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3-Phenyl derivatives

Figure 2-62. The substituted phenyl derivative is an example of a typical Markush structure. Herein, a number of compounds are described in one structure diagram by fill-ins. Phenylalanine is one of these structures when r is COOH, is H, and X is H. Figure 2-62. The substituted phenyl derivative is an example of a typical Markush structure. Herein, a number of compounds are described in one structure diagram by fill-ins. Phenylalanine is one of these structures when r is COOH, is H, and X is H.
Benzene- sulphon- amlde /)-Tolu- enesul- phon- amlde Benzal Derivative Plcrate 3-Nltro- phthal- Imlde 2 4- Dinitro- phenyl Derivative Formyl Derivative Phenyl thio- urea... [Pg.656]

The rates of reaction of phenacyl bromide with thiosemicarbazide and its phenylated derivative were determined by conductivity measurements in ethanol (517). The reaction is second order up to 85% completion. The activation energies are 10.5 to 11.3 kcal/mole with the phenyl thiosemicarbazide and 8.5 to 9.3 kcal/mole for the unsubstituted derivatives. [Pg.256]

At room temperature bismuthine rapidly decomposes into its elements. The rate of decomposition increases markedly at higher temperatures (8). Bismuthine decomposes when bubbled through silver nitrate or alkafl solutions but is unaffected by light, hydrogen sulfide, or 4 sulfuric acid solution. There is no evidence for the formation of BiH, though the phenyl derivative, (C H BU, is known. The existence of BiH would not be anticipated on the basis of the trend found with other Group 15 (V) "onium" ions. [Pg.127]

Values given for 5-methoxy-2-methyl derivative. 3-Substituted 4-phenyl derivatives. ... [Pg.19]

Despite the weak basicity of isoxazoles, complexes of the parent methyl and phenyl derivatives with numerous metal ions such as copper, zinc, cobalt, etc. have been described (79AHC(25) 147). Many transition metal cations form complexes with Imidazoles the coordination number is four to six (70AHC(12)103). The chemistry of pyrazole complexes has been especially well studied and coordination compounds are known with thlazoles and 1,2,4-triazoles. Tetrazole anions also form good ligands for heavy metals (77AHC(21)323). [Pg.51]

Clearly, the proportion of substitution occurring adjacent to the pyridinic nitrogen atom is increased by protonation. Also noteworthy are the high proportion of ortho substitution product and the selective attack at C-3 in the iV-phenyl derivative. [Pg.247]

Triazole, 1-phenyl-derivatives, 5, 752 polymeric complexes, 5, 790 pyrolysis, 5, 108... [Pg.908]

Three selective methods to remove protective groups are receiving much attention assisted, electrolytic, and photolytic removal. Four examples illustrate assisted removal of a protective group. A stable allyl group can be converted to a labile vinyl ether group (eq. 4) a /3-haloethoxy (eq. 5) or a /3-silylethoxy (eq. 6) derivative is cleaved by attack at the /3-substituent and a stable o-nitro-phenyl derivative can be reduced to the o-amino compound, which undergoes cleavage by nucleophilic displacement (eq. 7) ° ... [Pg.2]

Diseleno acetals and ketals are cleaved more rapidly than their dithio counterparts a methyl derivative is cleaved more rapidly than a phenyl derivative. Methyl iodide or ozone converts diseleno acetals and ketals to vinyl selenides. ... [Pg.210]

The pyrolysis of perfluoro carboxylic salts can result both in mono and bimolecular products At 210-220 °C, silver salts give mostly the coupled products, at 160-165 °C in A -methylpyrrolidinone, the corresponding copper salts also give the simple decarboxylated compounds in nearly equal amounts The decomposition of the copper salts m the presence of lodobenzene at 105-125 °C results m a phenyl derivative, in addition to the olefin and coupled product [94] (equations 60-62)... [Pg.906]

The use of azide reagents is also important for the synthesis of cyclic sulfur(VI)-nitrogen systems. The reaction of SOCI2 with sodium azide in acetonitrile at -35°C provides a convenient preparation of the trimeric sulfanuric chloride [NS(0)C1]3 (Eq. 2.16). " Thionyl azide, SO(N3)2 is generated by the heterogeneous reaction of thionyl chloride vapour with silver azide (Eq. 2.17). This thermally unstable gas was characterized in situ by photoelectron spectroscopy. The phenyl derivative of the six-membered ring [NS(0)Ph]3 can be prepared from lithium azide and PhS(0)Cl. ... [Pg.23]

In solution, the phenyl derivative 12.29 (R = Ph) is fluxional. The mechanism of the fluxional process has been shown by an N NMR investigation of a partially N-labelled sample, Le., PhCN2 N3S3 ( N = 99% N), to involve a series of 1,3-nitrogen shifts (Section 4.8.4). Thermolysis or photolysis of 12.29 generates the corresponding 1,2,3,5-dithiadiazolyl radicals [RCNaSa]". ... [Pg.254]

For both economic and technical reasons, commercial production of such polymers is almost entirely restricted lo the methyl derivatives (and to a lesser extent the phenyl derivatives) and hydrolysis of the various methylchlorosilanes has. accordingly, been much studied. Hydrolysis of MeiSiCl yields triniethylsilanol as a volatile liquid (bp 99 ) it is noticeably more acidic than... [Pg.364]

Similarly, methyl propiolate and methyl phenylpropiolate give the cyclazine (67) and its 2-phenyl derivative, respectively, as would be expected of reactions initiated through a Michael addition to the acetylenic ester. [Pg.141]

Benz[/]isoindole (125), recently prepared from the p-toluene-sulfonyl derivative (124), proved to be too unstable for isolation, but eould be trapped in solution as the Diels-Alder adduct (127). The corresponding 1-phenyl derivative (126) was also prepared and, aecording to spectral measurements, reacts with maleic anhydride to give the product (128) derived by additive substitution. This subsequently rearranged to the adduct (129). The same behavior is observed in the reaction of (126) with V-phenylmaleimide. This provides the first clear indication that substitution products from isoindole derivatives and dienophiles can be converted into the normal addition products. [Pg.144]

A number of quinoxalines carrying substituents in the benzene ring base have been quaternized, including 5-ethoxy,6-methyl, 6-chloro, and some 2-phenyl derivatives, but in none of these cases has the position of quatemization been ascertained. 5-Hydroxy-quinoxaline gives a methiodide which can still form metal complexes, indicating that salt formation occurred on N-1. ... [Pg.33]

Alteration of the relative reactivity of the ring-positions of quinoline is expected and observed when cyclic transition states can intervene. Quinoline plus phenylmagnesium bromide (Et20,150°, 3 hr) produces the 2-phenyl derivative (66% yield) phenyllithium gives predominantly the same product along with a little of the 4-phenylation product. Reaction of butyllithium (Et 0, —35°, 15 min) forms 2-butylquinoline directly in 94% yield. 2-Aryl- or 6-methoxy-quinolines give addition at the 2-position with aryllithium re-agents, and reaction there is so favored that appreciable substitution (35%) takes place at the 2-position even in the 4-chloroquinoline 414. Hydride reduction at the 2-position of quinoline predominates. Reaction of amide ion at the 2-position via a cyclic... [Pg.365]

By means of and NMR spectroscopy it was found that 2-(meth-ylamino)-l-pyrroline (R = Me) is present in solution mainly in the amino form. For the corresponding A -phenyl derivative an equilibrium between 2-aminopyrroline, imino, and 2-amino-4,5-dihydropyrrole tautomers is found (Scheme 20) (87MI5). [Pg.129]

According to the Friedlander method, the condensation of the readily available 2-aminoiiicotinic aldehyde (20a) (74JOC726) or its 6-phenyl derivative (20b) [66JCS(C)315] with nitroacetic acid (21) in boiling ethanol with piperidine as catalyst is another example of this method, which affords in fair yields the corresponding 3-nitro-l,8-naphthyridin-2(lFI)-ones (22a, 74%) and (22b, 47%), respectively [66JCS(C)315]. [Pg.289]


See other pages where 3-Phenyl derivatives is mentioned: [Pg.431]    [Pg.241]    [Pg.553]    [Pg.4]    [Pg.130]    [Pg.226]    [Pg.246]    [Pg.14]    [Pg.14]    [Pg.220]    [Pg.279]    [Pg.7]    [Pg.215]    [Pg.379]    [Pg.32]    [Pg.377]    [Pg.384]    [Pg.116]    [Pg.134]    [Pg.295]    [Pg.86]    [Pg.195]    [Pg.143]   
See also in sourсe #XX -- [ Pg.583 ]




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1,3-Butanedione, 1-phenyl derivative

2-phenyl derivatives, dimers

2-phenyl derivatives, dimers structure

2-phenyl-4-substituted derivatives, ring

2-phenyl-4-substituted derivatives, ring opening

A-Phenyl-y-lactone derivative stereoselective

Amino acid derivatives, 3-phenyl-2-thiohydantoin

Aryl complexes, with phenyl derivatives

Cyclopropanes phenyl derivatives

Diethyl phenyl phosphate derivatives

Dioxans 2-phenyl-, derivatives

Hydrazine derivatives 1-benzyl-1-phenyl

INDEX phenyl derivatives

Iodonium phenyl derivatives

Phenyl Backbone-Derived P,0 Ligands

Phenyl Chloride Derivatives

Phenyl amido derivatives

Phenyl isocyanate deriv

Phenyl isocyanate deriv amines

Phenyl pyrrole derivatives

Phenyl sulfone derivative

Phenyl sulfone derivative hydrogenation

Phenyl sulfone derivative synthesis

Phenyl-stilbene derivatives, Kvl synthesis

Potassium phenyl derivatives

Sodium phenyl derivatives

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