Organometallic compounds palladium coupling

Negishi E, Tan Z (2005) Diastereoselective, Enantioselective, and Regioselective Carbo-alumination Reactions Catalyzed by Zirconocene Derivatives. 8 139-176 Netherton M, Fu GC (2005)Palladium-catalyzed Cross-Coupling Reactions of Unactivated Alkyl Electrophiles with Organometallic Compounds. 14 85-108 NicolaouKC, KingNP, He Y (1998) Ring-Closing Metathesis in the Synthesis of EpothUones and Polyether Natural Products. 1 73-104 Nishiyama H (2004) Cyclopropanation with Ruthenium Catalysts. 11 81-92 Noels A, Demonceau A, Delaude L (2004) Ruthenium Promoted Catalysed Radical Processes toward Fine Chemistry. 11 155-171... 

Netherton M, Fu GC (2005) Palladium-catalyzed Cross-Coupling Reactions of Unactivated Alkyl Electrophiles with Organometallic Compounds. 14 85-108 Neumann H, see Jacobi von Wangelin A (2006) 18 207-221... 

Transition metal-catalyzed cross-coupling reactions between vinyl organometallic compounds and unactivated alkyl halides that can be usually performed with palladium, nickel and cobalt are of particular synthetic interest [37-39]. Recently, the groups of Cahiez [48] and Cossy [49] concurrently reported the first iron-catalyzed reaction of alkenyl Grignard compounds with primary and secondary alkyl halides (X=Br, I) (Scheme 5.15). The two protocols basically differ in the iron source... 

There have been a number of reports of indirect coupling constants to carbon in organometallic compounds (see Tables XXXI and XXXII). Several trends are discernible. For transition metal complexes, the trends in V(i3C—M—3ip) and (i C—M— H) appear to follow those observed for V( P—M— H) and V( P—M— P). For complexes of ruthenium, osmium, rhodium, iridium, palladium, and platinum, it is generally found that V(A—M—B) (A, B = P, H) is large when... 

Palladium-catalyzed coupling reactions of 2-(5-iodoisoxazol-3-yl)pyridine 274 with a variety of organometallic compounds led to derivatives 275-278 through Sonogashira, Suzuki, Negishi, and Stille reactions, respectively (Scheme 64) <20010L4185>. 

In some cases, it is possible to couple an alcohol with an organometallic compound. Allylic alcohols are coupled with alkylmagnesium bromides in the presence of Ti(OiPr)4, for example. Allylic alcohols can be coupled with arylboronic acids in ionic liquid solvent and a rhodium catalyst. The palladium-catalyzed... 

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