Phase Equilibrium Engineering of Supercritical Gas-Liquid Reactors

5 Phase Equilibrium Engineering of Supercritical Gas-Liquid Reactors 

There are four main steps in the PEE procedure (1), seleet an adequate thermodynamic model to represent process mixtures and conditions (2), build an experimental data bank on phase behaviour in order to tune the model to sensitive system properties (3), seleet a solvent when it is required and (4), search for feasible and optimum operating regions. 

In this section specific criteria for gas-liquid reactions under supereritieal conditions will be presented. Also, several applieations of the MHV2 and Group Contribution Assoeiation equation of state models to different stages in the study of these reactions will be diseussed. 

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