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Quantum reversal effect

This limit is that of the quantum Zeno effect (QZE), namely, the suppression of relaxation as the interval between interruptions decreases [64-66]. In this limit, the system-bath exchange is reversible and the system coherence is fully maintained (Figure 4.4c). Namely, the essence of the QZE is that sufficiently rapid interventions prevent the excitation escape to the continuum, by reversing the exchange with the bath. [Pg.155]

Sn02 with ions. Each process seems to be due to an excitation transfer in the reverse order from Eu to Tb or to an increase of excitation transfer from Sn02 or to an increase of the quantum confinement effect since Sn02 crystallites size... [Pg.119]

No relationship exists for complexes of reverse polarity. Quantum perturbation effects do not seem to modify much these rules [32]. [Pg.186]

Solutions of water-containing reversed micelles are systems characterized by a multiplicity of domains apolar bulk solvent, oriented alkyl chains of the surfactant, hydrated surfactant headgroup region at the water/surfactant interface, and bulk water in the micellar core. Many polar, apolar, and amphiphilic substances, which are preferentially solubilized in the micellar core, in the bulk organic solvent, and in the domain comprising the alkyl chains and the hydrated surfactant polar heads, henceforth referred to as the palisade layer, respectively, may be solubilized in these systems at the same time. Moreover, it is possible that (1) local concentrations of solubilizate are very different from the overall concentration, (2) molecules solubilized in the palisade layer are forced to assume a certain orientation, (3) solubilizates are forced to reside for long times in a very small compartment (compartmentalization, quantum size effects), (4) the structure and dynamics of the reversed micelle hosting the solubilizate as well as those of the solubilizate itself are modified (personalization). [Pg.13]

Thus, we can use the approximate quantum number m to label such levels. Moreover, it may be shown [11] that (1) 3/m is one-half of an integer for the case with consideration of the GP effect, while it is an integer or zero for the case without consideration of the GP effect (2) the lowest level must have m = 0 and be a singlet with Ai symmetry in 53 when the GP effect is not taken into consideration, while the first excited level has m = 1 and corresponds to a doublet E conversely, with consideration of the GP effect, the lowest level must have m = j and be a doublet with E symmetry in S, while the first excited level corresponds to m = and is a singlet Ai. Note that such a reversal in the ordering of the levels was discovered previously by Hancock et al. [59]. Note further thatj = 3/m has a meaning similar to thej quantum numbers described after Eq. (59). The full set of quantum numbers would then be... [Pg.594]

In a recent analysis carried out for a bounded open system with a classically chaotic Hamiltonian, it has been argued that the weak form of the QCT is achieved by two parallel processes (B. Greenbaum et.al., ), explaining earlier numerical results (S. Habib et.al., 1998). First, the semiclassical approximation for quantum dynamics, which breaks down for classically chaotic systems due to overwhelming nonlocal interference, is recovered as the environmental interaction filters these effects. Second, the environmental noise restricts the foliation of the unstable manifold (the set of points which approach a hyperbolic point in reverse time) allowing the semiclassical wavefunction to track this modified classical geometry. [Pg.61]


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See also in sourсe #XX -- [ Pg.21 ]




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