Propane, 1,2,3-trichloro

Beilstein Handbook Reference) AI3-26040 Allyl trichloride BRN 1732068 CCRIS 5874 EINECS 202-486-1 HSDB 1340 NCI-C60220 NSC 35403 Propane, 1,2,3-trichloro- Trichloropropane, Liquid mp = -14.7° bp = 167° d = 1.3889 slightly soluble in H2O, soluble in EtOH, Et20, CHCI3, CCI4. 

Trichloropropene oxide (1,1,1-tri-chloropropane-2,3-oxide, 3,3,3-trichloropropene oxide, 1,2-epoxy-3,3,3-trichloro-propane, trichloro-methyl oxirane) [3083-23-6] Epifluorohydrin (l,2-epoxy-3-fluoropropane) [503-09-3]... 

Bisphenol A, a compound highly used in the production of epoxy resins and polycarbonate plastics, forms monochloro-, dichloro, trichloro-, and tetrachloro derivatives when chlorinated [127], Its reaction with ozone produces as major transformation products, catechol, orthoquinone, muconic acid derivatives of bisphenol A, benzoquinone, and 2-(4-hydroxyphenyl)-propan-2-ol [128],... 

The carcinogenicity of 1,2,3-trichloro-propane is consistent with positive genotoxic findings that have included mutagenicity in Salmonella typhimurium and induction of sister chromatid exchanges in cultured hamster cells. It forms DNA adducts in vivo in mice and rats. ... 

Propane 3,3.3-Trichloro-l,l,1-trifluoro- ElOb,. 5.7 (Educt) EI0b2. 102 (Educt)... 

Cyano-l,2,3-tris(difluoroamino)propane, 1428a Cyanuric acid, see 2,4,6-Trihydroxy-1,3,5-triazine, 1115 Cyanuric chloride, see 2,4,6-Trichloro-1,3,5-triazine, 1035 Cyclo-o%o-butadiynyl-2,3-dioxocyclobutenylidene, see Oligo(octacarbondioxide), 3103 f Cyclobutane, 1575... 

Propane (— )-(5)-3-Bromo-l, 1,1-trichloro-3-phenyl- E21c, 2720 (Ar —en 4 BrCCl3)... 

S)-2-(Benzyloxy)propanal Propanal, 2- phenylmethoxy)-, (S)- (11) (81445-44-5) (S)-Ethyl hydroxypropanoate (S)-Ethyl lactate Lactic acic, ethyl ester, L- (8) Propanoic acid, 2-hydroxy-, ethyl ester, (S)- (9) (687-47-8) 0-Benzyl-2,2,2-trichloroacetimidate Ethanimidic acid, 2,2,2-trichloro-, phenylmethyl ester (11) (81927-55-1)... 

Photochlorination of cyclopropane gave chlorocyclopropane (la) and 1,3-dichloro-propane. The latter was the major product at low temperature. Photochlorination with tert-h Ay hypochlorite gave mostly chlorocyclopropane (la). Methylcyclopropane reacted with chlorine to give predominantly l-chloro-2-methylcyclopropane (lb), but small amounts of acyclic products such as 2-chlorobutane, 1,3-dichlorobutane, and 1,3-dichloro-2-methyl-propane were also obtained. With ferr-butyl hypochlorite 4-chlorobut-l-ene was isolated as the only acyclic product. Photochlorination of 1,1-dimethylcyclopropane in trichloro-fluoromethane atO°C gave the chloromethylcyclopropane derivative 2 in 67% yield after immediate workup. 

Products were identified as 2,2,2-trichloroethanol and 2,2,2-trichloro-acetaldehyde by GC-MS and GC, respectively. Trichloroethanol (6.7 mu M) was completely degraded in 72 hours. When toluene was added to reaction mixtures, there was a 50% increase in the mineralization of (sup 14 C) TCE. M. vaccae s ability to cometabolize 2,4,6-trinitrotoluene (TNT) was also investigated. Two novel metabolites, as well as known reduction products, have been identified during catabolism of TNT with propane as cosubstrate. When M. vaccae was incubated with propane and (sup 14 C) TNT, 50% of the labelled carbon was found in the lipid fraction of cells. Analysis of this fraction demonstrated metabolism of sup 14 C into known phosphatides and other polar lipids indicating that ring cleavage had occurred. TNT or reduced intermediates were not found in any portion of the lipid fractions. 

Fig. 25 Kharasch addition of 1,1,1-trichloroethane, l,LL2,2-pentachloroethane, LLl-trichloro-propane, 1,1,1,3,3-pentachloropropane and 1,1,1,3-tetrachloropropane to alkenes [27-32]...

Trichloro propane 3881 Tridecylalcohol, ethoxylated, phosphated, potassium salt 3068... 

Trichloroacetone, however, with methanethiol and hydrogen chloride immediately gives 1,1, l-trichloro-2,2-bis(methylthio)propane. 

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