Organonitrogen

Table 2.3. Chemical shift ranges for organonitrogen compounds...

Lartiges SB, Garrigues PP. 1995. Degradation kinetics of organophosphorus and organonitrogen pesticides in different waters under various environmental conditions. Environ Sci Technol 29 1246-1254. 

Structures of Organonitrogen-Lithium Compounds Recent Patterns and Perspectives in Organolithium Chemistry... 

This section summarizes the literature on biodenitrogenation, with focus on BDN studies using quinoline, carbazole, pyridine and indole as model organonitrogen molecules. Research related to biodegradation (vs. nitrogen-specific conversion) of organonitrogen molecules is also considered, since it can be a viable option for relatively low-nitrogen feedstocks. 

The most broadly studied organic nitrogen compound is probably quinoline however, most studies report biodegradation. As we have seen from Table 14, quinoline is representative of the organonitrogen compounds present in the diesel cut. Its transformation has been studied in both, anaerobic and aerobic conditions. Several metabolic pathways have been proposed to explain the aerobic transformations however, no pathway has been proposed for quinoline metabolism under anaerobic conditions. 

The Nitrogen Availability Assay [376] consists of growth tests under defined conditions using mineral salts medium and organonitrogen compounds as sources of carbon and/or nitrogen. Probe molecules include quinoline, pyridine, carbazole, and porphyrin. Growth tests are performed using six conditions ... 

Gascon J, Salau JS, Oubina A, Barcelo D (1998) Monitoring of organonitrogen pesticides in the Ebro river. Preliminary loadings estimates. Analyst 123 941-945... 

Delpuech J-J, Lambert JB, Takeuchi Y. Cyclic Organonitrogen Stereodynamics, VCH Publishers, New York, 1992. 

Ripley BD, Braun HE. 1983. Retention time data for organochlorine, organophosphorus, and organonitrogen pesticides on SE-30 capillary column and application of capillary gas chromatography to pesticide residue analysis. J Assoc Off Anal Chem 66(5) 1084-1095. 

Alkali metal organonitrogen chemistry is a fertile field of research boasting an ever-burgeoning variety of structural types, including not just clusters in the traditional sense but also rings, ladders, chains, etc. Even to review clusters alone would be a substantial task and not feasible to complete in a chapter of this limited size. Therefore what follows in the next section is firstly an introduction to commonly observed cluster motifs in metal nitrogen compounds, chosen because they illus-... 

Common Cluster Motifs in Croup 1 Metal- and Croup 2 Metal-Organonitrogen Chemistry... 

Common Cluster Motifs in Group 1 Metal- and Group 2 Metal—Organonitrogen Chemistry 397... 

Having acquired the ground rules of alkali metal organonitrogen compound aggregation as outlined in the previous section, how does one begin to generate new architectures and, as structure is intimately linked to reactivity, new chemistry, i.e., how can we synthesize new metal-organonitrogen compounds which do not con-... 

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