Photopolymerizable resin composition

The ditetrazolium salts (309) have been patented for use in electrochromic electrodes which are used in display devices <89JAP01230026) and tetrazolium salts have also been developed for cell bioassays for neurotoxins active on voltage-sensitive sodium channels <93MI 417-03). Tests for inhibition of corrosion of zinc and brass carried out on 5-aminotetrazole showed it to be ineffective relative to other azoles <86MI 417-01). A number of tetrazoles including the 5-amino, 5-methyl, and 5-phenyl derivatives have been separately incorporated into surfactants used for corrosion inhibition with copper in water <9lMl4l7-07). Photopolymerizable resin compositions which are highly resistant... 

Ishidai, K. Okubo, K. Photopolymerizable resin composition, presensitized lithographic plate material, platemaking method, and coumarin derivative sensitizing dye. Jpn. Kokai Tokkyo Koho JP 2006106675,2006. 

Materials. The radical-type photopolymerizable formulation consisted of a mixture of hexanediol diacrylate (HDDA from UCB) and a polyurethane-diacrylate (Actilane 20 from Arkros). A bis-acylphosphine oxide (BAPO from Ciba) was used as photoinitiator at a typical concentration of 1 wt %. The cationic type photopolymerizable resin consisted of a mixture of the divinylether of triethyleneglycol (RapiCure DVE-3 from ISP) and a divinylether derivative of bis-phenol A (DVE-BPA). The cationic photoinitiator (Cyracure UVI-6990 from Union Carbide) had a composition of 50 wt % of mixed triarylsulfonium hexafluorophosphate salts and 50 wt % of propylene carbonate. The BAPO initiator... 

Naphthalate polyester articles can be coated with polymerizable and crosslinkable compositions. The composition is made from the matrix and a large amount of benzotriazole derivatives. This class of compounds absorbs UV light. The cured compositions help protect the naphthalate polyester from UV exposure and other weathering effects [78]. The matrix consists of acrylic resins and methacrylic resins. The compositions are photopolymerizable. 

Photopolymerizable epoxies using onium salt photoinitiators also show considerable promise for use in high performance composite applications. Traditional thermally cured epoxy resins are already well entrenched in these applications however, the use of the recently developed photocurable epoxy materials offers considerable potential for rapid fabrication of fiber-reinforced composites without the need for cumbersome ovens and long cure times. Photopolymerized epoxy laminates and filament wound pipe have already been demonstrated in our laboratory. 

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