POLYURETHANE-MODIFIED SYSTEMS

The first patent of a polyurethane-modified system was taken by Szukiewiczl l in 1959. Another system modified with a polyurethane resin was patented by Shearingl l in 1970. In 1969, Ohama reported the results of a wide-ranging study of a polyurethane-modified mortar system,and this product now is commercially available in Japan. The product consists of three components, i.e., promoter, polyol, and polyisocyanate. The modified system is prepared by the following procedure cement and sand are dry-blended, the promoter component is added to the cement-sand mfacture, and then the polyol component is blended with the mixture. Finally, the polyisocyanate component is mixed with the cement-sand-promoter-polyol mixture until a uniform mortar is obtained. 

An acrylate-terminated polyurethane modified epoxy compound and a polyethylene polyamine homologue and fatty acid combination were formulated into a two-component adhesive system. The adhesive is useful for bonding various thermoplastic resins such as ABS, PC, PBT-PC blends, and PPO.22... 

Liquid polyurethane waterproofing systems are coal-tar modified products. Two-component materials are catalysed curing systems, and one-component materials are cured by exposure to moisture. Both the materials exhibit comparable properties on complete curing. Two-component materials require on-site mixing of the components. One-component materials can be applied directly, but the problem with this type is polymerisation of the product inside the container if it is improperly sealed. Such products are purged with an inert gas when the pack is sealed. 

Valero, M.F., Gonzalez, A., 2012. Polyurethane adhesive system from castor oil modified by a transesterification reaction. J. Elastomers Plast. 44, 433—442. 

Polyurethane foams do, however, suffer from one serious disadvantage. Unless modified they bum with copious evolution of smoke and toxic by-products, which has led to a number of fatal fires, particularly in domestic accommodation. To some extent the problem may be reduced by suitable upholstery covering, but as mentioned on p. 775 a number of countries have now made mandatory the use of fire retardent additives. At the time of writing there is considerable activity in the development of new safer systems, particularly in the use of amino materials such as melamine as additives. Further developments may also be expected in the near future. 

Siloxane containing interpenetrating networks (IPN) have also been synthesized and some properties were reported 59,354 356>. However, they have not received much attention. Preparation and characterization of IPNs based on PDMS-polystyrene 354), PDMS-poly(methyl methacrylate) 354), polysiloxane-epoxy systems 355) and PDMS-polyurethane 356) were described. These materials all displayed two-phase morphologies, but only minor improvements were obtained over the physical and mechanical properties of the parent materials. This may be due to the difficulties encountered in controlling the structure and morphology of these IPN systems. Siloxane modified polyamide, polyester, polyolefin and various polyurethane based IPN materials are commercially available 59). Incorporation of siloxanes into these systems was reported to increase the hydrolytic stability, surface release, electrical properties of the base polymers and also to reduce the surface wear and friction due to the lubricating action of PDMS chains 59). 

This system was slightly modified by R J. Flory, who placed the emphasis on the mechanisms of the polymerisation reactions. He reclassified polymerisations as step reactions or chain reactions corresponding approximately to condensation or addition in Carother s scheme, but not completely. A notable exception occurs with the synthesis of polyurethanes, which are formed by reaction of isocyanates with hydroxy compounds and follow step kinetics, but without the elimination of a small molecule from the respective units (Reaction 1.3). 

Composite Particles, Inc. reported the use of surface-modified rubber particles in formulations of thermoset systems, such as polyurethanes, polysulfides, and epoxies [95], The surface of the mbber was oxidized by a proprietary gas atmosphere, which leads to the formation of polar functional groups like —COOH and —OH, which in turn enhanced the dispersibility and bonding characteristics of mbber particles to other polar polymers. A composite containing 15% treated mbber particles per 85% polyurethane has physical properties similar to those of the pure polyurethane. Inclusion of surface-modified waste mbber in polyurethane matrix increases the coefficient of friction. This finds application in polyurethane tires and shoe soles. The treated mbber particles enhance the flexibility and impact resistance of polyester-based constmction materials [95]. Inclusion of treated waste mbber along with carboxyl terminated nitrile mbber (CTBN) in epoxy formulations increases the fracture toughness of the epoxy resins [96]. 

Coal tar-modified polyurethane is a cold-applied liquid waterproofing system. The system by Sonneborn is an example of this approach to waterproofing. It is applied as a liquid at the rate of 10-15 mils/coat. The coating dries hard, but has some elasticity. This material may be attacked by acids in groundwater but can be defended by a protection board. The performance of any liquid-applied waterproofing systems is limited by the capabilities of the applicator (it is difficult to achieve even coats on vertical surfaces). 

Polymer-modified asphalt is a cold-applied liquid waterproofing system. As with the Sonneborn system mentioned above, the quality of the installation depends on the applicator (it is difficult to achieve an even coating on a vertical surface). High-grade polymer-modified asphalt is superior to coal tar-modified polyurethane in elasticity, crack-spanning ability, and resealability, but inferior in its resistance to chemicals. 

Polyurethane-acrylic coatings with interpenetrating polymer networks (IPNs) were synthesized from a two-component polyurethane (PU) and an unsaturated urethane-modified acrylic copolymer. The two-component PU was prepared from hydroxyethylacrylate-butylmethacrylate copolymer with or without reacting with c-caprolactonc and cured with an aliphatic polyisocyanate. The unsaturated acrylic copolymer was made from the same hydroxy-functional acrylic copolymer modified with isocyanatoethyl methacrylate. IPNs were prepared simultaneously from the two-polymer systems at various ratios. The IPNs were characterized by their mechanical properties and glass transition temperatures. 

Determination Of MBOCA in Human Urine. MBOCA is commercially important as a curing agent for polyurethanes and epoxy resin systems. Since MBOCA was found to be carcinogenic in animals and is a suspected human carcinogen, it is important to have a reliable method available for the determination of MBOCA in the urine of those workers who are potentially exposed to this compound. In a NIOSH publication a GC method was described for the determination of MBOCA in urine. However, since HPLC does not require derivatization and a lower detection limit was expected, the GC method was modified to be performed by HPLC/ . In order to be able to compare both methods, we used the same extraction procedure. The extraction and sample preparation procedures are as follows ... 

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