P-Chlorobenzenesulfonate

Chemical Name Ammonium, dimethyl(2-phenoxyethyl)-2-thenyl-, salt with p-chlorobenzenesulfonic acid (1 1)... 

A solution of free base of the last compound and p-chlorobenzenesulfonic acid (molar ratio 1 1) were reacted together in boiling acetone. After 30 min the solution was cooled and ethyl acetate added to precipitate a colourless solid of N,N-dimethyl-N-(2-phenoxyethyl)-N-(2-thenyl)ammonium 4-chlorbenzolsulfonate. 

The chlorine is an ortho/para director and the sulfonic acid group is a meta director. Since the desired product is p-chlorobenzenesulfonic acid, the chlorine should be introduced first so it can direct the sulfonic acid group para. 

These results can be explained by considering the electrostatic interactions between the cations, the structure of the AOT reversed micelle interface at varying co, and the transition states leading to the formation of the cyclobutane dimers. As mentioned above, p is the only photoproduct formed in studies with /V-octadecyl-trans-4-stilbazolium p-chlorobenzenesulfonate. This can be attributed to the packing constraints of the monomer within the crystal lattice. The fact that the ratio of p/a increases with decreasing co indicates that the way in which the stilbazolium monomer units pack at the interface is affected by to. 

Regardless of the modifications being made, ERA Method 314.0 can be subject to interferences and loss of sensitivity caused by the presence of high concentrations of common matrix anions such as chloride, sulfate, and bicarbonate. In addition, p-chlorobenzenesulfonic acid, which can be found in leachates from some hazardous waste sites, is known to have exactly the same retention time as perchlorate on lonPac AS16 and can, therefore, lead to false positives. 

A new method of catalyzed aromatization was identified for the CHD-diacetate polymers and copolymers in the presence of strong acids. As seen in Figure 2 the addition of 3.7 mole % p-chlorobenzenesulfonic acid reduces the temperature of thermal aromatization by greater than lOO C. The order of acid catalyst effectiveness observed is,... 

Fig. 3. Aromatizatlon Rate Plots of CHD-Diacetate Homopolymer at 239 C. Effect Wt.% p-Chlorobenzenesulfonic Acid... 

Chlorobenzenesulfonic acid p-Chlorobenzenesulfonic acid C5H5CIO3S 98-66-8 192.620 nd (w+1) 67 14725 sH20,Et0H i eth, bz... 

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