Organic compounds, characterization using

Jensen B., Wolkoff R, Wilkins C.K., Clausen P.A. (1995a) Characterization of linoleum. Part I Measurement of volatile organic compounds by use of the field and laboratory emission cell FLEC . Indoor Air, 5, 38-43. 

Diethyl ether (i)dl- e-thol- (ca. 1930) n. (1) A light volatile flammable liquid used as a sovlent and anesthetic. (2) Any of various organic compounds characterized by an oxygen atom attached to two carbon atoms. 

The two most useful supplementary techniques for the light microscope are EDS and FTIR microscopy. Energy dispersed x-ray systems (EDS) and Eourier-transform infrared absorption (ETIR) are used by chemical microscopists for elemental analyses (EDS) of inorganic compounds and for organic function group analyses (ETIR) of organic compounds. Insofar as they are able to characterize a tiny sample microscopically by PLM, EDS and ETIR ensure rapid and dependable identification when appHed by a trained chemical microscopist. 

Analytical applications of pyrazolones have been reviewed by Busev et al. (65RCR237). Organic bases are easily characterized by formation of highly crystalline salts with picrolonic acid (l-(4-nitrophenyl-3-methyl-4-nitro-5-hydroxypyrazole). The last-named compound is used as a reagent for alkaloids, tryptophan, phenylalanine and for the detection and estimation of calcium (B-76MI40404). 

Suitable reagents for derivatizing specific functional groups are summarized in Table 8.21. Many of the reactions and reagents are the familiar ones used in qualitative analysis for the characterization of organic compounds by physical means. Alcohols are converted to esters by reaction with an acid chloride in the presence of a base catalyst (e.g., pyridine, tertiary amine, etc). If the alcohol is to be recovered after the separation, then a derivative which is fairly easy to hydrolyze, such as p-nltrophenylcarbonate, is convenient. If the sample contains labile groups, phenylurethane derivatives can be prepared under very mild reaction conditions. Alcohols in aqueous solution can be derivatized with 3,5-dinitrobenzoyl chloride. 

Then, once the desired fluorine-containing compounds have been synthesized, the real fun begins as the world of fluorine NMR is entered. However, one s first encounter with fluorine NMR can also present a problem because although most synthetic organic chemists are thoroughly familiar with the use of proton and carbon NMR for compound characterization, few have much experience with the use of fluorine NMR for that purpose. Moreover, there is presently no single place where a person can turn to obtain a concise but thorough introduction to fluorine NMR itself and, just as importantly, to learn how the presence of fluorine substituents can enhance the efficacy of both proton and carbon NMR as tools for structure characterization. 

First step of the approach is the chemical characterization of leachate using well-established analytical techniques (Fig. 2) GC-MS for polar organic compounds (POCs), HRGC-MS for PCDD/Fs, PCBs and PAHs [18], atomic absorption spectrometry for heavy metals and ion chromatography for ammonia. 

This reaction set may be regarded as parallel reactions with respect to consumption of species B and as a series reaction with respect to species A, V, and W. Common examples include the nitration and halogenation of benzene and other organic compounds to form polysubstituted compounds. To characterize the qualitative behavior of such systems, it is useful to consider reactions 9.3.3 and 9.3.4 as mechanistic equations and to analyze the effects of different contacting patterns on the yield of species V. We shall follow the treatment of Levenspiel (7). 

---