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One strategy

We have said that the Schroedinger equation for molecules cannot be solved exactly. This is because the exact equation is usually not separable into uncoupled equations involving only one space variable. One strategy for circumventing the problem is to make assumptions that pemiit us to write approximate forms of the Schroedinger equation for molecules that are separable. There is then a choice as to how to solve the separated equations. The Huckel method is one possibility. The self-consistent field method (Chapter 8) is another. [Pg.172]

These two methods are closely related but differ in the point of initial attachment of the substituent from which the carbocyclic indole ring is constructed. One strategy for building up 2-substituted pyrroles capable of... [Pg.79]

If individual controllers are used instead of optimal computer control, several strategies are possible. In one strategy (Lynch and Fiber, 3rd IFAC Symposium on Automation of Mining, Mineral and Metal Proce.ssing, 25-32, 1980) the sluri y-pump rate is controlled to maintain sump-level constant, which results in smooth cyclone operation. The water-feed rate is ratioed to the ore-feed rate, which keeps the circiilating load from oscillating. The ore-feed rate is then controlled to maintain product-particle size. [Pg.1840]

When a precipitate has been formed during the qualitative analysis of the ions present in a solution, it may be necessary to dissolve the precipitate again to identify the cation or anion. One strategy is to remove one of the ions from the solubility equilibrium so that the precipitate will continue to dissolve in a fruitless chase for equilibrium. Suppose, for example, that a solid hydroxide such as iron(IIl) hydroxide is in equilibrium with its ions in solution ... [Pg.593]

One strategy in limiting the formation of ozone and other photochemical oxidants has been the use (in the past) of low reactivity fuels in internal combustion engines. More recently, alternate fuels (methanol, for instance) have been proposed for regions that suffer from elevated levels of photochemical air pollution. The effect of switching to such a low-reactivity fuel may be seen in Equation E2 for methanol, which has a simple atmospheric reaction mechanism. [Pg.78]

If, 2 substitution is involved, one strategy may avoid separation of isomers in that the other position becomes blocked. [Pg.20]

Patients who are acutely intoxicated with an opioid usually present with miosis, euphoria, slow breathing and slow heart rate, low blood pressure, and constipation. Seizures may occur with certain agents such as meperidine (Demerol ). It is critically important to monitor patients carefully to avoid cardiac/ respiratory depression and death from an excessive dose of opioids. One strategy is to reverse the intoxication by utilizing naloxone (Narcan ) 0.4 to 2 mg IV every 2 to 3 minutes up to 10 mg. Alternatively, the IM/SC route may be used if IV access is not available. Because naloxone is shorter-acting than most abused opioids, it may need to be readministered at periodic intervals otherwise the patient could lapse into cardiopulmonary arrest after a symptom-free interval of reversed... [Pg.532]

Many research compounds are poorly soluble in water. When very lipophilic molecules precipitate in the donor wells, it is possible to filter the donor solution before the PAMPA sandwich is prepared. On occasion, the filtered donor solution contains such small amounts of the compound that determination of concentrations by UV spectrophotometry becomes impractical. One strategy to overcome the precipitation of the sample molecules in the donor wells is to add a cosolvent to the solutions (Section 7.4.4). It is a strategy of compromise and practicality. Although the cosolvent may solubilize the lipophilic solute molecule, the effect on transport may be subtle and not easy to predict. At least three mechanisms may cause Pe and membrane retention (%R) values to alter as a result of the cosolvent addition. To a varying extent, all three mechanisms may simultaneously contribute to the observed transport ... [Pg.226]

One strategy that has often been used is to proceed along the path of steepest ascent until a maximum is reached. Then another search is made. A path of steepest ascent is determined and followed until another maximum is reached. This is continued until the climber thinks he is in the vicinity of the global maximum. To aid in reaching the maximum, the technique of using three points to estimate a quadratic surface, as was done previously, may be used. [Pg.399]

A mbros It could be a peculiarity of C. elegans. The animal is relatively simple and develops rapidly, so it must employ strategies to optimize developmental fidelity given its small number of cells and short time to develop. Cell cycle dependent cell fate commitment could be one strategy to achieve precision with limited cells to work with and limited developmental time. [Pg.218]

Vacuum forming has limitations due to the non-uniform wall thicknesses of its products. As the sheet is drawn into the mold, its thickness decreases, especially in the corners. For this reason, just as in blow molding, we design vacuum formed products to have rounded corners. If the depth of the cavity is excessive, walls can become locally so thin that they are unacceptably weak. One strategy that we use to alleviate this problem is to pump air into the cavity after the sheet has been clamped. This inflates the sheet, pushing it upwards and expanding its area approximately uniformly. When we subsequently apply a vacuum the expanded sheet is drawn back down into the mold. The finished product has a more uniform wall thickness than if we had applied the vacuum directly. [Pg.273]

Particle Transport. Because many organic chemicals bind with aquatic particulate matter, particle transport can determine the fate of compounds. Sediment transport has been of interest to the engineering profession for many years. Many discussions of the dynamics of fluvial sediment transport have appeared in the literature (11, 12). As with hydrodynamic transport, one strategy for environmental modeling is to "piggy-back the transport of sorbed chemicals on a model of transport of the sediment phase. [Pg.27]


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See also in sourсe #XX -- [ Pg.50 ]




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