Oxygen content and

Oxygen Control. To meet industrial standards for both oxygen content and the allowable metal oxide levels in feed water, nearly complete oxygen removal is required. This can be accompHshed only by efficient mechanical deaeration supplemented by an effective and properly controlled chemical oxygen scavenger. 

Plating variables for this process maybe summarized as higher (87°C) operating temperatures enable the oxygen content of the metal to be reduced to 0.01% the CrO iSO ratio should be below 100 to obtain low oxygen metal current efficiencies >8% are associated with high oxygen contents and better current efficiencies are obtained at low current densities. 

Alter the chemistry of the common fluid to render it less conductive and/or less corrosive. Generally, water corrosivity increases with an increase in temperature and oxygen content and a decrease in pH. Inhibitors may he effective. Note that in mixed-metal systems, higher dosages of inhibitors may be required than would be necessary in single-metal systems in the same environment. 

An explosion occurred in a vapor-phase hydrocarbon oxidation plant, injuring ten people and seriously damaging the plant, despite the fact that it was fitted with a protective system that measured the oxygen content and isolated the oxygen supply if the concentration approached the flammable limit. 

Environmentally the most important variables are pH, oxygen content and temperature of the water (Figure 1.96). In single phase conditions both high pH and additions of low levels of oxygen have been used to prevent erosion corrosion . However, because of partitioning effects between water and steam this is more difficult to achieve in two-phase flow. Although additions of morpholine or AMP (2-amino-2-methyl-propan-l-ol) have been successfully used to control pH. 

One of the main factors which establishes the corrosivity of water to stainless steel is the chloride content. Also significant are oxygen content and pH, and it is also probable that other features such as hardness and the nature and concentration of other anions and cations have effects. Water temperature and flow velocity can also be important. Any corrosion takes the form of pitting or, if crevices are available, larger areas of attack within the crevice. 

It is often difficult to conduct laboratory tests in which both the environmental and stressing conditions approximate to those encountered in service. This applies particularly to the corrosive conditions, since it is necessary to find a means of applying cyclic stresses that will also permit maintenance around the stressed areas of a corrosive environment in which the factors that influence the initiation and growth of corrosion fatigue cracks may be controlled. Among these factors are electrolyte species and concentration, temperature, pressure, pH, flow rate, dissolved oxygen content and potential (free corrosion potential or applied). 

Rare earth metals, as well as alkali earth metals, can be used as oxygen getters in the purification of tantalum powder. Osaku and Komukai [608] developed a method for the production of tantalum and niobium metal powder by a two-step reduction of their oxides. The second step was aimed at reducing the oxygen content and was performed by thermal treatment with the addition of rare metals. The powder obtained by the described method is uniform, had a low oxygen level and was suitable for application in the manufacturing of tantalum capacitors. 

Calculate the dissolved oxygen content and express it as mg L 1 1 mL of Mj80 thiosulphate = 1 mg dissolved oxygen. 

There are several available terminal oxidants for the transition metal-catalyzed epoxidation of olefins (Table 6.1). Typical oxidants compatible with most metal-based epoxidation systems are various alkyl hydroperoxides, hypochlorite, or iodo-sylbenzene. A problem associated with these oxidants is their low active oxygen content (Table 6.1), while there are further drawbacks with these oxidants from the point of view of the nature of the waste produced. Thus, from an environmental and economical perspective, molecular oxygen should be the preferred oxidant, because of its high active oxygen content and since no waste (or only water) is formed as a byproduct. One of the major limitations of the use of molecular oxygen as terminal oxidant for the formation of epoxides, however, is the poor product selectivity obtained in these processes [6]. Aerobic oxidations are often difficult to control and can sometimes result in combustion or in substrate overoxidation. In... 

Electrode boilers produce hot water or steam (generally saturated steam) by conducting current through the BW. The water provides resistance, which causes heat to be generated when electrical current flows from one electrode to another. As a consequence, the electrical conductivity of the water is a primary factor in the satisfactory operation of these boilers. Other aspects of water treatment control (such as alkalinity levels, oxygen content, and foam control) and maintenance also must be considered if optimum efficiency is to be obtained. 

A more comprehensive purification procedure uses a sequence of steps as follows filtration at 200°C through a stainless steel powder compact filter of 10-jum pore size reduces the oxygen content and removes any solid impurities. Gettering with Zr foil for 46 h at 760°C reduces the oxygen concentration to 200 ppm. The weight ratio of K to Zr is 13 1 with a surface area to volume ratio of Zr to K 4 1. A second gettering with zirconium foil for 72 h at 800°C reduces the oxygen content 50 ppm. 

In specific, it was found that up to 3.5 mole lithium per mole molybdenum can be intercalated in films with high oxygen content and 1.7 in the others. The Li diffusion coefficient was found equal to 10 cm s at the beginning of the intercalation. It was noted that intercalation of the first Li is never reversible. 

As an example of modeling a fluid in redox disequilibrium, we use an analysis, slightly simplified from Nordstrom et al. (1992), of a groundwater sampled near the Morro do Ferro ore district in Brazil (Table 7.2). There are three measures of oxidation state in the analysis the Eh value determined by platinum electrode, the dissolved oxygen content, and the distribution of iron between ferrous and ferric species. 

Here, we set oxidation state in the model using the dissolved oxygen content and calculate the distribution of species assuming redox equilibrium. 

Elemental analysis of fuel oil often plays a more major role that it may appear to do in lower-boiling products. Aromaticity (through the atomic hydrogen/carbon ratio), sulfur content, nitrogen content, oxygen content, and metals content are all important features that can influence the use of residual fuel oil. 

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