Optical resonator structures

The scope of Wessling route has been extended by Mullen and co-workers to develop a soluble precursor route to poly(anthrylene vinyiene)s (PAVs) [51]. It was anticipated that the energy differences between the quinoid and aromatic resonance structures would be diminished in PAV relative to PPV itself. An optical band gap of 2.12 eV was determined for 1,4-PAV 29, some 0.3 eV lower than the value observed in PPV. Interestingly, the 9, lO-b/.v-sulfonium salt does not polymerize, possibly due to stcric effects (Scheme 1-9). 

The collection of chapters in this book represents the most recent global efforts in the research and development of photonic bio/chemical sensing structures. The photonic structures included in book are quite diversified, ranging from optical resonators and interferometers to photonic crystals and specially designed waveguides. For guidance, they are summarized as follows ... 

All these waveguiding films lack one important feature that would be necessary for true lasing They do not have a resonator for optical feedback that would lock the optical modes traveling in the gain direction. The thin-film waveguide confines the optical modes in one direction (in the vertical), but in the other two dimensions the modes have translational and rotational symmetry. The incorporation of resonator structures into the thin films in order to get true organic solid-state lasers will be described next. 

Chromophores with a rather high optical anisotropy are the merocyanines (77), especially in the cyanine limit with equal contributions of the apolar and zwitterionic resonance structures [319]. Thus, they also have been proposed as promising candidates for photorefractive systems based on molecular glasses. For 77, doped with a photosensitizer, a refractive index modulation of 0.01 at an electrical field of 22 V/pm was reported. 

To demonstrate the method an example of a slow-wave optical structure is modelled. Such structures consist of a cascade of directly coupled optical resonators in order to enhance the nonlinear effects. The structure used here was recently defined within Working Group 2 of the European Action COST Pll (http //w3.uniromal.it/energetica/slow waves.doc). One period of the structure consists of one-dimensional Fabry-Perot cavity placed between two distributed Bragg reflectors (DBR) and can be described by the sequence... 

All of the studies discussed above for silver have been done with an incident beam of 1064 nm. These studies have proven that the anisotropy in the nonlinear polarizability from the silver surface is not purely free-electron-like at these wavelengths, that the anisotropy can be correlated with surface symmetry, and that the SH response measured in situ is nearly identical to that measured in UHV. The issue of the sensitivity of the rotational anisotropy to surface electronic properties has been the topic of very recent work which has been conducted by variation of the incident wavelengths to where optical resonances in the bulk or surface electronic structure can be accessed. 

Several optical methods have been used for DNA sensing, such as luminescence, fluorescence Raman or optical waveguide structure spectroscopy, and surface plasmon resonance (SPR). Various immobilization strategies to attach ssDNA to surfaces with the aim of attaining maximum selectivity and sensitivity have been described. 

R vanderVos, PJ van Leeuwen, P Braun and AJ Hoff (1992) Analysis of the optical absorbance spectra ofD1-D2-cytochrome b559 complexes by absorbance-detected magnetic resonance. Structural properties of 6 80. Biochim Biophys Acta 1140 184-198... 

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