Cadmium complexes phthalocyanines

Cf produces two fission products that travel in opposite directions. If one projectile hits the sample, ions will be produced. These ions may then be focused and measured by TOF MS. The other projectile may be used to measure the start of the ionization process. This method has been used to study the ions produced from the ionization of metal complexes such as cadmium thiolates (33) and lanthanide phthalocyanine complexes (34). This method has also been used on metal oxides such as La203 to produce metal oxide cluster ions (35). 

In contrast to the ionic complexes of sodium, potassium, calcium, magnesium, barium, and cadmium, the ease with which transition metal complexes are formed (high constant of complex formation) can partly be attributed to the suitably sized atomic radii of the corresponding metals. Incorporated into the space provided by the comparatively rigid phthalocyanine ring, these metals fit best. An unfavorable volume ratio between the space within the phthalocyanine ring and the inserted metal, as is the case with the manganese complex, results in a low complex stability. 

Cadmium nitrate, preparation of, 6 135 Cadmium phthalocyanine electronic absorption spectra of, 7 68 preparation of, 7 41 Cadmium selenocyanates, 17 337 Cadmium sulfoxide complexes, 24 167-168... 

Crystal PS Good light stability Processing temperatures up to 240°C Red and yellow toners Polycyclics Azo condensation Isoindolinone Metal complex Phthalocyanine Blue Phthalocyanine Green Selected dyes Ultramarine Blue Cadmium pigments Lead pigments Special monoazos... 

Impact PS Good light stability. Must withstand temperatures up to 280X Yellow and red toners Polycyclics Isoindolinone Selected Bis-arylamides Phthalocyanine Blue Phthalocyanine Green Metal complex Selected dyes Cadmium pigments Ultramarine Blue Azo condensation Special monoazos... 

The recoil chemistry of Cd phthalocyanine has been studied by following the behaviour of the In daughter product. The argument is that no bond rupture occurs in the beta decay, and all observed effects are due to the (n,y) reaction during the production of Cd. This is contrary to general experience in p decay studies (see Section 7). The evidence is that cadmium phthalocyanine, which is ionic, anneals even at 20 C, in contrast to crystals of the copper and zinc complexes. A detailed analysis of the annealing kinetics is given. ... 

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