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Potassium cinnamate

This article reports on the synthesis of photosensitive polymers with pendant cinnamic ester moieties and suitable photosensitizer groups by cationic copolymerizations of 2-(cinnamoyloxy)ethyl vinyl ether (CEVE) (12) with other vinyl ethers containing photosensitizer groups, and by cationic polymerization of 2-chloroethyl vinyl ether (CVE) followed by substitution reactions of the resulting poly (2-chloroethyl vinyl ether) (PCVE) with salts of photosensitizer compounds and potassium cinnamate using a phase transfer catalyst in an aprotic polar solvent. The photochemical reactivity of the obtained polymers was also investigated. [Pg.226]

Substitution reactions of the remaining pendant chloroethyl groups in PCVE-NPVE with 20 mol-% excess of potassium cinnamate were carried out using TBAB as a phase transfer catalyst in DMF at 100"C for 24 h. The reaction conditions and results are summarized in Table III. It should be noted that 100 mole % substitution occurred in all cases. [Pg.231]

No. Mole % ester Mole % photosensitizer mmole chlorine Potassium cinnamate (mmol) TBAB (mmol) Yield (g) b 4sp/c... [Pg.232]

These results suggest that the reaction conditions for the syntheses of PCEVE-NPVE and PCEVE-NNVE can be accomplished by the reactions of PCVE with any ratio of potassium cinnamate and PNP or PNN in one pot using a phase transfer catalyst. In addition, it is to be expected that PCEVE-NPVE and PCEVE-NNVE prepared from the reactions of PCVE have the same degree of polymerization if no side reactions occur during the substitution reactions. It is also expected that these copolymers are more random compared to the copolymers prepared from the cationic copolymerizations of the monomers, because the former is not affected by the monomer reactivity ratios. [Pg.233]

From all these results, it was concluded that polymers have high photochemical reactivity and high practical photosensitivity when synthesized by the cationic copolymerizations of CEVE with NNVE or NPVE, or by the reactions of PCVE with potassium cinnamate and PNN or PNP using phase transfer catalyst in DMF. [Pg.239]

Does not give Unsaturation Test with alkaline potassium permanganate (distinction from cinnamic acid, see below). [Pg.352]

Phenylpropiolic acid. This is an example of an aromatic acetylenic acid, and is made by adding bromine to the ethylenio linkage in ethyl cinnamate, and treating the resulting dibromide with alcohobc potassium hydroxide which eliminates two molecules of hydrogen bromide ... [Pg.755]

Benzal chloride is hydrolyzed to benzaldehyde under both acid and alkaline conditions. Typical conditions include reaction with steam in the presence of ferric chloride or a zinc phosphate catalyst (22) and reaction at 100°C with water containing an organic amine (23). Cinnamic acid in low yield is formed by heating benzal chloride and potassium acetate with an amine as catalyst (24). [Pg.59]

Selective oxidation of either the aromatic ring or the side chain can also be accompHshed. For example, epoxidation of the double bond of cinnamic acid is effected in excellent yield by treatment with potassium hydrogen persulfate (10). [Pg.173]

Manufacture. The most widely employed method for the commercial synthesis of (H)-cinnamic acid uti1i2es ben2aldehyde, acetic anhydride, and anhydrous sodium or potassium acetate in a condensation reaction commonly referred to as the Perkin reaction (11). [Pg.173]

Manufacture. A limited, amount of natural cinnamyl alcohol is produced by the alkaline hydrolysis of the cinnamyl cinnamate present in Styrax Oil. Thus treatment of the essential oil with alcohoHc potassium hydroxide Hberates cinnamyl alcohol of reasonable purity which is then subjected to distillation. This product is sometimes preferred in fine fragrance perfumery because it contains trace impurities that have a rounding effect in finished formulations. [Pg.176]

As with poly(vinyl alcohol), poly(vinyl cinnamate) is prepared by chemical modification of another polymer rather than from monomer . One process is to treat poly(vinyl alcohol) with cinnamoyl chloride and pyridine but this is rather slow. Use of the Schotten Baumann reaction will, however, allow esterification to proceed at a reasonable rate. In one example poly(vinyl alcohol) of degree of polymerisation 1400 and degree of saponification of 95% was dissolved in water. To this was added a concentrated potassium hydroxide solution and then cinnamoyl chloride in methyl ethyl ketone. The product was, in effect a vinyl alcohol-vinyl cinnamate copolymer Figure 14.8)... [Pg.396]

Furfural condenses with acetic anhydride and potassium acetate to give furylacrylic acid (compare Perkin reaction, Cinnamic Acid, Section IV, 124) ... [Pg.834]

For the reduction of nitro-compounds containing a group which may be attacked by nascent hydrogen, as, for example, an aldehyde group, an unsaturated side chain, and so on, special methods must he applied. In such cases ferrous hydroxide or iron powder (cf. Chap. VII. 5, arsanilic acid) are often used. The reduction is carried out thus a weighed amount of ferrous sulphate is caused to act, in the presence of alkali (potassium or sodium hydroxide, baryta), on the substance to he reduced. In this way it is possible to reduce, for example, o-nitro-benzaldehyde to aminobenzaldehyde, and o-nitrocinnamic acid to amino-cinnamic acid. [Pg.172]


See other pages where Potassium cinnamate is mentioned: [Pg.227]    [Pg.232]    [Pg.21]    [Pg.27]    [Pg.322]    [Pg.18]    [Pg.123]    [Pg.227]    [Pg.232]    [Pg.21]    [Pg.27]    [Pg.322]    [Pg.18]    [Pg.123]    [Pg.707]    [Pg.712]    [Pg.174]    [Pg.200]    [Pg.434]    [Pg.707]    [Pg.712]    [Pg.40]    [Pg.1088]    [Pg.378]    [Pg.1335]    [Pg.377]    [Pg.338]    [Pg.40]    [Pg.431]    [Pg.12]    [Pg.707]    [Pg.712]    [Pg.92]    [Pg.713]   
See also in sourсe #XX -- [ Pg.164 ]

See also in sourсe #XX -- [ Pg.164 ]




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