Polymer chemistry, greening

Keywords Green catalyst Green polymer chemistry Green solvent Green starting materials Lactic acid... 

Kobayashi S, Makino A (2009) Enzymatic polymer synthesis an opportunity for green polymer chemistry. Chem Rev 109 5288-5353... 

Examples of acid-catalyzed carbonyl chemistiy are abundant in synthetic organic chemistry, biochemistry, industrial processes (such as in the synthesis of malachite green eq 5), and in polymer chemistry (such as in the synthesis of bisphenols of derived epoxy and polycarbonate resins eq 6).9... 

Barbier-Baudry, D. and L. Braachais. Synthesis of Polycarolactone by Microwave Irradiation—An Interesting Route to Synthesize This Polymer by Green Chemistry. Environ Chem Lett 1 (2003) 19-23. 

With chains anchored to the surface, either by a chemical grafting or an insoluble block, good solvent conditions always produce a repulsion. Consequently, copolymers, e.g., diblock, comb, or graft, tend to comprise the most effective stabilizers. Direct grafting to the particle is feasible but requires chemistry specific to the particle (e.g., Green et al., 1987). Advances in synthetic polymer chemistry continue to increase the types of polymers available for this application (e.g., Reiss et al., 1987). 

Greene, N. Lee, J.-D. Hong, J.-I. Shimizu, K., Employing molecular imprinted polymers for sensor discrimination, Polymer Preprints (Amer. Chem. Soc., Division of Polym. Chemistry) 2005,46,139-140... 

Superslurpers (polymers, spe- Green chemistry Growing (salts, fertilizer Energy to take away Gasification (technol-... 

General reviews of polymer biocatalysis can be found in (a) Cheng, H.N., and Gross, R.A. (eds) (2008) Polymer Biocatalysis and Biomaterials II, ACS Symposium Series 999, American Chemical Society. (b) Cheng, H.N., and Gross, R.A. (eds) (2005) Polymer Biocatalysis and Biomaterials, ACS Symposium Series 900, American Chemical Society. (c) Kobayashi, S., and Makino, A. (2009) Enzymatic polymer synthesis an opportunity for green polymer chemistry. Chem. Rev., 109, 5288-5353. (d) Kobayashi, S Uyama, H., and Kimura, S. (2001) Enzymatic polymerization. Chem. Rev.,... 

Cheng, H.N., and R.A. Gross, eds. Green Polymer Chemistry Biocatalysis and Biomaterials. ACS Symposium Series. Vol. 1043. 2010, American Chemical Society. 

MUL 13] Mulhaupt R., Green polymer chemistry and bio-based plastics dreams and verity , Macromolecular Chemistry and Physics, vol. 214, pp. 159-174,2013. 

Green Polymer Chemistry 2012 Cologne. Germany http //www2.amiplastics.com/Events/Event. aspx code=C412 sec= 1853... 

S. Kalia, B.S. Kaith, 1. Kaur, Cellulose Fibers Bio- and Nano-Polymer Composites Green Chemistry and Technology, Polyolefin Based Natural Fiber Composite (Springer, Heidelberg, Dordrecht, London, New York, 2011)... 

Enz5matic polymerization is an important issue for green polymer chemistry to save energy in production processes and to reduce the formation of undesired by-products since the reaction is mostly selective. In general, an enz5mie catalyzed reaction proceeds much faster than a conventional reaction, by lowering the activation energy. 

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