Phase space fixed point

For certain parameter values tliis chemical system can exlribit fixed point, periodic or chaotic attractors in tire tliree-dimensional concentration phase space. We consider tire parameter set... 

Excitable media are some of tire most commonly observed reaction-diffusion systems in nature. An excitable system possesses a stable fixed point which responds to perturbations in a characteristic way small perturbations return quickly to tire fixed point, while larger perturbations tliat exceed a certain tlireshold value make a long excursion in concentration phase space before tire system returns to tire stable state. In many physical systems tliis behaviour is captured by tire dynamics of two concentration fields, a fast activator variable u witli cubic nullcline and a slow inhibitor variable u witli linear nullcline [31]. The FitzHugh-Nagumo equation [34], derived as a simple model for nerve impulse propagation but which can also apply to a chemical reaction scheme [35], is one of tire best known equations witli such activator-inlribitor kinetics ... 

From a mathematical point of view, conformations are special subsets of phase space a) invariant sets of MD systems, which correspond to infinite durations of stay (or relaxation times) and contain all subsets associated with different conformations, b) almost invariant sets, which correspond to finite relaxation times and consist of conformational subsets. In order to characterize the dynamics of a system, these subsets are the interesting objects. As already mentioned above, invariant measures are fixed points of the Frobenius-Perron operator or, equivalently, eigenmodes of the Frobenius-Perron operator associated with eigenvalue exactly 1. In view of this property, almost invariant sets will be understood to be connected with eigenmodes associated with (real) eigenvalues close (but not equal) to 1 - an idea recently developed in [6]. 

In contrast to dissipative dynamical systems, conservative systems preserve phase-space volumes and hence cannot display any attracting regions in phase space there can be no fixed points, no limit cycles and no strange attractors. There can nonetheless be chaotic motion in the sense that points along particular trajectories may show sensitivity to initial conditions. A familiar example of a conservative system from classical mechanics is that of a Hamiltonian system. 

Since the phase space of a dissipative dynamical system contracts with time, we know that, in the long time limit, t oo, the motion will be confined to some fixed attractor, A. Moreover, becaust of the contraction, the dimension, D, of A, must be lower than that of the actual phase space. While D adds little information in the case of a noiichaotic attractor (we know immediately, and trivially, for example, that all fixed-points have D = 0, limit cycles have D = 1, 2-tori have D = 2, etc.), it is of significant interest for strange attractors, whose dimension is typically non-integer valued. Three of the most common measures of D are the fractal dimension, information dimension and correlation dimension. 

It turns out that, in the CML, the local temporal period-doubling yields spatial domain structures consisting of phase coherent sites. By domains, we mean physical regions of the lattice in which the sites are correlated both spatially and temporally. This correlation may consist either of an exact translation symmetry in which the values of all sites are equal or possibly some combined period-2 space and time symmetry. These coherent domains are separated by domain walls, or kinks, that are produced at sites whose initial amplitudes are close to unstable fixed points of = a, for some period-rr. Generally speaking, as the period of the local map... 

Landau proposed in 1944 that turbulence arises essentially through the emergence of an ever increasing number of quasi-periodic motions resulting from successive bifurcations of the fluid system [landau44]. For small TZ, the fluid motion is, as we have seen, laminar, corresponding to a stable fixed point in phase space. As Ti is... 

The point q = p = 0 (or P = Q = 0) is a fixed point of the dynamics in the reactive mode. In the full-dimensional dynamics, it corresponds to all trajectories in which only the motion in the bath modes is excited. These trajectories are characterized by the property that they remain confined to the neighborhood of the saddle point for all time. They correspond to a bound state in the continuum, and thus to the transition state in the sense of Ref. 20. Because it is described by the two independent conditions q = 0 and p = 0, the set of all initial conditions that give rise to trajectories in the transition state forms a manifold of dimension 2/V — 2 in the full 2/V-dimensional phase space. It is called the central manifold of the saddle point. The central manifold is subdivided into level sets of the Hamiltonian in Eq. (5), each of which has dimension 2N — 1. These energy shells are normally hyperbolic invariant manifolds (NHIM) of the dynamical system [88]. Following Ref. 34, we use the term NHIM to refer to these objects. In the special case of the two-dimensional system, every NHIM has dimension one. It reduces to a periodic orbit and reproduces the well-known PODS [20-22]. 

The geometric version of TST laid out in Section II is centered around the NHIM that defines the dividing surface and its stable and unstable manifolds that act as separatrices. The NHIMs at different energies are in turn organized by the saddle point. It forms a fixed point of the dynamics—that is it is itself an invariant object—and it provides the Archimedean point in which the geometric phase-space structure is anchored. 

The moving invariant manifolds determine the reactivity or nonreactivity of an individual trajectory under the influence of a specific noise sequence. They thus provide the most detailed microscopic information on the reaction dynamics that one can possibly possess. In practice, though, one is more often interested in macroscopic quantities that are obtained by averaging over the noise. To illustrate that such quantities can easily be derived from the microscopic information encoded in the TS trajectory, we calculate the probability for a trajectory starting at a point (q, v) in the space-fixed phase space to end up on the product side of the... 

In Equation 6, the dlffuslvlty and mobility are second rank tensors whose positional dependence is a consequence of the hydrodynamic wall effect and F represents the probabllllty that the Brownian particle, initially at some fixed point, will be at some position in space R at a later time t. At low concentrations, P is replaced by the number concentration, C (25). Conceptually the approach followed is similar to that developed by Brenner and Gaydos (25), however, one needs to include an expression for the flux of particles at the wall due to exchange with the pores. Upon averaging over the interstitial tube cross section of Figure 2, one arrives at the following expression (29) for the area averaged rate equation for the mobile phase transport. 

So, the phase space V is divided onto subsets Att(Cy). Each of these subsets includes one cycle (or a fixed point, that is a cycle of length 1). Sets Att(Cy) are (jf)-invariant (jf)(Att(Cy)) C Att(Cy). The set Att(Cy) Cy consist of transient points and there exists such positive integer t that (jf) (Att(Cy)) — Cj if... 

Abstract Theoretical models and rate equations relevant to the Soai reaction are reviewed. It is found that in production of chiral molecules from an achiral substrate autocatalytic processes can induce either enantiomeric excess (ee) amplification or chiral symmetry breaking. The former means that the final ee value is larger than the initial value but is dependent upon it, whereas the latter means the selection of a unique value of the final ee, independent of the initial value. The ee amplification takes place in an irreversible reaction such that all the substrate molecules are converted to chiral products and the reaction comes to a halt. Chiral symmetry breaking is possible when recycling processes are incorporated. Reactions become reversible and the system relaxes slowly to a unique final state. The difference between the two behaviors is apparent in the flow diagram in the phase space of chiral molecule concentrations. The ee amplification takes place when the flow terminates on a line of fixed points (or a fixed line), whereas symmetry breaking corresponds to the dissolution of the fixed line accompanied by the appearance of fixed points. The relevance of the Soai reaction to the homochirality in life is also discussed. 

The asymptotics discussed above force both the concentrations of the substrate a = c- r - s - 2[RS] and the product rs to vanish ultimately. These two conditions define a line of fixed points in the three-dimensional r - s - [RS] phase space. If the initial state has a prejudice to R enantiomer such as ro > s(l, then the system ends up on a fixed line r + 2[RS] = c on a s = 0 plane, as shown in Fig. 5a. Otherwise with ro < so> the system flows to another fixed... 

Consider two molecules, one in the ith cell, one in the jth, of molecular phase space. If these cells happen to correspond to the same value of the coordinates, though to different values of the momenta, there is a chance that the molecules may collide. In the process of collision, the representative points of the molecules will suddenly shift to two other cells, say the kth and Zth, having practically the same coordinates but entirely different momenta. The momenta will be related to the initial values for the collision will satisfy the conditions of conservation of energy and conservation of momentum. These relations give four equations relating the final momenta to the initial momenta, but since there are six components of the final momenta for the two particles, the four equations (conservation of energy and conservation of three components of momentum) will still leave two quantities undetermined. For instance, we may consider that the direction of one of the particles after collision is undetermined, the other quantities being fixed by the conditions of conservation. 

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