Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Power time dependent

One of the major conclusions of the Wool theory (56,57) is that mechanical strength buildup during interface healing should have a one-fourth power time dependence. Note that the time dependence of equation (11.32) and others are rather than as expected for usual atomic diffusion processes. [Pg.600]

Thermal power plant components operated at high temperatures (>500°C) and pressures, such as superheater headers, steamline sections and Y-junctions, deserve great attention for both operation safety and plant availability concerns. In particular, during plant operation transients -startups, shutdowns or load transients - the above components may undergo high rates of temperature / pressure variations and, consequently, non-negligible time-dependent stresses which, in turn, may locally destabilize existing cracks and cause the release of acoustic emission. [Pg.67]

Extend the safe useful operation life of major HT/HP power plant items, subject to time-dependent creep and thermal fatigue damage, with benefits in terms of delayed costs for component replacement. [Pg.75]

Themiodynamics is a powerful tool in physics, chemistry and engineering and, by extension, to substantially all other sciences. However, its power is narrow, since it says nothing whatsoever about time-dependent phenomena. It can demonstrate that certain processes are impossible, but it caimot predict whether thennodynamically allowed processes will actually take place. [Pg.322]

Iterative approaches, including time-dependent methods, are especially successfiil for very large-scale calculations because they generally involve the action of a very localized operator (the Hamiltonian) on a fiinction defined on a grid. The effort increases relatively mildly with the problem size, since it is proportional to the number of points used to describe the wavefiinction (and not to the cube of the number of basis sets, as is the case for methods involving matrix diagonalization). Present computational power allows calculations... [Pg.2302]

To use direct dynamics for the study of non-adiabatic systems it is necessary to be able to efficiently and accurately calculate electronic wave functions for excited states. In recent years, density functional theory (DFT) has been gaining ground over traditional Hartree-Fock based SCF calculations for the treatment of the ground state of large molecules. Recent advances mean that so-called time-dependent DFT methods are now also being applied to excited states. Even so, at present, the best general methods for the treatment of the photochemistry of polyatomic organic molecules are MCSCF methods, of which the CASSCF method is particularly powerful. [Pg.299]

The preferable theoretical tools for the description of dynamical processes in systems of a few atoms are certainly quantum mechanical calculations. There is a large arsenal of powerful, well established methods for quantum mechanical computations of processes such as photoexcitation, photodissociation, inelastic scattering and reactive collisions for systems having, in the present state-of-the-art, up to three or four atoms, typically. " Both time-dependent and time-independent numerically exact algorithms are available for many of the processes, so in cases where potential surfaces of good accuracy are available, excellent quantitative agreement with experiment is generally obtained. In addition to the full quantum-mechanical methods, sophisticated semiclassical approximations have been developed that for many cases are essentially of near-quantitative accuracy and certainly at a level sufficient for the interpretation of most experiments.These methods also are com-... [Pg.365]

When a solute elutes from the column, the thermal conductivity of the mobile phase decreases and the temperature of the wire filament, and thus its resistance, increases. A reference cell, through which only the mobile phase passes, corrects for any time-dependent variations in flow rate, pressure, or electrical power, ah of which may lead to a change in the filament s resistance. [Pg.569]

The other models can be appHed to non-Newtonian materials where time-dependent effects are absent. This situation encompasses many technically important materials from polymer solutions to latices, pigment slurries, and polymer melts. At high shear rates most of these materials tend to a Newtonian viscosity limit. At low shear rates they tend either to a yield point or to a low shear Newtonian limiting viscosity. At intermediate shear rates, the power law or the Casson model is a useful approximation. [Pg.167]

Most modeling codes are a time-averaging technique. Depending upon the process, a time-dependent technique may be more suitable. Time-dependent modeling requires much more computing power than does time averaging. [Pg.1643]

Reliable during power outage for short period of time, dependent on size of air surge vessel. [Pg.293]

Upon comparison of Eqs. 29 and 36, it is readily apparent that both theories predict the same power law dependence of the contact radius on particle radius and elastic moduli. However, the actual value of the contact radius predicted by the JKR theory is that predicted by the DMT model. This implies that, for a given contact radius, the work of adhesion would have to be six times as great in the DMT theory than in the JKR model. It should be apparent that it is both necessary and important to establish which theory correctly describes a system. [Pg.152]

Other ideas proposed to explain the 3/4 power-law dependence include effects due to viscoelasticity, non-linear elasticity, partial plasticity or yielding, and additional interactions beyond simply surface forces. However, none of these ideas have been sufficiently developed to enable predictions to be made at this time. An understanding of this anomalous power-law dependence is not yet present. [Pg.158]

In the analysis of pumps, IPRDS failure data for 60 selected pumps at four nuclear power plants were statistically analyzed using FRAC. The data cover 23 functionally different pumps, respectively, for two BWRs. Catastrophic, degraded, and incipient failure severity categories were considered for both demand-related and time-dependent failures. [Pg.104]

Plot the CPU time used for each method as a function of the number of carbon atoms (N). Theoretically, CPU time required should scale as the fourth power of the number of carbon atoms IN ). How do the actual times depend on N ... [Pg.32]

An expansion in powers of 1 /c is a standard approach for deriving relativistic correction terms. Taking into account electron (s) and nuclear spins (1), and indicating explicitly an external electric potential by means of the field (F = —V0, or —— dAjdt if time dependent), an expansion up to order 1/c of the Dirac Hamiltonian including the... [Pg.210]

The reliability of a modern electric power system depends on continuous real-time control of power and energy production, transmission line flows, system frequency, and voltage. This complex task will get more involved in the new environment with increased market participation on both the supply and the demand sides. [Pg.425]

The best efficiency attainable from a gasoline engine of specified power rating depends heavily on four parameters compression ratio, air/fuel ratio, spark timing, and the fraction of the mechanical energy developed in the cylinder or cylinders devot-... [Pg.562]

Data for power consumption of Bingham plastic fluids have been reported and correlated by Nagata el alm) and of dilatant fluids by N.AGATA el ul.(2 ) and METZNER et al.i2V). Edwards et ai. M ) have dealt with the mixing of time-dependent thixotropic materials. [Pg.293]

Its poles are determined to any order of by expansion of M. However, even in the lowest order in the inverse Laplace transformation, which restores the time kinetics of Kemni, keeps all powers to Jf (t/xj. This is why the theory expounded in the preceding section described the long-time kinetics of the process, while the conventional time-dependent perturbation theory of Dirac [121] holds only in a short time interval after interaction has been switched on. By keeping terms of higher order in i, we describe the whole time evolution to a better accuracy. [Pg.87]

In general, if the removal flux is dependent upon the reservoir content raised to the power a (a 1), i.e., S = BM, the adjustment process will be faster or slower than the steady-state turnover time depending on whether a is larger or smaller than unity (Rodhe and Bjorkstrdm, 1979). [Pg.71]

For the calculation of shear stress, the time-dependent impeller power, particle diameter dp and viscosity v according to v = K/9 with the representative shear gradient y = for the non Newtonian broth (see equation (17) [28]) were used. [Pg.74]


See other pages where Power time dependent is mentioned: [Pg.413]    [Pg.61]    [Pg.867]    [Pg.413]    [Pg.61]    [Pg.867]    [Pg.1071]    [Pg.298]    [Pg.655]    [Pg.378]    [Pg.136]    [Pg.234]    [Pg.3]    [Pg.188]    [Pg.86]    [Pg.517]    [Pg.557]    [Pg.487]    [Pg.391]    [Pg.100]    [Pg.605]    [Pg.205]    [Pg.449]    [Pg.606]    [Pg.393]    [Pg.218]    [Pg.219]    [Pg.6]    [Pg.139]    [Pg.190]    [Pg.97]    [Pg.63]   
See also in sourсe #XX -- [ Pg.186 ]




SEARCH



Power dependence

Time-dependent power spectral density

© 2024 chempedia.info