeric resin sulfonic acids including sulfonic acid resins complexed with Lewis acids and perfluorinated polymer resin acids (Nafion-H and Nafion-silica nanocomposites). [Pg.10]

The following subchapters cover various solid superacids, including perfluorinated sulfonic acid resins (Nafion resins). Furthermore, in the past, various attempts have been made to obtain solid superacids by either (a) enhancing the intrinsic acidity of a solid acid by treatment with a suitable co-acid or (b) physically or chemically binding a liquid superacid to an otherwise inert surface. We will briefly review some of these attempts because most of these catalysts rapidly lose activity and need to be regenerated. [Pg.64]

A.2.2. Perfluorinated Polymer Resin Acids. A convenient solid perfluori-... [Pg.66]

The new Nafion-nanocomposite catalysts are produced by DuPont and marketed as Nation SAC materials with Nation loading between 10% and 20%. Additional information for perfluorinated sulfonic acid resin nanocomposites including characterization by a variety of physical and chemical methods can be found in a recent... [Pg.68]

Cation exchange resins, polymeric perfluorinated resinsulfonic acids... [Pg.69]

All of these species (XIV, XV) have been for the most part applied towards function in the olefin polymerization arena use of these novel anions for the stabilization of other electrophilic species remains to be explored. Recently, the imidazolide anion XVI, as well as the perfluorinated tetraaryl borate derived from the diborane IX of Chart 2, have been used to stabilize iodonium cations.222 These cations are used as photoinitiators for cationic polymerization of epoxy resins in photolithography applications. While use of the [B(C6F5)4] led to a breakthrough in this area of research,223 higher activities are observed for more WCAs. [Pg.54]


See other pages where Resins perfluorinated is mentioned: [Pg.99]    [Pg.333]    [Pg.494]    [Pg.2409]    [Pg.462]    [Pg.332]    [Pg.1457]    [Pg.97]    [Pg.197]    [Pg.682]    [Pg.46]    [Pg.301]    [Pg.97]    [Pg.197]    [Pg.140]    [Pg.819]    [Pg.666]    [Pg.57]    [Pg.145]    [Pg.333]    [Pg.666]    [Pg.956]    [Pg.497]    [Pg.87]    [Pg.66]    [Pg.40]    [Pg.158]   
See also in sourсe #XX -- [ Pg.195 , Pg.302 , Pg.305 , Pg.306 ]




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Perfluorinated

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