Refrigeration mixed refrigerant

Mix together in a 250 ml. flask carrying a reflux condenser and a calcium chloride drying tube 25 g. (32 ml.) of freshly-distilled acetaldehyde with a solution of 59-5 g. of dry, powdered malonic acid (Section 111,157) in 67 g. (68-5 ml.) of dry pyridine to which 0-5 ml. of piperidine has been added. Leave in an ice chest or refrigerator for 24 hours. Warm the mixture on a steam bath until the evolution of carbon dioxide ceases. Cool in ice, add 60 ml. of 1 1 sulphuric acid (by volume) and leave in the ice bath for 3-4 hours. Collect the crude crotonic acid (ca. 27 g.) which has separated by suction filtration. Extract the mother liquor with three 25 ml. portions of ether, dry the ethereal extract, and evaporate the ether the residual crude acid weighs 6 g. Recrystallise from light petroleum, b.p. 60-80° the yield of erude crotonic acid, m.p. 72°, is 20 g. 

Veratronitrile, Dissolve 83 g. of veratraldehyde in 200 ml. of warm rectified spirit in a 1 litre bolt-head flask, and add a warm solution of 42 g. of hydroxylamine hydrochloride in 50 ml. of water. Mix thoroughly and run in a solution of 30 g. of sodium hydroxide in 40 ml. of water. Allow the mixture to stand for 2-5 hours, add 250 g. of crushed ice, and saturate the solution with carbon dioxide. The aldoxime separates as an oil allow the mixture to stand for 12-24 hours in an ice chest or refrigerator when the oil will sohdify. Filter off the crystalline aldoxime at the pump, wash well with cold water, and dry in the air upon filter paper. The yield of veratraldoxime is 88 g. 

Dry Ice. Refrigeration of foodstuffs, especially ice cream, meat products, and frozen foods, is the principal use for soHd carbon dioxide. Dry ice is especially useful for chilling ice cream products because it can be easily sawed into thin slabs and leaves no Hquid residue upon evaporation. Cmshed dry ice may be mixed directly with other products without contaminating them and is widely used in the processing of substances that must be kept cold. Dry ice is mixed with molded substances that must be kept cold. For example, dry ice is mixed with molded mbber articles in a tumbling dmm to chill them sufficiently so that the thin flash or rind becomes brittle and breaks off. It is also used to chill golf-ball centers before winding. 

Fig. 3. Propane precooled mixed refrigerant process for natural gas Hquefaction.

The dephlegmator process recovers a substantially higher purity C2+ hydrocarbon product with 50—75% lower methane content than the conventional partial condensation process. The C2+ product from the cryogenic separation process can be compressed and further separated in a de-ethanizer column to provide a high purity C3+ (LPG) product and a mixed ethylene—ethane product with 10—15% methane. Additional refrigeration for the deethanization process can be provided by a package Freon, propane or propylene refrigeration system. 

The mixed refrigerant cwcle was developed to meet the need for hq-uefying large quantities of natural gas to minimize transportation costs of this fuel. This cycle resembles the classic cascade cycle in principle and may best be understood by referring to that cycle. In the latter, the natural gas stream after purification is cooled successively by vaporization of propane, ethylene, and methane. Each refrigerant may be vaporized at two or three pressure levels to increase the natural gas coohng efficiency, but at a cost of considerable increased process complexity. 

The mixed refrigerant cycle is a variation of the cascade cycle and involves the circulation of a single multicoiTmonent refrigerant stream. The simplification of the compression and heat exchange services in such a cycle can offer potential for reduced capital expenditure over the conventional cascade cycle. 

FIG. 11-116 Propane precooled mixed-refrigerant cycle cooling curve for natural gas. 

Ward reported power consumption for a plant using the mixed-refrigerant cycle. Compressor power was 9,460 kw for an LNG production rate of 28,550 m /hr. This converts to 3.37 kw-hr/lb-mole of liquid. The minimum work for a feed-gas pressure of 37 atm, an assumed feed-gas temperature of 80°F, and an assumed heat-sink temperature of 80°F = 1.09 kw-hr/lb-mole of liquid. This gives an efficiency of 32.4%. 

The total plant or train main process bottleneck will probably be identified by the licensor, such as the gasifier for a coal gasification train, the main exchanger for a mixed refrigerant LNG plant train, or the cracked gas compressors for an olefin plant. First and foremost, be sure that the licensor has not made the utility area a bottleneck. This can never be allowed since overloaded utilities could repeatedly shut the entire complex down on a crash basis, adversely impacting economics. 

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