Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

P acetamide

Amine B.P. M.P. Acetamide Benz- amide Benzene- sulphon- amlde /)-Tolu- enesul- phon- amlde Benzal Derivative Pi crate 3-Nltro- phthal- Imlde 2 4- Dlnltro- phenyl Derivative Formyl Derivative Phenyl thio- urea... [Pg.658]

Anodic oxidation of n-alkanes in acetonitrile results in mixtures of A -s-alkylacetamides but skeletal rearrangement of the intermediate i-carbenium ions is not observed. Aromatic compounds can undergo direct acetamidation in the ring. Thus, acetophenone, which normally undergoes electrophilic aromatic substitution at the meta position, affords the o- and p-acetamides (Scheme 44). Anthracene is cleanly converted into the acetamide (84) when the reaction is performed in the presence of TFAA as water scavenger (equation 41). ... [Pg.282]

Naphthalene, oxalic acid (hydrated), cinnamic acid, acetamide, benzamide, m-dinitrobenzene,/>-nitrophenol, toluene p-sulphon-... [Pg.21]

Acetamide is thus obtained as a colourless crystalline solid, which has a characteristic odour of mice, stated to be due to the presence of small quantities of methylacetamide, CH3CONHCH3. The acetamide can be purified and rendered odourless by re-crystallisation from acetone, and then has m.p. 82°, b.p. 223°. If this recrystallisation is contemplated, the distilled material should be collected directly into a small weighed beaker or conical flask, so that the solidified acetamide can be readily broken up and removed. [Pg.118]

The crude acetonitrile contains as impurity chiefly acetic acid, arising from the action of phosphoric acid on the acetamide. Therefore add to the nitrile about half its volume of water, and then add powdered dry potassium carbonate until the well-shaken mixture is saturated. The potassium carbonate neutralises any acetic acid present, and at the same time salts out the otherwise water-soluble nitrile as a separate upper layer. Allow to stand for 20 minutes with further occasional shaking. Now decant the mixed liquids into a separating-funnel, run off the lower carbonate layer as completely as possible, and then pour off the acetonitrile into a 25 ml, distilling-flask into which about 3-4 g. of phosphorus pentoxide have been placed immediately before. Fit a thermometer and water-condenser to the flask and distil the acetonitrile slowly, collecting the fraction of b.p. 79-82°. Yield 9 5 g. (12 ml.). [Pg.122]

Acetonitrile is a colourless liquid, of b.p. 82° and [Pg.122]

D) Nitriles. Acetonitrile, CH3CN, b.p. 82°, is miscible with water, but benzonitrile, CaHjCN, b.p. 191, is insoluble. Acetonitrile, unless specially purified, retains the mouse like odour of acetamide benzonitrile has an odour resembling both that of benzaldchyde and of nitrobenzene (bitter almonds). [Pg.359]

Nitrosomethylurea. Acetamide method. To a solution of 59 g. of acetamide in 88 g. (28 ml.) of bromine (1) in a 4-litre beaker add dropwise, with hand stining, a solution of 40 g. of sodium hydroxide in 160 ml. of water. Heat the resulting yellow reaction mixture on a steam bath until eflfervescence sets in (2), after which continue the heating for 2-3 minutes. CrystaUisation of the product from the yellow or red coloured solution usually commences immediately. Cool in an ice bath for 1-2 hours, collect the product by suction filtration, wash with a little ice-cold water, and dry in the air. The yield of colourless acetylmethylurea, m.p. 178-180°, is 50 g. [Pg.969]

Water hydroly2es pure diketene only slowly to give acetoacetic acid [541-50-4] which quickly decomposes to acetone and carbon dioxide, but increasing the pH or adding catalysts (amines, palladium compounds) increases the rate of hydrolysis. The solvolysis of diketene in ammonia results in aceto acetamide [5977-14-0] if used in stoichiometric amounts (99), and P-arninocrotonarnide [15846-25-0] if used in excess (100). [Pg.478]

A/-(P-hydroxy)ethyl- aceto acetamide [24309-97-5] mp 35—40 animal feed additive... [Pg.480]

The most convenient synthesis of 6-hydroxy-2-pyridones is by the condensation of a P-ketoester, eg, ethyl acetoacetate, with an active methylene compound, eg, malonic ester, cyanoacetic ester, and an amine. The amine can be omitted if an acetamide is used and in some cases this modification results in a higher yield. [Pg.297]

Fig. 2. Enzyme catalysis by glycinaminde nbonucleotide transfomiylase (GAR TFase). (a) Transfer of the formyl group from (13) to (12) to form 2-(formylamino)-A/-(5-0-phosphono-P-D-ribofuranosyl acetamide [349-34-8] (14) and (b) multisubstrate inhibitor (15). Fig. 2. Enzyme catalysis by glycinaminde nbonucleotide transfomiylase (GAR TFase). (a) Transfer of the formyl group from (13) to (12) to form 2-(formylamino)-A/-(5-0-phosphono-P-D-ribofuranosyl acetamide [349-34-8] (14) and (b) multisubstrate inhibitor (15).

See other pages where P acetamide is mentioned: [Pg.656]    [Pg.659]    [Pg.659]    [Pg.656]    [Pg.659]    [Pg.1374]    [Pg.1376]    [Pg.659]    [Pg.37]    [Pg.656]    [Pg.659]    [Pg.659]    [Pg.656]    [Pg.659]    [Pg.1374]    [Pg.1376]    [Pg.659]    [Pg.37]    [Pg.163]    [Pg.376]    [Pg.408]    [Pg.589]    [Pg.118]    [Pg.121]    [Pg.127]    [Pg.256]    [Pg.402]    [Pg.403]    [Pg.403]    [Pg.842]    [Pg.863]    [Pg.74]    [Pg.307]    [Pg.158]    [Pg.38]    [Pg.194]    [Pg.653]    [Pg.78]   
See also in sourсe #XX -- [ Pg.70 ]




SEARCH



Acetamide

© 2024 chempedia.info