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Possible reasons for

Determine the density at least five times, (a) Report the mean, the standard deviation, and the 95% confidence interval for your results, (b) Eind the accepted value for the density of your metal, and determine the absolute and relative error for your experimentally determined density, (c) Use the propagation of uncertainty to determine the uncertainty for your chosen method. Are the results of this calculation consistent with your experimental results ff not, suggest some possible reasons for this disagreement. [Pg.99]

Antibiotics (qv) have been fed at subtherapeutic levels to promote mminant animal growth. Possible reasons for the observed growth include decreased activity of microbes having a pathogenic effect on the animal, decreased production of microbial toxins, decreased microbial destmction of essential nutrients, increased vitamin synthesis or synthesis of other growth factors, and increased nutrient absorption because of a thinner intestinal wall... [Pg.157]

Fmit and vegetable juices high in potassium have been recommended to correct hypokalemic alkalosis in patients on diuretic therapy. Apparendy the efficacy of this treatment is questionable. A possible reason for ineffectiveness is the low Ck content of most of these juices. Because Ck is high only in juices in which Na" is high, these have to be excluded (64). [Pg.381]

In view of the overall increased reactivity of furan compared with thiophene it would be anticipated that furan would be less regioselective in its reactions with electrophiles than thiophene. Possible reasons for the high regioselectivity of furan in electrophilic substitution reactions include complex formation between substrates and reagents and the ability of heteroatoms to assist in the stabilization of cationic intermediates (80CHE1195). [Pg.44]

Certainly, at the moment of starting a pump with a new seal installed, the events prior to the installation begin to disappear as a cause or origin of failure, and the factors of operation, process, and design in the system begin to appear as possible reasons for any premature failure. [Pg.204]

It was shown that the effect of the particle size is not significant in HOPC (1). The experiments were conduced using silica gels of the same pore size but with a different average particle size between 15 and 100 /urn. A kinetic effect— enrichment of the mobile phase with high MW components is better at short times before equilibrium is reached—was cited as a possible reason for almost equal quality of separation by large particles. The back-pressure problem was not serious in that range of the particle size. [Pg.626]

From the intercept at AG° = 0 we find AGo = 31.9 kcal mol , and the slope is 0.77. As we have seen, if Eq. (5-69) is applicable, the slope should be 0.5 when AG = 0. In this example either the data cover too small a range to allow a valid estimate of the slope to be made or the equation does not apply to this system. Such a simple equation is not expected to be universally applicable. Recall that it was derived for an elementary reaction, so multistep reactions, even if showing simple rate-equilibrium behavior, introduce complications in the interpretation. The simple interpretation of Eq. (5-69) also requires that AGo be constant within the reaction series, but this condition may not be met. Later pages describe another possible reason for the failure of Eq. (5-69). [Pg.227]

Usually the Arrhenius plot of In k vs. IIT is linear, or at any rate there is usually no sound basis for coneluding that it is not linear. This behavior is consistent with the conclusion that the activation parameters are constants, independent of temperature, over the experimental temperature range. For some reactions, however, definite curvature is detectable in Arrhenius plots. There seem to be three possible reasons for this curvature. [Pg.251]

Discuss possible reasons for the curvature in the Br nsted-type plot of Fig. 7.5 for the nucleophilic reactions of oxygen nucleophiles. [Pg.382]

Note in Table 5-1 the correlation between the normal boiling point and heat of vaporization of a number of liquids. Suggest possible reasons for this regularity. [Pg.82]

Give possible reasons for selecting each of the following operating conditions for a hypothetical amino add fermentation. [Pg.248]

Another possible reason for the deviations observed is some heterogeneity of highly crosslinked PAAm gels which manifests itself in particular by an anomalous growth of the modulus at substantial elongations of the gel [18]. [Pg.118]

In non-competitive inhibition, the substrate (S) and inhibitor (I) have equal potential to bind to the free enzyme (E). The inhibitor forms a ternary complex with enzyme-substrate (ES) whereas the substrate will form another ternary complex with enzyme-inhibitor (El). Since the non-competitive inhibitor had no effect on the binding of substrate to the enzyme, the Km value remained consistent (or unchanged). There are two different ways for the formation of ESI ternary complex this complex would not form the product and therefore was decreased. Non-competitive inhibitor had no effect on substrate binding or the enzyme-substrate affinity, therefore the apparent rate constant (K ) was unchanged.5 A possible reason for product inhibition was because of the nature of 2-ethoxyethanol,... [Pg.134]

The structure of the aqua complex (Figure 1.51), which is an active intermediate in some catalytic systems, shows the Ru-OH2 distance to be some 0.1 A longer than in the ruthenium(III) hexaqua ion, indicating a possible reason for its lability the water molecule also lies in a fairly exposed position, away from the bulk of the EDTA group. [Pg.49]

The dependence of the C,E curves for a solid metal on the method of electrode surface preparation was reported long ago.10 20 67 70 219-225 in addition to the influence of impurities and faradaic processes, variation in the surface roughness was pointed out as a possible reason for the effect.10 67,70 74 219 For the determination of R it was first proposed to compare the values of C of the solid metal (M) with that of Hg, i.e., R = C-M/c-Hg 10,74.219-221 data at ff=0 for the most dilute solution (usually... [Pg.44]

The high energy behavior of the cross-section for this reaction— i.e., its rapid fall-off—can be explained by assuming that different exit channels compete on the basis of available phase space (24), The low energy behavior presents a greater mystery. Further possible reasons for this behavior are discussed below. [Pg.30]

One possible reason for the reluctance of non-electrochemists to venture into this field is that in contrast to the electrochemists claim that controlled potential electrolysis offers a method for the selective introduction of energy into molecules, many electrode reactions carried out at a controlled potential have still been reported to give low yields and a diversity of products. The electrode potential is, however, only one of several variables and the lack of selectivity in the electrode process may be attributed to a failure to understand and to control all the parameters of the overall electrode reaction. [Pg.156]

What could be the possible reasons for noise in 2D NMR spectra, and how can symmetrization be used to improve the quality and readability of the plot ... [Pg.172]

A possible reason for the departures from Pick s first law is the fact that the diffusion process tends to level chemical potentials (thermodynamic activities) rather than concentrations of the substances involved. Hence, the equation sometimes is written as... [Pg.53]


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