Pressure change, system response

If a system is disturbed by periodical variation of an external parameter such as temperature (92), pressure, concentration of a reactant (41,48,65), or the absolute configuration of a probe molecule (54,59), then all the species in the system that are affected by this parameter will also change periodically at the same frequency as the stimulation, or harmonics thereof (91). Figure 24 shows schematically the relationship between stimulation and response. A phase lag <)) between stimulation and response occurs if the time constant of the process giving rise to some signal is of the order of the time constant Inim of the excitation. The shape of the response may be different from the one of the stimulation if the system response is non-linear. At the beginning of the modulation, the system relaxes to a new quasi-stationary state, about which it oscillates at frequency cu, as depicted in Fig. 24. In this quasi-stationary state, the absorbance variations A(v, t) are followed by measuring spectra... 

Kokufuta, Zhang and Tanaka developed a gel system that undergoes reversible swelling and collapsing changes in response to saccharides, sodium salt of dextran sulfate (DSS) and a-methyl-D-mannopyranoside (MP) [126]. The gel consists of a covalently cross-linked polymer network of W-isopropylacrylamide into which concanavalin A (ConA) is immobilized. As shown in Fig. 31, at a certain temperature the gel swells five times when DSS ions bind to ConA due to the excess ionic pressure created by DSS. The replacement of the DSS by non-ionic MP brings about collapse of the gel. The transition can be repeated with excellent reproducibility. 

The experiments were carried out at ambient pressure. All hydrocarbons were tested at a S/C ratio of three and all alcohols at a corresponding oxygen to carbon ratio. Decreasing conversion was found for the various fuels with increasing feed rates except for methanol owing to the very high reaction temperature of 725 °C. Table 2.9 summarizes some of the results presented for the various fuels. The proprietary catalyst showed only minor deactivation after 70 h TOS. It was deactivated reversibly by sulfur. Load changes of the liquid input from 100 to 10% resulted in a system response after 5-10 s. 

Gas pressures in vacuum applications are usually either recorded via membrane transducers, systems that monitor the gas density via partial ionisation of the gas or sensors that make use of the fact that the thermal conductivity or diffusivity of a gas is pressure dependent. The first type of transducer is sensitive to the total gas pressure while the other methods yield gas dependent signals. In terms of application properties such as the response time of the sensor, the sensitivity and the pressure range that the sensor covers are important technical specifications. The response of a membrane pressure sensor to a step-like pressure change is essentially an exponential function characterized by a relaxation time r for a MKS transducer, type Baratron 220 [1], r was determined to be 0.227 s (see Fig. 1), the actual pressure and the value as recorded by the transducer therefore do not match within the error bars given for the sensor until more than a second passed. 

In vivo, intravenous administration of ET-1 to conscious [20], anaesthetized [21] or pithed [22] rats produces a biphasic blood pressure response a small, transient depressor response followed by a prolonged pressor response. The systemic blood pressure changes induced by ET-1 are reflected in changes in regional haemodynamics, although the dilator response is not seen in all vascular beds [23-25], Big ET-1, when administered intravenously, is almost as potent as ET-1 in producing a pressor response which suggests effective in vivo conversion to ET-1 [22]. The haemodynamic effects of ET-1 have also been studied in man and pressor responses are seen after intravenous or intra-arterial administration [26-28]. 

On the other hand, fuel supply system response (when hydrogen is stored in high pressure tanks) results intrinsically faster than air supply system. The dynamics of this last sub-system appear particularly significant for the evaluation of dynamic performance of an overall FCS [48], as air compressor response is the limiting step for an adequate response of stack to load requirement changes. In particular the variations in air flow rates have to guarantee instantaneous stoichiometric ratios always not much lower than 2 during fast accelerations [49]. 

In single-component systems (or pure substances), the chemical composition in all phases is the same. In multicomponent systems, the chemical composition of a given phase changes in response to pressure and temperature changes and these compositions are not the same in all phases. For single-component systems, first-order phase transitions occur with a discontinuity in the first derivative of the Gibbs free energy. In the transitions, T and p remain constant. 

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