Quasi one dimensional

As an example, we look at tire etching of silicon in a CF plasma in more detail. Flat Si wafers are typically etched using quasi-one-dimensional homogeneous capacitively or inductively coupled RF-plasmas. The important process in tire bulk plasma is tire fonnation of fluorine atoms in collisions of CF molecules witli tire plasma electrons... 

The synthesis of molecular carbon structures in the form of C q and other fullerenes stimulated an intense interest in mesoscopic carbon structures. In this respect, the discovery of carbon nanotubes (CNTs) [1] in the deposit of an arc discharge was a major break through. In the early days, many theoretical efforts have focused on the electronic properties of these novel quasi-one-dimensional structures [2-5]. Like graphite, these mesoscopic systems are essentially sp2 bonded. However, the curvature and the cylindrical symmetry cause important modifications compared with planar graphite. 

Tanuma, S., Synthesis and structure of quasi-one-dimensional carbon crystal carbolite and intercalation with alkali metals and halogens. In Supercarbon, Synthesis, Properties and Applications, ed. S. Yoshimura and R. P. H. Chang, Springer-Verlag, Heidelberg, 1998, pp. 120 127. 

In this contribution, we discussed effects of disorder on the electronic properties of quasi-one-dimensional Peierls systems, like the conjugated polymer fraus-poly-acetylene. Since polymer materials generally are rather disordered and the effect of disorder on any quasi-one-dimensional system is strong, a proper description of these materials requires consideration of such effects. 

This model, which is sometimes referred to as the Fluctuating Gap Model (FGM) [42], has been used to study various aspects of quasi-one-dimensional systems. Examples arc the thermodynamic properties of quasi-one-dimensional organic compounds (NMP-TCNQ, TTF-TCNQ) [271, the effect of disorder on the Peierls transition [43, 44, and the effect of quantum lattice fluctuations on the optical spectrum of Peierls materials [41, 45, 46]. 

Spectroscopic properties of the quasi-one-dimensional tetracyanoplatinate(II) compounds. G. Glie-mann and H. Yersin, Struct. Bonding (Berlin), 1985, 62, 88 (181). 

The quasi-one-dimensional model of two-phase flow in a heated capillary slot, driven by liquid vaporization from the interface, is described in Chap. 8. It takes... 

The quasi-one-dimensional model of laminar flow in a heated capillary is presented. In the frame of this model the effect of channel size, initial temperature of the working fluid, wall heat flux and gravity on two-phase capillary flow is studied. It is shown that hydrodynamical and thermal characteristics of laminar flow in a heated capillary are determined by the physical properties of the liquid and its vapor, as well as the heat flux on the wall. 

Peles el al. (2000) elaborated on a quasi-one-dimensional model of two-phase laminar flow in a heated capillary slot due to liquid evaporation from the meniscus. Subsequently this model was used for analysis of steady and unsteady flow in heated micro-channels (Peles et al. 2001 Yarin et al. 2002), as well as the study of the onset of flow instability in heated capillary flow (Hetsroni et al. 2004). 

Below we consider a quasi-one-dimensional model of flow and heat transfer in a heated capillary, with hydrodynamic, thermal and capillarity effects. We estimate the influence of heat transfer on steady-state laminar flow in a heated capillary, on the shape of the interface surface and the velocity and temperature distribution along the capillary axis. 

Chapter 8 consists of the following in Sect. 8.2 the physical model of the process is described. The governing equations and conditions of the interface surface are considered in Sects. 8.3 and 8.4. In Sect. 8.5 we present the equations transformations. In Sect. 8.6 we display equations for the average parameters. The quasi-one-dimensional model is described in Sect. 8.7. Parameter distribution in characteristic zones of the heated capillary is considered in Sect. 8.8. The results of a parametrical study on flow in a heated capillary are presented in Sect. 8.9. 

Significant simplification of the governing equations may be achieved by using a quasi-one-dimensional model for the flow. Assume that (1) the ratio of meniscus depth to its radius is sufficiently small, (2) the velocity, temperature and pressure distributions in the cross-section are close to uniform, and (3) all parameters depend on the longitudinal coordinate. Differentiating Eqs. (8.32-8.35) and (8.37) we reduce the problem to the following dimensionless equations ... 

From the frame of the quasi-one-dimensional model it is possible to determine the hydrodynamic and thermal characteristics of the flow in a heated capillary, accounting for the influence of the capillary force. 

The quasi-one-dimensional model of flow in a heated micro-channel makes it possible to describe the fundamental features of two-phase capillary flow due to the heating and evaporation of the liquid. The approach developed allows one to estimate the effects of capillary, inertia, frictional and gravity forces on the shape of the interface surface, as well as the on velocity and temperature distributions. The results of the numerical solution of the system of one-dimensional mass, momentum, and energy conservation equations, and a detailed analysis of the hydrodynamic and thermal characteristic of the flow in heated capillary with evaporative interface surface have been carried out. 

Peles et al. (1998) and Khrustalev and Faghri (1996) considered two-phase laminar flow in a heated micro-channel with distinct evaporating meniscus in the frame of quasi-one-dimensional and two-dimensional models. 

Below the system of quasi-one-dimensional equations considered in the previous chapter used to determine the position of meniscus in a heated micro-channel and estimate the effect of capillary, inertia and gravity forces on the velocity, temperature and pressure distributions within domains are filled with pure liquid or vapor. The possible regimes of flow corresponding to steady or unsteady motion of the liquid determine the physical properties of fluid and intensity of heat transfer. 

The quasi-one-dimensional model described in the previous chapter is applied to the study of steady and unsteady flow regimes in heated micro-channels, as well as the boundary of steady flow domains. The effect of a number of dimensionless parameters on the velocity, temperature and pressure distributions within the domains of liquid vapor has been studied. The experimental investigation of the flow in a heated micro-channel is carried out. 

The subject of the present chapter is the analysis of possible states of capillary flow with distinct evaporative meniscus. The system of quasi-one-dimensional mass, momentum and energy equations are applied to classify the operating parameters corresponding to various types of flow. The domains of steady and unsteady states are also outlined. 

Two-phase flows in micro-channels with an evaporating meniscus, which separates the liquid and vapor regions, have been considered by Khrustalev and Faghri (1996) and Peles et al. (1998, 2000). In the latter a quasi-one-dimensional model was used to analyze the thermohydrodynamic characteristics of the flow in a heated capillary, with a distinct interface. This model takes into account the multi-stage character of the process, as well as the effect of capillary, friction and gravity forces on the flow development. The theoretical and experimental studies of the steady forced flow in a micro-channel with evaporating meniscus were carried out by Peles et al. (2001). These studies revealed the effect of a number of dimensionless parameters such as the Peclet and Jacob numbers, dimensionless heat transfer flux, etc., on the velocity, temperature and pressure distributions in the liquid and vapor regions. The structure of flow in heated micro-channels is determined by a number of factors the physical properties of fluid, its velocity, heat flux on... 

The quasi-one-dimensional model is based on the system of Eqs. (10.8-10.10) with condition (10.5-10.7) and describes the major features of the flow in the heated... 

The quasi-one-dimensional model used in the previous sections for analysis of various characteristics of fiow in a heated capillary assumes a uniform distribution of the hydrodynamical and thermal parameters in the cross-section of micro-channel. In the frame of this model, the general characteristics of the fiow with a distinct interface, such as position of the meniscus, rate evaporation and mean velocities of the liquid and its vapor, etc., can be determined for given drag and intensity of heat transfer between working fluid and wall, as well as vapor and wall. In accordance with that, the governing system of equations has to include not only the mass, momentum and energy equations but also some additional correlations that determine... 

The general features of two-dimensional flow with evaporating liquid-vapor meniscus in a capillary slot were studied by Khrustalev and Faghri (1996). Following this work we present the main results mentioned in their research. The model of flow in a narrow slot is presented in Fig. 10.16. Within a capillary slot two characteristic regions can be selected, where two-dimensional or quasi-one-dimensional flow occurs. Two-dimensional flow is realized in the major part of the liquid domain, whereas the quasi-one-dimensional flow is observed in the micro-film region, located near the wall. 

To calculate the micro-field, the quasi-one-dimensional model by Khrustalev and Faghri (1994, 1995) is used. 

The results of calculations of the Nusselt number are presented in Fig. 10.19. Here also the data of the calculated heat transfer by the quasi-one-dimensional model by Khrustalev and Faghri (1996) is shown. The comparison of the results related to one and two-dimensional model shows that for relatively small values of wall superheat the agreement between the one and two-dimensional model is good enough (difference about 3%), whereas at large At the difference achieves 30%. 

In this section we present the system of quasi-one-dimensional equations, describing the unsteady flow in the heated capillary tube. They are valid for flows with weakly curved meniscus when the ratio of its depth to curvature radius is sufficiently small. The detailed description of a quasi-one-dimensional model of capillary flow with distinct meniscus, as well as the estimation conditions of its application for calculation of thermohydrodynamic characteristics of two-phase flow in a heated capillary are presented in the works by Peles et al. (2000,2001) and Yarin et al. (2002). In this model the set of equations including the mass, momentum and energy balances is ... 

The system of quasi-one-dimensional non-stationary equations derived by transformation of the Navier-Stokes equations can be successfully used for studying the dynamics of two-phase flow in a heated capillary with distinct interface. 

The quasi-one-dimensional model allows analyzing the behavior of the vapor-liquid system, which undergoes small perturbations. In the frame of the linear approximation the effect of physical properties of both phases, the wall heat flux and the capillary sizes, on the flow instability is studied, and a scenario of the development of a possible processes at small and moderate Peclet number is considered. 

Gleitzer C, Goodenough JB (1985) Mixed-Valance Iron Oxides. 61 1-76 Gliemann G, Yersin H (1985) Spectroscopic Properties of the Quasi One-Dimensional Tetracyanoplatinate(II) Compounds. 62 87-153 Golovina AP, Zorov NB, Runov VK (1981) Chemical Luminescence Analysis of Inorganic substances. 47 53-119... 

Because of fhe planar nafure of the cormterflow flame and the relatively high Reynolds number associated with the flow, the flame/flow configuration can be considered to be "aerodynamically clean," where the quasi-one-dimensional and bormdary-layer simplifications can be implemented in either analytical or computational studies. Useful insights into the thermochemical structure... 

Examples of recently reported oxychlorides with one- or quasi-one-dimensional frameworks include A2Ti2Nb6Cli405 and Cs2Ti4Nbi5Cli80i5 in which the octahedral cluster unit has 5 or 6 oxygen ligands, respectively. 

Meerchaut, A. Rouxel, J. in Crystal Chemistry and Properties of Materials with Quasi-one Dimensional Structures, Rouxel, J., Ed. Reidel, Dordrecht, 1986, p. 205. 

The cobalt, nickel, and copper bis(2-ethylhexyl) phosphate surfactants dissolved in n-heptane lead to quasi-one-dimensional association microstructures, i.e., rodlike reversed micelles that increase in size via water solubilization [111],... 

Li H, Mackay R, Hwu SJ, Kuo YK, Skove MJ, Yokota Y, Ohtani T (1998) On the electrochemicaUy grown quasi-one-dimensional KCu7 j S4 series (0 < x < 0.34) Nonstoichiometry, superlattice, and unusual phase transitions. Chem Mater 10 3172-3183... 

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