Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Polar functions bonding properties

In the case of nonionic but polar compounds such as sugars, the excellent solvent properties of water stem from its ability to readily form hydrogen bonds with the polar functional groups on these compounds, such as hydroxyls, amines, and carbonyls. These polar interactions between solvent and solute are stronger than the intermolecular attractions between solute molecules caused by van der Waals forces and weaker hydrogen bonding. Thus, the solute molecules readily dissolve in water. [Pg.38]

Composite Particles, Inc. reported the use of surface-modified rubber particles in formulations of thermoset systems, such as polyurethanes, polysulfides, and epoxies [95], The surface of the mbber was oxidized by a proprietary gas atmosphere, which leads to the formation of polar functional groups like —COOH and —OH, which in turn enhanced the dispersibility and bonding characteristics of mbber particles to other polar polymers. A composite containing 15% treated mbber particles per 85% polyurethane has physical properties similar to those of the pure polyurethane. Inclusion of surface-modified waste mbber in polyurethane matrix increases the coefficient of friction. This finds application in polyurethane tires and shoe soles. The treated mbber particles enhance the flexibility and impact resistance of polyester-based constmction materials [95]. Inclusion of treated waste mbber along with carboxyl terminated nitrile mbber (CTBN) in epoxy formulations increases the fracture toughness of the epoxy resins [96]. [Pg.1055]

A speculative proposal was made thirty years ago by Schmid and Krenmayr77, namely that a nitrosyl ion solvated, but not covalently bonded, by a water molecule may be involved in these systems. This hypothesis was investigated theoretically in 1984 by Nguyen and Hegarty78 who carried out ab initio SCF calculations of structure and properties employing the minimal STO-3G basis set, a split-valence basis set plus polarization functions. Optimized geometries of six planar and two nonplanar forms were studied for the nitrosoacidium ion. The lowest minimum of molecular electrostatic potential... [Pg.642]

Separation is based on the reversible chelate-complex formation between the chiral selector covalently bonded to the chromatographic support, and the chiral solute with transition metal cations. Chelation properties of both the chiral selector and the chiral solute are required. Compounds therefore need to have two polar functional groups in a favorable arrangement to each other, like a )3-amino acids, amino alcohols and a-hydroxy acids, which can form rings membered with central chelating metal ions, like Cu(II), Zn(II), Cyclic... [Pg.468]

Delivery of hydrogen occurs syn to the polar functional group. Presumably, the stereoselectivity is the result of coordination of iridium by the functional group. The crucial property required for a catalyst to be stereodirective is that it be able to coordinate with both the directive group and the double bond and still accommodate the metal hydride bond necessary for hydrogenation. In the iridium catalyst illustrated above, the cycloocta-diene (COD) ligand in the catalyst is released upon coordination of the reactant. [Pg.253]

Notice that we want to use 2 d-type functions in the basis. This is because for correlated wave functions the d-type functions serve two purposes, which cannot easily be accomplished by one basis function First they serve as polarization functions, polarizing the electron density in the bonding region, a feature that is especially important in 7t-bonded systems. Secondly, they give important contributions to the angular correlation effects, which is very important in linear molecules. Studies of the ANO s shows that the two properties of the d-type functions cannot be incorporated into one function. Hie polarization d is rather diffuse, while the correlating d is a much more contracted function. We therefore prefer to include two d-type functions in the basis set... [Pg.245]

One problem with the use of molecular connectivities is that they cannot model well such properties as polarity and hydrogen bonding. Lu et al. (2000) attempted to allow for this by the incorporation of polarity correction factors for the presence of polar functional groups ... [Pg.347]

The relative insensitivity of this class of Ni catalysts to polar functional groups, and especially their low oxophilicity, is another important characteristic. This property has been exploited for the development of novel polymeric materials that might find new applications. For example, 1-hexene has been copolymerized with 6-(2-ureido-4-[lH]-pyrimidinone)hex-l-ene (30) to generate a new poly(olefin) elastomer (equation 7). The dimerization (through H-bonding) of the pyrimidinone moieties forms noncovalent crosslinks that bestow unique properties to the otherwise amorphous poly(l-hexene) matrix. [Pg.2923]


See other pages where Polar functions bonding properties is mentioned: [Pg.1013]    [Pg.369]    [Pg.153]    [Pg.19]    [Pg.31]    [Pg.48]    [Pg.4]    [Pg.313]    [Pg.81]    [Pg.246]    [Pg.319]    [Pg.517]    [Pg.182]    [Pg.27]    [Pg.50]    [Pg.247]    [Pg.35]    [Pg.517]    [Pg.467]    [Pg.37]    [Pg.110]    [Pg.103]    [Pg.247]    [Pg.236]    [Pg.215]    [Pg.26]    [Pg.75]    [Pg.337]    [Pg.53]    [Pg.354]    [Pg.1358]    [Pg.66]    [Pg.8]    [Pg.232]    [Pg.311]    [Pg.2]    [Pg.187]    [Pg.262]    [Pg.60]    [Pg.123]    [Pg.250]    [Pg.263]    [Pg.421]   
See also in sourсe #XX -- [ Pg.63 ]




SEARCH



Bond functions

Bond polarity

Bond polarization

Bond property

Bonding bond polarity

Bonding polar bonds

Bonding properties

Functional properties

Polar bonds

Polar functionalities

Polar properties

Polarity function

Polarization functions

Polarized bond

Polarized bonding

© 2024 chempedia.info