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Reflection interference system

The basis of surface enhanced optical absorption is the so-called "anomalous absorption". To observe anomalous absorption an absorbing colloid or colloid layer is positioned in a defined distance to a metal mirror and illuminated from the colloid side. At a certain distance of the colloid or absorbing layer to the mirror the incident fields has the same phase as the electromagnetic field that is reflected by the mirror at the position of the absorbing colloid particle (or colloid particle layer). The set-up is described as a reflection interference system, which feedback mechanism strongly enhances the absorption coefficient of the absorbing colloid (layer). [Pg.166]

Devices that use uricase in a dry reagent format to measure uric acid have also been described. For example, a multilayer film system employs uricase and peroxidase separated by a semipermeable membrane from a leuco dye that is oxidized to form a colored product. A ceUulose matrix pad system employs uricase, peroxidase, and MBTH as oxygen acceptor the system employs a diluted plasma sample, which helps to reduce interferences, although ascorbic acid was shown to be a significant interferant. A third system incorporates separation of plasma from red cells and uricase, peroxidase, and a substituted phenol to measure uric acid. AH three systems employ a reflectance meter system to facilitate accurate and precise quantitation of the color change. [Pg.808]

Multilayer interference systems are ideally suited as reflection coatings, for the fully reflecting and the partially transmitting mirrors of lasers. Because of negligible absorption, reflection values of approximately 100% are possible. Such reflectors give minimum attenuation of laser emission. They can be made of ZnS/ThF4, TiCVSiC, / and of some other oxide combinations. [Pg.463]

The optical anisotropy of cokes gives rise to a characteristic pattern of extinction contours when a polished surface is examined by polarized light microscopy using crossed polars, or reflection interference colours if the polars are parallel and a half wave plate is inserted into the optical system (, 12) ... [Pg.5]

From the point of view of having a well-defined system, an isolated vesicle freely floating in solution is almost perfect. For interesting applications or a higher level in complexity, interaction with other objects can be considered. The simplest case corresponds to adhesion to a rigid substrate [43]. For this case, a comprehensive set of experimental data can be obtained using reflection interference microscopy... [Pg.78]

The advent of lasers allowed optical interferometry to become a useful and accurate technique to determine surface motion in shocked materials. The two most commonly used interferometric systems are the VISAR (Barker and Hollenbach, 1972) and the Fabry-Perot velocity interferometer (Johnson and Burgess, 1968 Durand et al., 1977). Both systems produce interference fringe shifts which are proportional to the Doppler shift of the laser light reflected from the moving specimen surface. Both can accommodate a speci-... [Pg.56]

When an electron scatters from an atom, its phase is changed so that the reflected wave is not in phase with the incoming wave. This changes the interference pattern and hence the apparent distance between the two atoms. Knowledge of this phase shift is the key to getting precise bond lengths from SEXAFS. Phase shifts depend mainly on which atoms are involved, not on their detailed chemical environment, and should therefore be transferable from a known system to unknown systems. The phase shifts may be obtained ftom theoretical calculations, and there are published tabulations, but practically it is desirable to check the phase shifts using... [Pg.229]

The construction of a TXRF system, including X-ray source, energy-dispersive detector and pulse-processing electronics, is similar to that of conventional XRF. The geometrical arrangement must also enable total reflection of a monochromatic primary beam. The totally reflected beam interferes with the incident primary beam. This interference causes the formation of standing waves above the surface of a homogeneous sample, as depicted in Fig. 4.1, or within a multiple-layered sample. Part of the primary beam fades away in an evanescent wave field in the bulk or substrate [4.28],... [Pg.184]

An important consideration for the direct physical measurement of adhesion via pull-off measurements is the influence of the precise direction of the applied force. In AFM the cantilever does not usually lie parallel to the surface, due to the risk that another part of the cantilever chip or chip holder will make contact with the surface before the tip. Another problem relates to the fact that the spot size in the optical beam deflection method is usually larger than the width of the lever. This can result in an interference effect between the reflection from the sample and the reflection from the cantilever. This is reduced if the cantilever and sample are not parallel. Most commercial AFM systems use an angle in the range of 10°-15° between the sample and the cantilever. Depending on this angle and the extent to which the cantilever is bent away from its equilibrium position, there can be a significant fraction of unintentional lateral forces applied to the contact. [Pg.30]

The interference term is thus of the form of Eq. (4), where in the present case 8s reflects the molecular as well as the environment properties. Within our occupation space formalism, it is given as a simple analytical function of system parameters, and its physical content is explicit. In the isolated molecule limit, where pure dephasing vanishes, Eq. (58) reduces to... [Pg.180]


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Reflective systems

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