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Particles accumulation range

Gravitational settlement is allowed to proceed for 4 to 10 minutes, according to the particle-size range of the sample. The sedimentation tube is then centrifuged to reduce the time required for the smaller particles to reach the bottom. By measuring the volume of particles accumulated as a function of time, the equivalent spherical size distribution of the sample may be computed from formulae based upon Stokes law. In addition to the specially designed sedi-... [Pg.515]

Indeed, based on the number, surface, and volume distributions shown in Fig. 9.6, Whitby and co-workers suggested that there were three distinct groups of particles contributing to this atmospheric aerosol. Particles with diameters >2.5 yu,m are identified as coarse particles and those with diameters 2.5 pm are called fine particles. The fine particle mode typically includes most of the total number of particles and a large fraction of the mass, for example, about one-third of the mass in nonurban areas and about one-half in urban areas. The fine particle mode can be further broken down into particles with diameters between 0.08 and 1-2 yxm, known as the accumulation range, and those with diam-... [Pg.354]

Because of the nature of their sources, particles in the accumulation range generally contain far more organics than the coarse particles (other than biologically derived particles) as well as soluble inorganics such as NH4, N03, and S04. ... [Pg.356]

While many particle distributions show one peak in the accumulation range, many instances have been observed in which there are two peaks. For example, as seen in Fig. 9.8, John and co-workers (1990) observed two peaks within the traditional accumulation mode, one at 0.2 0.1 and one at 0.7 0.2 yu,m, in studies of... [Pg.356]

Particles in the accumulation range tend to represent only a small portion of the total particle number (e.g., 5%) but a significant portion (e.g., 50%) of the aerosol mass. Because they are too small to settle out rapidly (see later), they are removed by incorporation into cloud droplets followed by rainout, or by washout during precipitation. Alternatively, they may be carried to surfaces by eddy diffusion and advection and undergo dry deposition. As a result, they have much longer lifetimes than coarse particles. This long lifetime, combined with their effects on visibility, cloud formation, and health, makes them of great importance in atmospheric chemistry. [Pg.358]

The existence of the (quasi) steady-state in the model of particle accumulation (particle creation corresponds to the reaction reversibility) makes its analogy with dense gases or liquids quite convincing. However, it is also useful to treat the possibility of the pattern formation in the A + B —> 0 reaction without particle source. Indeed, the formation of the domain structure here in the diffusion-controlled regime was also clearly demonstrated [17]. Similar patterns of the spatial distributions were observed for the irreversible reactions between immobile particles - Fig. 1.20 [25] and Fig. 1.21 [26] when the long range (tunnelling) recombination takes place (recombination rate a(r) exponentially depends on the relative distance r and could... [Pg.34]

A cyclone on a cement plant suddenly malfunctions. By the time the plant shuts down, some dust has accumulated on parked cars and other buildings in the plant complex. The nearest affected area is 700 ft from the cyclone location, and the furthest affected area measurable on plant grounds is 2500 ft from the cyclone. What is the particle size range of the dust that has landed on plant grounds ... [Pg.296]

The term (3 /g v dv)/dt represents the accumulation of material in the cluster size range below the critical particle size range u. In homogeneous nucleation theoiy (Chapter 10), this term vanishes there is a steady state for this portion of the distribution in which material is removed as fast as it is supplied. (This is actually true only as a quasi-steady approximation.) The second term on the right-hand side of (11.18) can be written as follows ... [Pg.312]

Thus the volume distribution function is constant over the particle size range where the power law exponent p = —4. Can the constant volume distribution for p = —4 be compatible with the bimodal volume distribution that covers much the same particle size range The power law and bimodal volume distributions are equivalent only as a very rough approximation. Most of the aerosol volume is present in the accumulation... [Pg.365]

Spritzel droplet formation occurs on or near burning stars if the conditions are favorable. In the case of stars which burn very fiercely and produce conditions where fine sprays of liquid droplets of sizes in the range of air colloids (smoke), the spritzels are formed near the star by a small nucleating droplet or particle accumulating the fine spray of material until a drop of 0.05 mm or larger is formed. This usually occurs within a distance of 5 mm from the burning surface. Accumulation of material by such a spritzel consists of aluminum which is in a molten state or is being melted. The molten mixture of salts which cover the surface of the aluminum constitutes the principle mass ofthe spritzel. [Pg.13]

Continental aerosol particles contain a significant fraction of minerals. The insoluble fraction consists mainly of the major crustal elements silicon, aluminum and trivalent iron, which occur as alumino-silicates, quartz, and iron oxides. Elements that are eluted from minerals by water are sodium, potassium, calcium (inpart), and magnesium. The water-soluble inorganic salt ftaction is dominated by am-monimn sulfate. Again, sulfate arises from the oxidation of sulfur dioxide, both by gas-phase and by aqueous phase reactions. Whereas the mineral components are mainly found in the coarse particle size range, ammonium sulfate resides mainly in the accumulation mode. Nitrate occurs partly in association with ammoniirm in the accumulation mode, and partly together with sodiirm and other cations in the coarse particle mode. Thus, nitrate often shows a bimodal size distribution. [Pg.360]

The twin mechanisms of coagulation and heterogeneous nucleation (condensation of one materiai to another) tend to accumulate submicrometre aerosol particle mass in this mode (Whitby and Cantrell, 1976 Willeke and Whitby, 1975). Because of the sharp decrease in particles larger than 0.3 pm in diameter, little mass is transferred from the accumulation mode to the coarse particle size range. Sedimentation and impaction tend to increase the relative concentration of the smallest mechanically produced particles, and then accumulate in this mode. Salt from sea spray is typically present as particles in the 1-5 pm size range, outside the normal accumulation mode. [Pg.7]

A method for estimating the residence time of tropospheric aerosol particles associated with the cosmic-ray produced radionuclides, such as Be, is based on the aerosol particle growth rate, which is the change of particle diameter with time, which was estimated to be 0.004 to 0.005 pmh (McMurry and Wilson, 1982) and the difference between the activity median aerodynamic diameter, AMAD, of a radionuclide, e.g. Be, and the size of the Aitken nuclei in the size distribution of the aerosol particles, which is 0.015 pm (NRC, 1979). The AMAD of all radionuclides is in the accumulation mode of the size distribution of atmospheric aerosol particles which ranges between 0.1 and 2.0 pm (NRC, 1979 Papastefanou and Bondietti, 1987). [Pg.73]

Atmospherie aerosol particles are principally divided into fine and coarse partieles. The fine-particle-size range covers geometric particle diameters (Dp) 1 >Dp > 1000 nm. Particles with Dp > 1 pm are called coarse partiele. Fine particles are also defined as Dap > 2.5 pm (e.g., by inhalation toxieologists for which Dap is defined as the aerodynamic particle diameter). The entire number-size distribution can be principally described by four different aerosol particle modes (Table 2). Fine particles belong to the nucleation (ultrafine), the Aitken, or the accumulation mode (1). The fourth mode is the coarse particle mode. [Pg.68]


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Particles range

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