Pure organic compound identification

MuUiken, Ideniification of Pure Organic Compounds, Volumes I-IV, 1904-1922 (J. Wiley this work is difficult to obtain in Great Britain). Huntress - MuUiken, Identification of Pure Organic Compounds, Order I, 1941 (J. Wiley Chapman and HaU). 

Mulliken, Identification of Pure Organic Compounds, Volumes I-IV, 1904-1922 (J. WUey). 

Huntress, E.H. and Mulliken, S.P. Identification of Pure Organic Compounds - Tables of Data on Selected Compounds of 0/ cfe/ /(New York John Wiley Sons, 1941), 691 p. 

JMulliken, S. P. The Identification of Pure Organic Compounds, 1911-1916. Norris, J. F. Experimental Organic Chemistry, 1915. 

Mulliken, Samuel Parsons. A Method for the Identification of Pure Organic Compounds by a Systematic Analytical Procedure Based on Physical Properties and Chemical Reactions. New York Wiley, Chapman Hall, 1904. 

In calculating the specific gravity of a substance the weight observed is divided by the volume of the pipette the result is the specific gravity of the substance at the observed temperature compared with water at 4°. If the number determined in this 1 Identification of Pure Organic Compounds, Vol. I. 

NOTES.—(a) Tests which are based on the recognition of odors are not reliable for the absolute identification of compounds. Whenever possible the compound to be identified is converted into a solid substance, which possesses a definite melting-point. For a test for ethyl alcohol based on this principle see "The Identification of Pure Organic Compounds," by S. P. Mulliken, Vol. I, page 168. 

The author has consulted all the well-known texts on laboratory work in organic chemistry in the preparation of the book. In writing the directions for the preparation of compounds on a small scale, valuable help was obtained from S. P. Mulliken s "The Identification of Pure Organic Compounds." A number of experiments on fats, carbohydrates, and proteins have been adapted, with the permission of the author, from a laboratory manual in descriptive organic chemistry prepared for the use of students of household economics, by Professor Alice F. Blood, of Simmons College. The author wishes to express his thanks for the courtesy shown in granting permission to make use of this material. 

The IR absorption peaks and bands for different carbon materials, along with the functional groups that are the source of the IR signal, are summarized in Table 1.10. The identification of the different functional gronps is based on comparison with the IR spectra of pure organic compounds. 

Nuclear Magnetic Resonance (NMR) spectroscopy is a powerful technique to identify and determine the structure of a pure organic compound or the repeat unit of a polymer. For polymer materials and composites, infrared (IR) and Raman spectroscopy are commonly used for identification of different functionalities. IR [49, 58-63], Raman [64, 65] and NMR [40, 43, 66, 67] spectroscopy have been carried out on PBIs and their composites to identify and/or confirm the chemical structure of the polymers. As an example of the wPBI, the IR spectrum in the region from 2000 to 4000 cm is of particular interest since most of the informative N-H stretching modes occur in this range, with typically three distinguishable bands at around 3415, 3145, and 3063 cm ... 

A more recent and far more extensive treatment for the identification of dyes has been developed by Mulliken, Identification of Pure Organic Compounds, Vol. III. About fifteen hundred dyes are classified in this extended treatise. The method of attack is as follows ... 

The chemist to whom most credit is due for the development of organic qualitative analysis is Professor S. P. MuUiken. The appearance of his exhaustive reference book on the Identification of Pure Organic Compounds," Vol. I, in 1905 is obviously the beginning of this line of work. The authors of foreign texts... 

NMR IR UVVIS and MS) were obtained using pure substances It is much more common however to encounter an organic substance either formed as the product of a chemical reaction or iso lated from natural sources as but one component of a mixture Just as the last half of the twentieth cen tury saw a revolution in the methods available for the identification of organic compounds so too has it seen remarkable advances in methods for their separation and purification... 

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