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Reaction mechanisms qualitative models

Qualitative models of reactivity and quantum mechanical calculations of reaction paths both indicate an angular approach of the attacking nucleophile to the first-row sp -hybridized electrophilic centers M at intermediate and reactive distances, 29. The geometry of 29 is also characteristic for the case of nucleophilic addition to electron-deficient centers of main-group 12 and 13 elements. By contrast, a linear arrangement 30 of making and breaking bonds is required for sp -hybridized first-row centers (C, N, O)... [Pg.191]

To gain an insight into the likely hydrolytic behavior of sulfated simple sugars and polysaccharides, Brimacombe, Foster, Hancock, Overend, and Stacey carried out a rigorous set of experiments with the cyclic sulfates of cyclohexane cis-and trims-1,2-diol as model compounds. The results were interpreted on the reasonable assumption that, in all cases, the cyclic sulfates initially afford a diol monosulfate. Examples of both S-0 and C-0 bond cleavage were encountered. A qualitative reaction mechanism was proposed for use as a working hypothesis for the hydrolysis of sugar sulfates. [Pg.16]

The period 1930-1980s may be the golden age for the growth of qualitative theories and conceptual models. As is well known, the frontier molecular orbital theory [1-3], Woodward-Hoffmann rules [4, 5], and the resonance theory [6] have equipped chemists well for rationalizing and predicting pericyclic reaction mechanisms or molecular properties with fundamental concepts such as orbital symmetry and hybridization. Remarkable advances in aeative synthesis and fine characterization during recent years appeal for new conceptual models. [Pg.221]

Despite of the common reaction mechanism, peroxo complexes exhibit very different reactivities - as shown by the calculated activation energies -depending on the particular structure (nature of the metal center, peroxo or hydroperoxo functionalities, type and number of ligands). We proposed a model [72, 80] that is able to qualitatively rationalize differences in the epoxidation activities of a series of structurally similar TM peroxo compounds CH3Re(02)20-L with various Lewis base ligands L. In this model the calculated activation barriers of direct oxygen transfer from a peroxo group... [Pg.293]

In many other cases it is not at all clear that these exothermic reactions are operated in such a way that the system can remain isothermal. Self-heating and hence thermal feedback routes can be expected to have a strong autocatalytic effect on the reaction, perhaps in addition to chemical mechanisms. Recent modelling invoking cellular automata (Jaeger et al. 1985) has been to some extent successful at matching qualitatively many of the rather exotic responses which have been observed experimentally. [Pg.331]

Kinetics Third The dynamic nature of chemistry becomes fully evident through kinetics. Our approach shows how insight and model building are critical to the indentification of reaction mechanisms. The full chapter on kinetics follows coverage of equilibrium however, qualitative kinetic arguments are used early to develop an understanding of equilibrium, and the full treatment can be used anywhere in the sequence. [Pg.24]

RO, Fig. 3d) (2) higher-frequency, smaller amplitude, quasi-harmonic oscillations (QHO, Fig. 3a) and (3) double-frequency oscillations containing variable numbers of each of the two previous types. By far the most familiar feature of the BZ reaction, the relaxation oscillations of type 1 were explained by Field, Koros, and Noyes in their pioneering study of the detailed BZ reaction mechanism.15 Much less well known experimentally are the quasiharmonic oscillations of type 2,4,6 although they are more easily analyzed mathematically. The double frequency mode, first reported by Vavilin et al., 4 has been studied also by the present author and co-workers,6 who explained the phenomenon qualitatively on the basis of the Field-Noyes models of the BZ reaction. [Pg.206]

The above data have been rationalized in terms of the mechanisms shown in equation 214, and taken as indicating that reaction 211 proceeds via rate-determining electron transfer (ET), while in reactions 212 and 213 the rate-determining step shifts to recombination (RC) because in reaction 213 the RC-step becomes slower for the more hindered ketone. The small p = 0.27 value in reaction 211 also means that the extent of the geometrical changes is negligible in the TS of this reaction. These qualitative interpretations of the 14C KIE have not been supported by model calculations as has been done similarly in the reactions of ketones with SBH and LAH. The 14CH3Li-carbon-14 KIE have not been studied in reactions 211-213. The inverse 14C KIE is expected in... [Pg.1026]

This approach was very popular in former times when it was impossible to apply HF, DFT, or correlated ab initio methods to systems of more than a few atoms, so that phosphines were almost always modeled as PH3 (see Figures 10.5 and 10.7). In many cases, where the aim of the calculations was to understand qualitative aspects of reaction mechanisms, this type of truncation is perfectly acceptable and indeed offers some benefits beyond the lower computational expense. For example, it facilitates analysis, especially when the truncated system has symmetry absent in the full molecule. Also, it serves to remind the computational chemist that he or she is always studying a model, rather than the real system solvent is not present, and the level of theory used does not give exact results. It is sometimes possible to forget this when modeling the full system. [Pg.491]

The qualitative features of the r( pco) curve of Fig. 1 are the same for all types of platinum metal surfaces and will serve as a guide for exploring the mechanisms of kinetic oscillations occurring with this reaction. The shape of this curve can be modeled quite easily on the basis of the underlying reaction mechanism (8, 25). These equations are nonlinear in nature and can, for example, describe hysteresis effects observed in the transition region between high and low reactivity, but they will not produce sustained temporal oscillations. The latter require additional processes for which numerous suggestions and speculations can be found in the literature (S). [Pg.218]

As already mentioned, also for the other oxygenated Cl compounds, i.e. formaldehyde [118, 138-147] and methanol [148-154], as well as for larger organic molecules, dynamic instabilities are reported. Many of them are compiled in Ref. [154], for formaldehyde oxidation on Rh and Pt [147] and methanol oxidation on Pt [155] the oscillations could be clearly identified as HN-NDR type oscillations. However, in view of the number of reaction steps involved in these oxidation reactions and of the possible complexity of the interaction of the supporting electrolyte with the dynamics even in the much simpler formic acid oxidation, it is not astonishing that any quantitative considerations should still be missing. There are some attempts to qualitatively explain the observed phenomena with reaction mechanisms that go beyond the simple dual-path model described above. However, at the time being, they are quite speculative. Therefore I shall not discuss them in more detail in this article. A summary of these works can be found in [156],... [Pg.142]

With an E° value of —0.75 V, entry no. 19 of Table 17, reaction between alkyl halides and alkyllithium compounds, represents a strongly exergonic electron-transfer reaction which is expected to proceed at a diffusion-controlled tate. Experimental rate constants are not available, but such reactions are qualitatively known to be very fast. As we proceed to entry no. 21, two model cases of the nucleophilic displacement mechanism, it can first be noted that the nosylate/[nosylate]- couple is electrochemically reversible the radical anion can be generated cathodically and is easily detected by esr spectroscopy (Maki and Geske, 1961). Hence its E° = —0.61 V is a reasonably accurate value. E° (PhS /PhS-) is known with considerably less accuracy since it refers to an electrochemically irreversible process (Dessy et al., 1966). The calculated rate constant is therefore subject to considerable uncertainty and it cannot at present be decided whether the Marcus theory is compatible with this type of electron-transfer step. In the absence of quantitative experimental data, the same applies to entry no. 22 of Table 17. For the PhS-/BuBr reaction we again suffer from the inaccuracy of E° (PhS /PhS-) what can be concluded is that for an electron-transfer step to be feasible the higher E° value (—0.74 V) should be the preferred one. The reality of an electron-transfer mechanism has certainly been strongly disputed, however (Kornblum, 1975). [Pg.171]

The chemistry involved in the formation of mesoporous silica thin films is qualitatively well understood. However, specific reaction mechanisms of the individual steps are still debated. In addition, owing to the complexity of the sol-gel reaction pathways and cooperative self-assembly, full kinetic models have not been developed. From the time of mixing, hydrolysis reactions, condensation reactions, protonation and deprotonation, dynamic exchange with solution nucleophiles, complexation with solution ions and surfactants, and self-assembly, all occur in parallel and are discussed here. Although the sol-gel reactions involved may be acid or base catalyzed, mesoporous silica film formation is carried out under acidic conditions, as silica species are metastable and the relative rates of hydrolysis and condensation reactions lead to interconnected structures as opposed to the stable sols produced at higher pH. Silicon alkoxides are the primary silica source (tetramethyl orthosilicate, tetraethyl orthosilicate, tetrapropyl orthosilicate, etc.) and are abbreviated TMOS, TEOS, and TPOS, respectively. Starting from the alkoxide, Si(OR)4, in ROH and H2O solution, some of the general reactions are ... [Pg.1589]

J. Phys. Chem. A. 108 (2004) 6017 Chem. Eur. J. 9 (2003) 4540]. This chapter outlines a guide to the qualitative use of the model by discussing a variety of applications, to radical reactions, reactions of electrophiles and nucleophiles, cycloadditions, bond activation by transition metal catalysts, new reaction mechanisms, photochemical reactions, and so on. [Pg.635]

Quantitative calculations of the CIDNP effect can be performed as described in Section II.B.5. One has to set up the nuclear spin system of the intermediate radical pair or biradical, choose a diffusional model, compute reaction probabilities for every nuclear spin state by solving the stochastic Liouville equation numerically or approximately, establish a correlation between the nuclear spin states in the paramagnetic intermediates and the nuclear spin states in the products to obtain the populations of the latter, and finally apply Eq. 61 or the formalism of the preceding section to get line intensities. This approach, which for all but the simplest systems is impracticable except on a computer, is often necessary with the usual uncertainty of the parameters entering the calculations of the radical pair mechanism, a reasonable accuracy can be expected. However, qualitative relationships between signal intensities, especially signal phases, and parameters of the reaction mechanism as well as magnetic properties of the intermediates are... [Pg.95]

Conformational changes are frequently invoked to describe biochemical mechanisms qualitatively. With the surface free energy model, it is possible to evaluate the energetic consequences of conformational changes in proteins. We have done this for the ligand-binding reactions of hemoglobin (8). [Pg.429]

Obviously, the assumption of non-dissociative adsorption as well as that of the reaction being first order in both reactants are gross simplifications, since both methane and oxygen will dissociate prior to the reaction, and the further surface reaction mechanism will involve several consecutive and parallel reaction steps. Nevertheless, the model should allow for a qualitative test of the assumption that site competition between methane and oxygen account for the observed trend in ignition temperatures. [Pg.276]


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