Precipitating reagent

Precipitation was the principal protein separation technology initially chosen for the development of an industrially suitable fractionation process. Ethanol [64-17-5] (qv) was selected as the precipitation reagent because of its volatility. It can be subsequently removed using available drying technology... 

Technology Description To achieve precipitation, acid or base is added to a solution to adjust the pH to a point where the constituents to be removed have their lowest solubility. Chemical precipitation facilitates the removal of dissolved metals from aqueous wastes. Metals may be precipitated from solutions as hydroxides, sulfides, carbonates, or other soluble salts. A comparison of precipitation reagents is presented in Table 7. Solid separation is effected by standard flocculation/ coagulation techniques. 

FUllungs-becherglas, n. precipitation beaker, -kraft, /. precipitating power, -mittel, n. precipitant, -reagens, n. precipitation reagent, -reaktion, /. precipitation reaction, -vermogen, n. precipitating power, -wkrme, /. heat of precipitation, -wert, m. precipitation value. 

Note. Prepare the precipitating reagent by dissolving 5.0 g aluminium potassium sulphate (potash alum) in 90 mL warm water. Cool and add dropwise with stirring, while cooling in ice, a solution of 2.0 g sodium hydroxide in 5.0 mL water until the initially formed precipitate re-dissolves. After standing for 12 hours, filter, adjust the pH to 12.6, and dilute to 100 mL with water. 

Determination of zinc as 8-hydroxyquinaldinate Discussion. Zinc may be precipitated by 8-hydroxyquinaldine (2-methyloxine) in acetic acid-acetate solution it can thus be separated from aluminium and magnesium [see Section 11.11(G)]. It can be weighed as Zn(C10H8ON)2 after drying at 130-140 °C. The co-precipitated reagent is volatile at 130 °C. 

A summary of some alternative procedures for cations is given here under the headings of the various precipitating reagents used. Section references, given in parentheses, relate to the other procedure already given for that cation. 

The common ion effect (Chapter 3) is a further important factor affecting solubilities. Addition of A or B to the above system (equation (5.28)) will shift the equilibrium to the left and reduce the solubility of AB. In practice, this situation would arise when an excess of a precipitating reagent has been added to an analyte solution. Such an excess leads to the possibility of complexation reactions occurring which will tend to increase the solubility of AB. For example, when aluminium or zinc is precipitated by hydroxyl ions, the following reactions with excess reagent can occur... 

Precipitation inhibitors, dispersants contrasted, 3 686 Precipitation leachate procedure, synthetic, 25 868-869 Precipitation reactions, for niobium and tantalum determination, 27 142-143 Precipitation reagents, protein, 22 133 Precipitation with compressed antisolvent (PCA) process, 24 17, 18 Precipitator dust, in phosphorus manufacture, 19 12 Precipitators, electrostatic, 23 180 Precision agriculture, 23 328 26 269-270 Precision measurement techniques, noble gases in, 27 370 Precision scales, 26 245 Preconcentration, of uranium ores, 25 401 Pre-crosslinked polychloroprene grades, 19 852... 

Gravimetric Analysis The precipitation is guided by the concentration of the solute and of the precipitating reagent, reaction time, reaction temperature and the nature and amount of other substance(s) present in solution. 

An instrument was proposed for measurement of Li concentration in human serum, based on the turbidimetric or nephelometric determination of the maximum rate of precipitation of a Li complex, which is related to the Li concentration in the serum. The precipitating reagent was prepared by dissolving KIO4 and FeCls in a KOH solution. Measurements were made every 10 s for 5 min at 550 nm. No interference was recorded for the presence of triglycerides, cholesterol, Na or... 

Chlorpromazine was determined by precipitation with an excess of 0.2% ammonium reineckate solution, and titration of the unconsumed reagent bromatometrically after alkaline hydrolysis [67]. Excess hexathiocyanato-chromate was used as a precipitating reagent for chlorpromazine, whereupon the unconsumed reagent was determined with KBr03 in the filtrate [68]. 

The more finely divided the manganese dioxide the more rapid will be the reaction, so that the precipitated reagent is better than finely powdered pyrolusite. It is still better to prepare the precipitated hydroxide Mn(OH)4, by reducing the necessary quantity of potassium permanganate in neutral solution with alcohol and washing the precipitate from soluble potassium salts by decantation. 

If there is introduced into the solution from some other source an ion that is in common with an ion of the insoluble solid, the chemical equilibrium is shifted to the left, and the solubility of that solid will be greatly decreased from what it is in pure water. This is called the 11 common-ion effect." This effect is important in gravimetric analysis, where one wishes to precipitate essentially all of the ion being analyzed for, by adding an excess of the "common-ion" precipitating reagent. There is a practical limit to the excess, however, which involves such factors as purity of precipitate and possibility of complex formation. You can calculate the solubility under a variety of conditions, as illustrated in the following problem. 

Both antimony and bismuth triodides may be prepared in this way but concentrated (57%) hydriodlc acid (No. 89) should be used as precipitating reagent for the bismuth salt beeauie the latter is not readily soluble in organic liquids about BOg of add are required. 

LDL precipitating reagent. This solution contains phosphotungstate, magnesium ions, and sodium azide. 

Other typical reagents generated for coulometric titrations are hydrogen and hydroxyl ions, redox reagents such as ceric, cuprous, ferrous, chromate, ferric, manganic, stannous, and titanous ions, precipitation reagents such as silver, mercurous, mercuric, and sulfate ions, and complex-formation reagents such as cyanide ion and EDTA [8-10]. 

---