Porous Metal Organic Frameworks

whereas in (b) there are two different sorts of linear linkers, as in the diamine pillared zinc terephthalate of Dybtsev. Topology (c) is adopted by the terephthalate Sc2(02CCgH4C02)3. [Pg.47]

The majority of the MOFs that show interesting porous frameworks are built from amine or carboxylate ligands, or combinations of the two. The ability of carboxylates to bind fully through two strong M-OC links rather than one M-N bond, tends to result in carboxylates making up the most thermally robust materials, but there are thermally stable microporous amine- and phosphonate- and even phosphine-based MOFs. [Pg.47]

Some di- and tricarboxylate ligands that have been used successfully in the synthesis of metal organic frameworks mentioned in this text 1 - MOF-5, MIL-53, MIL-68, MIL-101, Sc2(02CC6H4C02)3 structures with the same topology as MOF-5, but with extended linkers 7, 8 - functionalised linkers in MOF and MIL solids 9 -FIKUST-1, MIL-100 10 MOF-177. [Pg.48]

2 Paddle wheel cluster. The paddle wheel cluster is known in many complexes and was found within several of the earliest MOFs to be prepared, typically as (CU2)- or (Zn2)-based units. With 1,4-benzenedicarboxylate or 2,6-naphthalene dicarboxylate (NDQ the paddle wheel complex typically [Pg.49]

For MIL-101, BDC linkers join trimers along the edges of the supertetrahedra, whereas for MIL-100, BTC linkers occupy the faces of the supertetrahedra, linking three trimers. The supertetrahedra are attached through shared trimers [Pg.51]

H. Li, M. Eddaoudi, M. O Keeffe, O. M. Yaghi, "Design and synthesis of an exceptionally stable and highly porous metal-organic framework , Nature 1999, 402,276-279. [Pg.233]

H. Van Bekkum, A. Corma, and E. Schuth), Stud. Surf Sd. Cat., vol. 168, Elsevier, Amsterdam, pp. 327-374 Muller, U., Schubert, M.M., and Yaghi, O.M. (2008) Chemistry and applications of porous metal-organic frameworks, in Handbook of Heterogeneous Catalysis, Wiley-VCH Verlag GmbH, Weinheim, pp. 247-252. [Pg.25]

Reticular design and synthesis of porous metal-organic frameworks... [Pg.799]

From Inorganic Porous Frameworks to Porous Metal-organic Frameworks (MOFs)... [Pg.8]

This is not to say that all has been discovered about these materials. New solids are continually being synthesised, and the rapidly developing field of porous metal organic frameworks (MOFs) is a current example. The applica-bihty of microporous solids is continually being extended within the traditional fields of adsorption, catalysis and ion exchange. One exciting application explores their use as catalysts in the manufacture of fine chemicals. Other emerging areas of research concern their potential use in medicine or in devices that require speeial electronic or optical properties. [Pg.435]

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Yaghi, O. M., Li, G., and Li, H., Selective binding and removal of guests in a micro-porous metal-organic framework. Nature, 378, 703-706 (1995). [Pg.898]

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