Process parallel lines

These Br nsted-type plots often seem to be scatter diagrams until the points are collated into groups related by specific structural features. Thus, p-nitrophenyl acetate gives four separate, but parallel, lines for reactions with pyridines, anilines, imidazoles, and oxygen nucleophiles.Figure 7-4 shows such a plot for the reaction of trans-cmmm c anhydride with primary and secondary aliphatic amines to give substituted cinnamamides.All of the primary amines without substituents on the a carbon (R-CHi-NHi) fall on a line of slope 0.62 cyclopentylamine also lies on this line. If this line is characteristic of normal behavior, most of the deviations become qualitatively explicable. The line drawn through the secondary amines (slope 1.98) connects amines with the structure R-CHi-NH-CHi-R. The different steric requirements in the acylation reaction and in the model process... 

A laminar flow enclosure provides a means for environmental control of a confined area for aseptic use. Laminar flow units utilize HEPA filters, with the uniform movement of air along parallel lines. The air movement may be in a horizontal or vertical direction and may involve a confined area, such as a workbench, or an entire room. Laminar flow modules are suspended above filling lines, vial- and stopper-washing equipment, and other processes to provide an aseptic and particulate-free environment. 

As in a continuous flow process downstream apparatus is directly linked to upstream devices, the complete production line is interrupted in case of a failure upstream. It will be examined if this failure behavior can be corrected either by the design of several parallel lines or by supplying buffer tanks, additional spare pumps, machines,... 

FIG. 22-55 Typical capital-cost schematic for membrane equipment showing trade-off for membrane area and mechanical equipment. Lines shown are from families for parallel lines showing limiting costs for membrane and for ancillary equipment. Abscissa Relative membrane area installed in a typical membrane process. Minimum capital cost is at 1.0. Ordinate Relative cost. Line with positive slope is total membrane cost. Line with negative slope is total ancillary equipment cost. Curve is total capital cost. Minimum cost is at 1.0. 

However, in the solution process, the same two opposing forces reach a different balance. In Figure 83, the shear response of polymer is again shown as a function of the catalyst activation temperature, but in this case the polymers were made in the solution process. Because the LCB level of polymers made in the solution process is much lower, it is the breadth that now dominates the response to shear stress. The data of Figure 83 show that the response to shear stress decreases with rising activation temperature. Again, the comparison is made with polymers produced to have the same three MI values shown in Figure 82. Three parallel lines are produced that decline with activation temperature. 

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