Phase equilibria at high pressure

THERMODYNAMICS OF FLUID-PHASE EQUILIBRIA AT HIGH PRESSURES... 

Knud 0stergaard, Gas-Liquid-Particle Operations in Chemical Reaction Engineering J. M. Prausnitz, Thermodynamics of Fluid-Phase Equilibria at High Pressures Robert V. Macbeth, The Burn-Out Phenomenon in Forced-Convection Boiling William Resnick and Benjamin Gal-Or, Gas-Liquid Dispersions... 

Thermodynamics of Fluid-Phase Equilibria at High Pressures... 

Gasparik T. and Lindsley D. H. (1980). Phase equilibria at high pressure of pyroxenes containing monovalent and trivalent ions. In Reviews in Mineralogy, vol. 7, P. H. Ribbe (series ed.), Mineralogical Society of America. 

Many different reviews on apparatus used for the experimental determination of phase equilibria at high pressure have been published [107-110], and it will be useful to separate the subject on the basis of the nature of the systems investigated. 

Optical cells are used to investigate phase equilibria at high pressures as well as for analytical purposes. A more sophisticated approach consists of monitoring the changes in concentration to determine the rate of chemical reactions. 

The presence of transition metal ions in mineral structures may significantly modify phase equilibria at high pressures as a result of increased CFSE acquired by certain cations in the dense oxide phases believed to constitute the Lower Mantle. The additional electronic stabilization can influence both the depth in the Mantle at which a phase transition occurs and the distribution coefficients of transition metals in coexisting dense phases in the Lower Mantle. 

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