Ozone, preparation reaction with alkynes

Applications of tetracyanoethylene have been reviewed recent information on molecular complexes, ozonization of alkenes and alkynes (the Criegee reaction), and reactions with ketones is included. Dicyanoketene has been prepared in situ from 2,5-diazido-3,6-dicyano- and 2,6-diazido-3,5-dicyano-l,... 

SCHEME 8.7 Schematic illustration of the process of ozone prelrealment, graft copolymerization PVDF with PMA, preparation of PVDF-g-PPMA membrane with clickable surface by phase inversion, preparation of functional PVDF-g-P[PMA-cZ/ck-MPS] membranes via surface thiol-yne click reaction of thiols on the PVDF-g-PPMA membrane, and preparation of PVDF-g-P[PMA-c//ck-P-CD] membranes via surface alkyne-azide click reaction on the PVDF-g-PPMA membranes. PVDF, poly(vinylidene fluoride) PMA, propargyl methacrylate MPS, 3-mercapto-l-propanesulfonic acid sodium salt azido-fl-CD, mono(6-azido-6-desoxy)-P-cyclodexIrin. Reprinted with permission from Reference 168. Copyright 2011 American Chemical Society. 

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