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Phenols halogen reactions

Quinone dioximes, alkylphenol disulfides, and phenol—formaldehyde reaction products are used to cross-link halobutyl mbbers. In some cases, nonhalogenated butyl mbber can be cross-linked by these materials if there is some other source of halogen in the formulation. Alkylphenol disulfides are used in halobutyl innerliners for tires. Methylol phenol—formaldehyde resins are used for heat resistance in tire curing bladders. Bisphenols, accelerated by phosphonium salts, are used to cross-link fluorocarbon mbbers. [Pg.225]

Vulcanisation of EPDM with sulfur systems was studied by H-NMR using ethylidene norbornane (ENBH) as a model of ENB [62]. The use of ENBH was also effective to elucidate the curing reaction of EPDM with phenol-formaldehyde resin [63]. Similarly, halogenation reaction of HR was studied by H-NMR using 2,2,4,8,8-pentamethyl-4-nonene as a model [64],... [Pg.422]

Fig. 2. Re-establishment of Hammett correlation for halogen-substituted phenols in the reaction with polyvinyl acetate radical. The straight line represents the Hammett equation found for 26 compounds (No. 12 in Table 3). Key o non-halogen substituted phenols including 2,6-dimethylphenols, excluding 2,6-t-Bu2-4-substituted-phenols halogen-substituted phenols. Fig. 2. Re-establishment of Hammett correlation for halogen-substituted phenols in the reaction with polyvinyl acetate radical. The straight line represents the Hammett equation found for 26 compounds (No. 12 in Table 3). Key o non-halogen substituted phenols including 2,6-dimethylphenols, excluding 2,6-t-Bu2-4-substituted-phenols halogen-substituted phenols.
The phenol-dienones could be conveniently prepared directly from phenols by reaction with Br2 in the presence of AgC104 and Na2C03. These dienones are transformed efficiently to the 4-alkoxycyclohexa-2,5-dienones by the silver ion mediated reaction in the presence of the corresponding alcohols (equation 96) 48s solid-phase bromina-tion of ferf-butyl-substituted phenols with N-bromosuccinimide also affords halogenated cyclohexadienones . ... [Pg.654]

Selective determinations of bromide and iodide have been performed by implementation of gas diffusion units for halogen permeation after analyte oxidation with permanganate or dichromate, followed by the phenol red reaction or amperometric measurements, and spectrophotometric detection of triiodide, respectively. [Pg.1294]

Sheme 1. As a reaction medium, phenol reduces reaction time and temperature of halogen-replacement reactions, by... [Pg.72]

Ullman reaction The synthesis of diaryls by the condensation of aromatic halides with themselves or other aromatic halides, with the concomitant removal of halogens by a metal, e.g. copper powder thus bromobenzene gives diphenyl. The reaction may be extended to the preparation of diaryl ethers and diaryl thio-ethers by coupling a metal phenolate with an aryl halide. [Pg.411]

Halogen Displacement. Poly(phenylene oxide)s can also be prepared from 4-halo-2,6-disubstituted phenols by displacement of the halogen to form the ether linkage (48). A trace of an oxidizing agent or free radical initiates the displacement reaction. With 4-bromo-2,6-dimethylphenol, the reaction can be represented as in equation 10 ... [Pg.329]

Preparation of phlorogluciaol or its monomethyl ether by reaction of a halogenated phenol with an alkaU metal hydroxide in an inert organic medium by means of a benzyne intermediate has been patented (142). For example, 4-chlororesorcinol reacts with excess potassium hydroxide under nitrogen in refluxing pseudocumene (1,2,4-trimethylbenzene) with the consequent formation of pure phlorogluciaol in 68% yield. In a version of this process, the solvent is omitted but a small amount of water is employed (143). [Pg.383]

Catalysts. In industrial practice the composition of catalysts are usuaUy very complex. Tellurium is used in catalysts as a promoter or stmctural component (84). The catalysts are used to promote such diverse reactions as oxidation, ammoxidation, hydrogenation, dehydrogenation, halogenation, dehalogenation, and phenol condensation (85—87). Tellurium is added as a passivation promoter to nickel, iron, and vanadium catalysts. A cerium teUurium molybdate catalyst has successfliUy been used in a commercial operation for the ammoxidation of propylene to acrylonitrile (88). [Pg.392]

Nucleophilic Substitutions of Benzene Derivatives. Benzene itself does not normally react with nucleophiles such as haUde ions, cyanide, hydroxide, or alkoxides (7). However, aromatic rings containing one or more electron-withdrawing groups, usually halogen, react with nucleophiles to give substitution products. An example of this type of reaction is the industrial conversion of chlorobenzene to phenol with sodium hydroxide at 400°C (8). [Pg.39]

Alkoxyl tion. The nucleophilic replacement of an aromatic halogen atom by an alkoxy group is an important process, especially for production of methoxy-containing iatermediates. Alkoxylation is preferred to alkylation of the phenol wherever possible, and typically iavolves the iateraction of a chloro compound, activated by a nitro group, with the appropriate alcohol ia the presence of alkaU. Careful control of alkaU concentration and temperature are essential, and formation of by-product azoxy compounds is avoided by passiag air through the reaction mixture (21). [Pg.293]

In many cases, substituents linked to a pyrrole, furan or thiophene ring show similar reactivity to those linked to a benzenoid nucleus. This generalization is not true for amino or hydroxyl groups. Hydroxy compounds exist largely, or entirely, in an alternative nonaromatic tautomeric form. Derivatives of this type show little resemblance in their reactions to anilines or phenols. Thienyl- and especially pyrryl- and furyl-methyl halides show enhanced reactivity compared with benzyl halides because the halogen is made more labile by electron release of the type shown below. Hydroxymethyl and aminomethyl groups on heteroaromatic nuclei are activated to nucleophilic attack by a similar effect. [Pg.69]

Ethers, esters, amides and imidazolidines containing an epithio group are said to be effective in enhancing the antiwear and extreme pressure peiformance of lubricants. Other uses of thiiranes are as follows fuel gas odorant (2-methylthiirane), improvement of antistatic and wetting properties of fibers and films [poly(ethyleneglycol) ethers of 2-hydroxymethyl thiirane], inhibition of alkene metathesis (2-methylthiirane), stabilizers for poly(thiirane) (halogen adducts of thiiranes), enhancement of respiration of tobacco leaves (thiirane), tobacco additives to reduce nicotine and to reduce phenol levels in smoke [2-(methoxymethyl)thiirane], stabilizers for trichloroethylene and 1,1,1-trichloroethane (2-methylthiirane, 2-hydroxymethylthiirane) and stabilizers for organic compounds (0,0-dialkyldithiophosphate esters of 2-mercaptomethylthiirane). The product of the reaction of aniline with thiirane is reported to be useful in the flotation of zinc sulfide. [Pg.184]

Toluene from Toluidine.—It is often desirable to obtain tbe hydiocarbon from the base. The process of diazotisntion offers the only convenient method. The diazonium salt may be reduced by alcohol (Reaction 1, p. 162) or, as in the piesent instance, by sodium stannite. Less direct methods are the con-veision of the diazonium compound into (i) the hydrazine (see p. 174), (2) the acid and distillation with lime (p. 200), (3) the halogen derivative and reduction with sodium amalgam, 01, finally (4) the phenol and distillation with zinc dust. [Pg.284]

Nearly every substitution of the aromatic ring has been tolerated for the cyclization step using thermal conditions, while acid-promoted conditions limited the functionality utilized. Substituents included halogens, esters, nitriles, nitro, thio-ethers, tertiary amines, alkyl, ethers, acetates, ketals, and amides. Primary and secondary amines are not well tolerated and poor yield resulted in the cyclization containing a free phenol. The Gould-Jacobs reaction has been applied to heterocycles attached and fused to the aniline. [Pg.430]

Mono-substitution occurs most readily in the stepwise replacement of the halogen substituents of 2,4,6-trichloro-s-triazine with aqueous methanol and sodium bicarbonate (30°, 30 min), the monomethoxy derivative (324) is obtained on heating (65°, 30 min), the disubstitu-ted derivative is formed and on brief heating (65°) with the more basic sodium carbonate or methanolic sodium hydroxide (25°, 3 hr) complete methoxylation (320) occurs. Ethanolic ethoxide (25°, 1 hr) or sodium carbonate (35°) is sufficient to give complete ethoxy-dechlorination. The corresponding phenoxy derivatives are obtained on treatment with one (0°), two (15°, 1 hr), or three equivalents (25-70°, 3 hr) of various sodium phenoxides in aqueous acetone. The stepwise reaction with phenols, alcohols, or thiols proceeds in better yield in organic solvents (acetone or chloroform) with collidine or 2,6-lutidine as acid acceptors than in aqueous sodium bicarbonate. ... [Pg.302]


See other pages where Phenols halogen reactions is mentioned: [Pg.258]    [Pg.124]    [Pg.239]    [Pg.243]    [Pg.157]    [Pg.134]    [Pg.288]    [Pg.149]    [Pg.343]    [Pg.305]    [Pg.365]    [Pg.894]    [Pg.478]    [Pg.484]    [Pg.574]    [Pg.28]    [Pg.507]    [Pg.269]    [Pg.561]    [Pg.485]    [Pg.329]    [Pg.330]    [Pg.331]    [Pg.292]    [Pg.426]    [Pg.292]    [Pg.485]    [Pg.389]    [Pg.173]    [Pg.197]    [Pg.104]    [Pg.334]   
See also in sourсe #XX -- [ Pg.182 ]




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2-Halogenated phenolates

Halogen phenols

Halogenated phenols

Halogenation reactions

Phenol halogenated phenols

Phenol phenolation reaction

Phenol reactions

Phenolates, reactions

Phenolation reaction

Phenols halogenation

Reactions halogens

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