Reaction compression molding

PWB printed wiring board RCM reaction compression molding... 

TS plastic products that are injection, transfer, or compression molded combine thick and thin sections relatively easily since the hardening process is a chemical reaction (Chapter 6). Annular shapes are best made by compression to gain best dimensional control and freedom from distortion. In the compression process, the molding compound is compressed and reduced to the plastic state in the mold. During this process, portions of the material may lie in hard forms in the mold while other portions are flowing rapidly with great force. 

Injection Molding Extrusion Blow Molding Thermoforming Reaction Injection Molding Rotational Molding Compression and Transfer Molding Matched Mold Spray-up... 

Stamatoff and Wittmann reported a synthesis of a 2-(4-phenoxyphenyl)hexa-duoroisopropanol in the presence of HF and an organic solvent via a Friedel-Crafts reaction, as shown in Scheme 6.29.231 The resulting polymer could be compression molded at 330-350°C. It also exhibited excellent thermostability and mechanical properties. 

Amine-terminated siloxane oligomers have also been utilized in the synthesis of various siloxane-amide and siloxane-imide copolymers, High molecular weight siloxane-amide copolymers have been synthesized by the solution or interfacial co-polymerization of siloxane oligomers with sebacoyl chloride or terephthaloyl chloride respectively 1S5,165). In some reactions diamine chain extenders have also been utilized. Thermal and dynamic mechanical characterization of these copolymers have shown the formation of multiphase systems160). Compression molded films displayed very good elastomeric properties. 

Recently the synthesis and characterization of novel fluorinated poly(aryl ether)s containing perfluorophenylene moieties " " was also reported. These fluorinated polyethers were prepared by reaction of decafluorobiphenyl with bisphenols. These polymers exhibit low dielectric constants, low moisture absorption, and excellent thermal and mechanical properties. Tough, transparent films of the polymers were prepared by solution-casting or compression-molding. The fluorinated poly(aryl ether)s containing perfluorophenylene moieties are good candidates for use as coatings in microelectronics applications. 

The physical properties for Reaction-Injection-Molded urethane foam cannot readily be determined because they are, as all sandwich structures, highly dependent on the particular shape of the article and the ratio of skin to foam or, in other words, the density distribution through the part. Typical densities for these new structural foams are 30 — 45 lbs./ft.3 with average moduli of elasticity of 120,000 — 250,000 p.s.i. The compression strengths are higher than those shown in Table VI for rigid foams without skins. 

The thermal stability of poly(vinyl chloride) is improved greatly by the in situ polymerization of butadiene or by reaction with preformed cis-1,4-polybutadiene using a diethyl-aluminum chloride-cobalt compound catalyst system. The improved thermal stability at 3-10% add-on is manifested by greatly reduced discoloration when the modified poly-(vinyl chloride) is compression molded at 200°C in air in the absence of a stabilizer, hydrogen chloride evolution at 180°C is retarded, and the temperature for the onset of HCl evolution and the peak decomposition temperature (DTA) increase, i.e. 260°-280°C and 290°-325° C, respectively, compared with 240°-260°C and 260°-280°C for the unmodified homopolymer, in the absence of stabilizer. The grafting reaction may be carried out on suspension, emulsion, or bulk polymerized poly(vinyl chloride) with little or no change in the glass transition temperature. 

Molding processes include compression molding, resin transfer molding (RTM), injection molding and reaction injection molding (RIM), autoclave molding, and several types of specific processes such as shell molding, which is used in foundries. 

Figure 13.44 represents the various stages of the compression molding cycle from the point of view of the plunger force needed to close the mold at a constant rate. In the first region, t < the force increases rapidly as the preform is squeezed and heated. At tf, the polymer is presumably in the molten state and, as such, is forced to flow into the cavity and fill it. Filling terminates at tc, when compression of the polymer melt takes place, to compensate for the volume contraction that results from the polymerization reaction. The bulk of the chemical reaction occurs after tc. We now comment on each of the steps of the compression molding process. 

Out of this experience come new processes such as in the past there was transfer compression molding and more recently came reaction injection molding (RIM). Very important is the fact that this development action continues to advance the use of the basic processes used in the industry. Those basic processes and a few others have been reviewed in this book. In this chapter a few of the others are reviewed. 

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