Polymer, blends anionic prepared polymers

Poly(amino acids)2892 and polypeptides2893 can also be grafted onto starch. Starch was first alkylated in the presence of lithium naphthalene, and then the alkoxy derivatives were reacted with /V-carboxy anhydrides. Poly(amide amines) were produced by reacting amines with dioic acids on starch and then crosslinking with epichlorohydrin or 1,2-dichloroethane 2894 Grafting of starch with a synthetic polymer chain, for instance, polystyryl carboxylate anions prepared by an anionic polymerization, can be carried out on a blend of starch and cellulose functionalized by sulfonation, mesylation, or tosylation. In this manner, cellulose-starch graft copolymers were prepared.2895... 

Synthalube. [PiedmotuChem. Industries] Anionic/polymer blend protecting knits and woven fabrics during preparation and dyeing. 

Cellulosic membranes are developed as a novel dmg delivery system, which is expressed to use on the skin and used as a mucus membrane of stomach, ear, nose, eye, rectum, and vagina. The goal excipients of these preparations are adhesive and film-former polymers. Modified cellulose, especially cellulose ethers, are extensively applied in bio-adhesives such as nasal, vaginal, ocular, buccal, and transdermal inventions only or by blend with additional polymers. Further newly applied ethers of cellulose in bio-adhesives contain anionic ether derivatives such as sodium carboxy-methyl cellulose (NaCMC) and non-ionic cellulose ethers such as hydoxypropyl cellulose (HPC), carboxymethyl cellulose (CMC), hydroxyethyl cellulose, ethyl cellulose (EC), hydroxylpropylmethyl cellulose (HPMC), or methyl cellulose (MC). Capability of polymer to absorb water from mucus and pH of objective area are main features defining the adhesive power of polymers. One benefit of cellulose ethers, such as HPC and NaCMC, is smaller dependence of adhesion period and their adhesion strength to pH of medium than thiolated bio-adhesive polymers and polyacrylate... 

Anionic polymerization, if carried out properly, can be truly a living polymerization (160). Addition of a second monomer to polystyryl anion results in the formation of a block polymer with no detectable free PS. This technique is of considerable importance in the commercial preparation of styrene—butadiene block copolymers, which are used either alone or blended with PS as thermoplastics. 

Polymers. The polymers used in the blending experiments were prepared by anionic polymerization using an alkyllithium initiator and a chemical randomizing agent to control monomer sequence, in the manner described by Hsieh and Wofford (3). Randomness was checked in each case by measuring the styrene content as a function of conversion. Table I gives descriptive data for these polymers. 

TSE s have been used to prepare new families of engineering materials of high performance, polymers and their blends. Polycondensation, free radical, anionic and cationic polymerizations were conducted to obtain, e.g., PA, PEST, POM, styrenic or acrylic resins. When the reaction is conducted in a low molecular weight liquid (e.g., solution or emulsion polymerization), usually devolatilization and compounding are carried out in a cascade second extruder. Functionalization and chemical modifications have been performed in TSE on virtually all polymers. 

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